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d'Oliveira, Léa; Dugerdil, Lucas; Ménot, Guillemette; Evin, Allowen; Muller, Serge D; Ansanay-Alex, Salomé; Azuara, Julien; Bonnet, Colline; Bremond, Laurent; Shah, Mehmet; Peyron, Odile (2024): Glycerol dialkyl glycerol tetraethers analysis of the last 15,000 years cal BP of the Canroute peatland sequence (Massif Central, France) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.967141

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Published: 2024-05-02DOI registered: 2024-05-31

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Abstract:
This dataset contains the relative abundance of isoprenoidal and branched glycerol dialkyl glycerol tetraethers (GDGT) components, in addition to various indexes used to reconstruct the mean annual air temperature and pH, of the Canroute peatland sequence (Massif Central, France) for the last 15,000 years cal BP. The analysis was performed by a double microwave extraction at 70°C with dichloromethane (DCM)-methanol (MeOH) mixture (3:1, v/v), filtered on a solid-phase extraction (SPE) cartridge and then separated into polar and apolar fractions on a silica column with a hexane-DCM (1:1, v/v) and DMC-MeOH (1:1, v/v) mixtures respectively. Samples were then analysed in hexane-propanol (98.2:0.2, v/v) by high-performance liquid chromatography with mass spectrometry (HPLC-MS). Ions in selected ion monitoring (SIM) are detected for mass-to-change ratios according to Hopmans et al. (2016, doi: 10.1016/j.orggeochem.2015.12.006). This data was used to better understand the biological origin of the components and reconstruct the environmental and paleoclimate of the Canroute peatland sequence.
Keyword(s):
GDGT; Holocene; peat core; Southern France
Funding:
European Research Council (ERC), grant/award no. 852573: DEMETER
Coverage:
Latitude: 43.646670 * Longitude: 2.587289
Date/Time Start: 2019-09-01T00:00:00 * Date/Time End: 2019-09-01T00:00:00
Minimum DEPTH, sediment/rock: 0.00 m * Maximum DEPTH, sediment/rock: 1.69 m
Event(s):
CAN02 * Latitude: 43.646670 * Longitude: 2.587289 * Date/Time: 2019-09-01T00:00:00 * Elevation: 790.0 m * Location: France * Method/Device: Russian corer (RUSC) * Comment: Canroute Peatland, Massif Central, France
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample code/labelSample labeld'Oliveira, Léa
DEPTH, sediment/rockDepth sedmd'Oliveira, LéaGeocode
AGEAgeka BPd'Oliveira, LéaAge, radiocarbonGeocode – Poznan Radiocarbon Laboratory (Poland)
Isoprenoid acyclic glycerol dialkyl glycerol tetraether, fractional abundanceiso GDGT-0d'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
Isoprenoid monocyclic glycerol dialkyl glycerol tetraether, fractional abundanceiso GDGT-1d'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
Isoprenoid dicyclic glycerol dialkyl glycerol tetraether, fractional abundanceiso GDGT-2d'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
Isoprenoid tricyclic glycerol dialkyl glycerol tetraether, fractional abundanceiso GDGT-3d'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
Isoprenoid glycerol dialkyl glycerol tetraether, 4, fractional abundanceiso GDGT-4d'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
Crenarchaeol isomer, fractional abundanceCren isod'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
10 Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIIa, fractional abundanceMBT5ME brGDGT IIIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
11 Methylation index of 6-methyl branched glycerol dialkyl glycerol tetraether, IIIa, fractional abundanceMBT6ME brGDGT IIIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
12 Methylation index of 7-methyl branched glycerol dialkyl glycerol tetraether, IIIa, fractional abundanceMBT7ME brGDGT IIIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
