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d'Oliveira, Léa; Dugerdil, Lucas; Ménot, Guillemette; Evin, Allowen; Muller, Serge D; Ansanay-Alex, Salomé; Azuara, Julien; Bonnet, Colline; Bremond, Laurent; Shah, Mehmet; Peyron, Odile (2024): Glycerol dialkyl glycerol tetraethers analysis of the last 15,000 years cal BP of the Canroute peatland sequence (Massif Central, France) [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.967141 (DOI registration in progress)

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Abstract:
This dataset contains the relative abundance of isoprenoidal and branched glycerol dialkyl glycerol tetraethers (GDGT) components, in addition to various indexes used to reconstruct the mean annual air temperature and pH, of the Canroute peatland sequence (Massif Central, France) for the last 15,000 years cal BP. The analysis was performed by a double microwave extraction at 70°C with dichloromethane (DCM)-methanol (MeOH) mixture (3:1, v/v), filtered on a solid-phase extraction (SPE) cartridge and then separated into polar and apolar fractions on a silica column with a hexane-DCM (1:1, v/v) and DMC-MeOH (1:1, v/v) mixtures respectively. Samples were then analysed in hexane-propanol (98.2:0.2, v/v) by high-performance liquid chromatography with mass spectrometry (HPLC-MS). Ions in selected ion monitoring (SIM) are detected for mass-to-change ratios according to Hopmans et al. (2016, doi: 10.1016/j.orggeochem.2015.12.006). This data was used to better understand the biological origin of the components and reconstruct the environmental and paleoclimate of the Canroute peatland sequence.
Keyword(s):
GDGT; Holocene; peat core; Southern France
Funding:
European Research Council (ERC), grant/award no. 852573: DEMETER
Coverage:
Latitude: 43.646670 * Longitude: 2.587289
Date/Time Start: 2019-09-01T00:00:00 * Date/Time End: 2019-09-01T00:00:00
Minimum DEPTH, sediment/rock: 0.00 m * Maximum DEPTH, sediment/rock: 1.69 m
Event(s):
CAN02 * Latitude: 43.646670 * Longitude: 2.587289 * Date/Time: 2019-09-01T00:00:00 * Elevation: 790.0 m * Location: France * Comment: Canroute Peatland, Massif Central, France
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Sample code/labelSample labeld'Oliveira, Léa
2DEPTH, sediment/rockDepth sedmd'Oliveira, LéaGeocode
3AGEAgeka BPd'Oliveira, LéaAge, radiocarbonGeocode – Poznan Radiocarbon Laboratory (Poland)
4Isoprenoid acyclic glycerol dialkyl glycerol tetraether, fractional abundanceiso GDGT-0d'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
5Isoprenoid monocyclic glycerol dialkyl glycerol tetraether, fractional abundanceiso GDGT-1d'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
6Isoprenoid dicyclic glycerol dialkyl glycerol tetraether, fractional abundanceiso GDGT-2d'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
7Isoprenoid tricyclic glycerol dialkyl glycerol tetraether, fractional abundanceiso GDGT-3d'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
8Isoprenoid glycerol dialkyl glycerol tetraether, 4, fractional abundanceiso GDGT-4d'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
9Crenarchaeol isomer, fractional abundanceCren isod'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
10Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIIa, fractional abundanceMBT5ME brGDGT IIIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
11Methylation index of 6-methyl branched glycerol dialkyl glycerol tetraether, IIIa, fractional abundanceMBT6ME brGDGT IIIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
12Methylation index of 7-methyl branched glycerol dialkyl glycerol tetraether, IIIa, fractional abundanceMBT7ME brGDGT IIIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
13Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIIb, fractional abundanceMBT5ME brGDGT IIIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
14Methylation index of 6-methyl branched glycerol dialkyl glycerol tetraether, IIIb, fractional abundanceMBT6ME brGDGT IIIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
15Methylation index of 7-methyl branched glycerol dialkyl glycerol tetraether, IIIb, fractional abundanceMBT7ME brGDGT IIIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
16Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIIc, fractional abundanceMBT5ME brGDGT IIIcd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
17Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIa, fractional abundanceMBT5ME brGDGT IIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
18Methylation index of 6-methyl branched glycerol dialkyl glycerol tetraether, IIa, fractional abundanceMBT6ME brGDGT IIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
19Methylation index of 7-methyl branched glycerol dialkyl glycerol tetraether, IIa, fractional abundanceMBT7ME brGDGT IIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
20Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIb, fractional abundanceMBT5ME brGDGT IIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
21Methylation index of 6-methyl branched glycerol dialkyl glycerol tetraether, IIb, fractional abundanceMBT6ME brGDGT IIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
22Methylation index of 7-methyl branched glycerol dialkyl glycerol tetraether, IIb, fractional abundanceMBT7ME brGDGT IIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
23Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIc, fractional abundanceMBT5ME brGDGT IIcd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
24Methylation index of 6-methyl branched glycerol dialkyl glycerol tetraether, IIc, fractional abundanceMBT6ME brGDGT IIcd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
25Methylation index of 7-methyl branched glycerol dialkyl glycerol tetraether, IIc, fractional abundanceMBT7ME brGDGT IIcd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
26Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, Ia, fractional abundanceMBT5ME brGDGT Iad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
27Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, Ib, fractional abundanceMBT5ME brGDGT Ibd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
28Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, Ic, fractional abundanceMBT5ME brGDGT Icd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
29Isoprenoid acyclic glycerol dialkyl glycerol tetraether/Crenarchaeol ratioiso GDGT-0/Crend'Oliveira, LéaCalculated according to Blaga et al. (2009)
30Sum branched glycerol dialkyl glycerol tetraether, IIIa/Sum Branched glycerol dialkyl glycerol tetraether, IIa ratioSum brGDGT IIIa/sum brGDGT IIad'Oliveira, LéaCalculated according to Schouten et al. (2012)
31Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraetherMBT'5MEd'Oliveira, LéaCalculated according to De Jonge et al. (2014)
32Cyclisation index of 6-methyl branched glycerol dialkyl glycerol tetraetherCBT6MEd'Oliveira, LéaCalculated according to De Jonge et al. (2014)
33IndexIndexd'Oliveira, LéaCalculated according to De Jonge et al. (2014)Index1
34Community IndexCId'Oliveira, LéaCalculated according to De Jonge et al. (2021)
35Isomer ratioIRd'Oliveira, LéaCalculated according to De Jonge et al. (2021)
36pHpHd'Oliveira, LéaCalculated according to De Jonge et al. (2014)CBT'-based calibration
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
2550 data points

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