13 Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIIb, fractional abundanceMBT5ME brGDGT IIIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
14 Methylation index of 6-methyl branched glycerol dialkyl glycerol tetraether, IIIb, fractional abundanceMBT6ME brGDGT IIIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
15 Methylation index of 7-methyl branched glycerol dialkyl glycerol tetraether, IIIb, fractional abundanceMBT7ME brGDGT IIIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
16 Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIIc, fractional abundanceMBT5ME brGDGT IIIcd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
17 Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIa, fractional abundanceMBT5ME brGDGT IIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
18 Methylation index of 6-methyl branched glycerol dialkyl glycerol tetraether, IIa, fractional abundanceMBT6ME brGDGT IIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
19 Methylation index of 7-methyl branched glycerol dialkyl glycerol tetraether, IIa, fractional abundanceMBT7ME brGDGT IIad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
20 Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIb, fractional abundanceMBT5ME brGDGT IIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
21 Methylation index of 6-methyl branched glycerol dialkyl glycerol tetraether, IIb, fractional abundanceMBT6ME brGDGT IIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
22 Methylation index of 7-methyl branched glycerol dialkyl glycerol tetraether, IIb, fractional abundanceMBT7ME brGDGT IIbd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
23 Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, IIc, fractional abundanceMBT5ME brGDGT IIcd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
24 Methylation index of 6-methyl branched glycerol dialkyl glycerol tetraether, IIc, fractional abundanceMBT6ME brGDGT IIcd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
25 Methylation index of 7-methyl branched glycerol dialkyl glycerol tetraether, IIc, fractional abundanceMBT7ME brGDGT IIcd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
26 Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, Ia, fractional abundanceMBT5ME brGDGT Iad'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
27 Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, Ib, fractional abundanceMBT5ME brGDGT Ibd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
28 Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraether, Ic, fractional abundanceMBT5ME brGDGT Icd'Oliveira, LéaHigh Performance Liquid Chromatography - Mass spectrometry (HPLC-MS)
29 Isoprenoid acyclic glycerol dialkyl glycerol tetraether/Crenarchaeol ratioiso GDGT-0/Crend'Oliveira, LéaCalculated according to Blaga et al. (2009)
30 Sum branched glycerol dialkyl glycerol tetraether, IIIa/Sum Branched glycerol dialkyl glycerol tetraether, IIa ratioSum brGDGT IIIa/sum brGDGT IIad'Oliveira, LéaCalculated according to Schouten et al. (2012)
31 Methylation index of 5-methyl branched glycerol dialkyl glycerol tetraetherMBT5MEd'Oliveira, LéaCalculated according to De Jonge et al. (2014a)
32 Cyclisation index of 6-methyl branched glycerol dialkyl glycerol tetraetherCBT6MEd'Oliveira, LéaCalculated according to De Jonge et al. (2014a)
33 IndexIndexd'Oliveira, LéaCalculated according to De Jonge et al. (2014a)Index1
34 Community IndexCId'Oliveira, LéaCalculated according to De Jonge et al. (2021)
35 Isomer ratioIRd'Oliveira, LéaCalculated according to De Jonge et al. (2021)
36 pHpHd'Oliveira, LéaCalculated according to De Jonge et al. (2014a)CBT'-based calibration
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
2550 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Sample label

Depth sed [m]

Age [ka BP]

iso GDGT-0

iso GDGT-1

iso GDGT-2

iso GDGT-3

iso GDGT-4

Cren iso
10 
MBT5ME brGDGT IIIa
11 
MBT6ME brGDGT IIIa
12 
MBT7ME brGDGT IIIa
13 
MBT5ME brGDGT IIIb
14 
MBT6ME brGDGT IIIb
15 
MBT7ME brGDGT IIIb
16 
MBT5ME brGDGT IIIc
17 
MBT5ME brGDGT IIa
18 
MBT6ME brGDGT IIa
19 
MBT7ME brGDGT IIa
20 
MBT5ME brGDGT IIb
21 
MBT6ME brGDGT IIb
22 
MBT7ME brGDGT IIb
23 
MBT5ME brGDGT IIc
24 
MBT6ME brGDGT IIc
25 
MBT7ME brGDGT IIc
26 
MBT5ME brGDGT Ia
27 
MBT5ME brGDGT Ib
28 
MBT5ME brGDGT Ic
29 
iso GDGT-0/Cren
30 
Sum brGDGT IIIa/sum brGDGT IIa
31 
MBT5ME
32 
CBT6ME
33 
Index
34 
CI
35 
IR
36 
pH
CAN00.00-0.770.6390960.0844250.0444980.0088700.0775070.1456040.1159230.0053310.0030470.0005170.0016290.0002180.0004470.3898310.0184100.0052980.0081590.0021600.0012900.0026400.0004350.0001160.3922150.0408320.0066474.3892700.2973670.459812-1.429302-0.0451100.4217120.0448364.877409
CAN20.02-0.310.7559020.0634490.0363310.0070870.0487720.0884590.1280500.0068760.0042260.0008850.0018150.0002130.0003820.3832380.0190590.0059460.0084180.0022020.0009780.0017040.0009910.0001950.3879420.0360160.0067338.5452210.3341260.452358-1.394905-0.0558240.4147620.0482754.932101
CAN40.040.170.7123460.0848090.0464500.0082450.0518910.0962590.1195110.0071280.0036540.0007070.0018540.0002390.0004670.3562740.0249900.0057330.0096570.0021650.0013300.0033800.0000500.0002390.4035750.0467910.0090227.4003150.3354460.484479-1.3089800.0016730.4382570.0632375.068721
CAN60.060.710.6529020.0865120.0660570.0192920.0628680.1123700.0880970.0054840.0040680.0006130.0014980.0001890.0005000.3493000.0197760.0077410.0086610.0027060.0016000.0027900.0011780.0003430.4369250.0515810.0112835.8102700.2522100.526850-1.3372380.0661380.4794050.0545975.023791
CAN80.081.330.6186760.0870210.0753060.0193620.0699260.1297100.0988670.0067490.0046040.0008220.0017690.0002040.0006160.3511060.0263550.0090690.0096750.0030360.0017190.0042050.0001470.0003990.4121280.0515220.0115634.7697040.2815880.506048-1.2628630.0390570.4534470.0685275.142047
CAN100.102.070.7066420.0729920.0680670.0197230.0469090.0856680.0833020.0051470.0040140.0005450.0012060.0001150.0004930.3477070.0186340.0081670.0088200.0029760.0016750.0031530.0007520.0003150.4450750.0518210.0113428.2486350.2395750.534301-1.3573400.0780670.4879960.0522904.991830
CAN120.122.940.7298550.0660060.0654340.0186780.0250570.0949700.0784290.0046210.0035750.0007100.0017150.0002980.0006440.3219820.0215830.0063330.0090990.0023670.0013340.0054870.0001950.0004560.4684360.0565080.0124537.6850820.2435830.564259-1.3238270.1285720.5176320.0614225.045116
CAN140.143.990.7209660.0764710.0572750.0160260.0271080.1021540.0754490.0049830.0051530.0027440.0025220.0001160.0010480.3387540.0152420.0075990.0140590.0023040.0019840.0047100.0014260.0000000.4454410.0559080.0127407.0576660.2227250.542826-1.3571840.0928260.4990260.0465574.992077
CAN160.165.230.6148230.0851090.0828900.0206600.0704270.1260910.0671430.0047370.0038930.0005100.0014050.0002020.0006190.3666410.0076900.0075900.0094640.0021530.0016410.0036840.0000640.0003340.4577240.0495800.0102394.8760270.1831310.536606-1.5418820.0742750.5000170.0278504.698408
CAN180.186.700.6258490.0943870.0849030.0208090.0632290.1108230.0771140.0047430.0044000.0006320.0011380.0001990.0006170.3519500.0282120.0105400.0108690.0017700.0022680.0032860.0007220.0005800.4302060.0532390.0128185.6472970.2191040.528230-1.2639310.0783720.4742320.0713275.140350
CAN200.208.420.6466070.1034120.0883520.0269500.0518470.0828320.0765040.0048580.0047400.0005910.0011710.0001230.0005840.3387480.0240740.0080010.0096790.0024620.0019730.0030560.0017970.0004440.4569360.0494400.0113437.8062190.2258430.547442-1.3009190.1050060.5000060.0651355.081538
CAN220.2210.390.6333510.0979730.0958110.0316590.0524320.0887740.0645390.0039770.0048130.0006250.0010630.0001230.0005450.3489570.0138720.0083340.0099670.0016890.0020310.0034950.0021370.0004140.4694010.0459740.0131457.1343870.1849470.553147-1.4060060.1054220.5136280.0413814.914450
CAN240.2412.570.6573580.0851850.0862270.0276640.0527300.0908360.0780130.0044020.0051750.0006010.0010720.0002680.0005290.3358380.0196860.0093960.0108020.0017820.0019760.0038140.0007830.0003440.4541350.0530230.0127647.2367910.2322930.548216-1.3500930.1036280.5008960.0550045.003352
CAN260.2614.910.5957020.0937890.1012580.0462060.0617690.1012760.0623040.0049550.0053390.0011220.0014080.0003920.0006790.3284550.0197760.0093210.0114690.0017170.0022050.0059630.0002810.0009060.4687590.0518070.0174905.4343430.1897620.568603-1.2983360.1336390.5214120.0594265.085646
CAN280.2817.380.6237640.0883250.0962910.0427560.0345050.1143590.0673820.0048380.0060470.0008750.0015340.0001930.0010710.3858060.0116160.0000000.0088060.0023920.0015600.0073670.0004350.0006540.4346090.0468840.0169625.4544560.1746520.515031-1.3819520.0280250.4774360.0350364.952696
CAN300.3019.940.5737330.0945830.1191410.0519960.0682030.0923440.0644800.0044310.0057450.0006170.0011520.0001900.0005630.3407290.0171470.0093030.0104780.0016420.0025040.0059750.0001980.0007830.4652270.0484940.0161556.2130230.1892410.556862-1.3477720.1122080.5128950.0505585.007043
CAN320.3222.540.5961730.0918040.1387840.0750450.0430580.0551360.0654530.0049550.0070760.0009070.0013730.0003760.0006460.4211470.0104720.0105020.0135520.0008180.0035510.0072680.0022900.0003610.4015260.0255140.01618310.8127780.1554170.466235-1.406919-0.0399240.4359060.0307284.912999
CAN340.3425.150.5903080.0937370.1331030.0648690.0475650.0704180.0677040.0044160.0063410.0009120.0012520.0002550.0006750.3635250.0090680.0089960.0122550.0010090.0032390.0084780.0001400.0004940.4595920.0314340.0159868.3829570.1862430.528703-1.4602230.0602240.4997510.0303204.828246
CAN360.3627.720.6477260.0847500.1117650.0635630.0273390.0648570.0627420.0037130.0062580.0008770.0011980.0001430.0009470.3845180.0105580.0056060.0122950.0008090.0023650.0115090.0003570.0004570.4453530.0281420.0185839.9869650.1631700.510909-1.4164420.0266920.4847400.0309214.897858
CAN380.3830.220.6225630.0945310.1193100.0552370.0486270.0597320.0639270.0058670.0107300.0008180.0009790.0003540.0006650.3953260.0106350.0032390.0139870.0006780.0040210.0096050.0017970.0003830.4313590.0235840.01917610.4226010.1617070.495441-1.371768-0.0000350.4683170.0346864.968888
CAN400.4032.600.6376940.0889020.1121290.0560190.0443870.0608700.0489800.0042420.0082460.0005650.0007520.0002020.0005430.3577420.0084640.0066170.0101430.0018370.0038420.0090680.0015670.0004240.4979570.0203940.01614610.4763670.1369140.556519-1.4509220.1019890.5341470.0302924.843034
CAN420.4234.860.6652270.0787710.1032730.0566090.0439760.0521440.0656380.0067350.0103220.0006250.0010300.0003350.0005090.3747830.0116380.0099970.0102630.0005400.0032900.0090610.0001550.0007120.4526910.0180920.01587712.7574310.1751370.514220-1.4133230.0370290.4858220.0400474.902817
CAN440.4436.990.6097620.0876750.1336650.0661930.0470410.0556640.0523850.0049560.0093470.0006030.0008880.0002100.0005310.3592770.0109440.0077980.0122720.0004870.0040980.0112880.0008680.0009710.4755210.0216580.01995210.9542690.1458080.543004-1.3830270.0803910.5167420.0371874.950987
CAN460.4639.000.5949640.0941040.1334480.0654620.0502280.0617950.0642790.0060410.0090120.0010560.0008590.0002860.0006150.3551090.0147470.0098420.0150050.0037940.0021530.0118380.0003620.0006490.4563260.0248480.0193989.6280450.1810130.528697-1.3064370.0644800.4985220.0472285.072765
CAN480.4840.890.6145400.0858940.1282250.0659810.0368830.0684770.0713990.0162480.0012460.0009600.0023400.0003860.0008230.3753330.0080020.0093800.0164940.0007170.0030910.0060630.0057800.0006060.4250730.0233890.0199748.9743440.1902270.499546-1.2326740.0114080.4688240.0514875.190048
CAN500.5042.690.4296020.1212350.2091720.0926580.0630650.0842670.0416080.0041460.0088140.0005620.0008830.0003250.0006300.3409690.0106080.0081390.0123900.0004060.0037550.0114210.0000890.0003990.5120110.0214910.0147295.0980840.1220290.574293-1.4773420.1383910.5527520.0371324.801026
CAN520.5244.380.4240490.1114820.2138020.1094040.0609370.0803270.0573630.0046070.0078850.0007990.0013070.0001350.0006220.3678700.0148700.0099540.0164860.0008060.0039410.0102770.0003190.0007960.4374530.0410110.0182845.2790530.1559320.523585-1.3501000.0589410.4860580.0437975.003341
CAN540.5445.980.4389860.1203940.2197590.1020390.0489640.0698580.0621610.0050490.0081460.0007870.0014200.0002560.0006440.3564940.0121970.0104690.0149530.0016020.0039540.0112200.0002230.0007680.4438780.0443390.0166716.2839700.1743670.531620-1.3833680.0704820.4940800.0395644.950444
CAN560.5647.500.5778010.0994780.1747750.0740290.0353160.0386010.0731060.0069890.0086780.0008200.0016110.0002740.0007710.3778840.0137690.0124960.0177000.0021620.0036660.0092430.0018740.0011310.3746340.0680000.01975814.9684810.1934610.491736-1.2740050.0075280.4318270.0440035.124333
CAN580.5848.930.4945300.1052690.1680940.0695170.0674610.0951280.0617550.0049070.0073700.0006750.0013650.0001740.0005760.3638050.0147450.0092040.0085390.0084260.0036670.0076180.0032260.0006990.4407000.0438610.0168485.1985640.1697490.531646-1.2606830.0655610.4883180.0441415.145514
CAN600.6050.300.5883990.1267780.1344560.0550190.0417020.0536460.0765580.0060920.0082590.0009580.0016710.0002170.0006010.3424710.0175830.0102790.0152720.0020030.0034640.0091270.0005770.0008890.4279080.0550210.01659010.9682360.2235450.529743-1.3004660.0718810.4812560.0534775.082259
CAN620.6251.590.5813270.1004670.1382510.0601190.0493800.0704550.0829480.0054980.0088540.0007460.0016540.0002350.0007120.3858520.0239720.0109410.0150870.0022290.0036690.0092250.0016310.0008090.3842710.0416550.0145378.2510660.2149740.471802-1.260577-0.0149800.4258620.0591455.145682
CAN640.6452.820.6884910.0952240.1105580.0502600.0278160.0276510.1121430.0076670.0129710.0008000.0017870.0001910.0006260.3946060.0151440.0133920.0005050.0190440.0032690.0084320.0008640.0008550.3458640.0429550.01432824.8997270.2841900.438760-1.185482-0.0850330.3835320.0430755.265083
CAN660.6653.990.6941620.0994150.0986480.0459870.0307190.0310700.0964290.0069370.0108670.0007580.0016610.0001700.0006650.4247960.0130410.0099270.0161190.0023460.0030710.0095810.0003440.0007920.3367670.0436050.01516922.3420670.2270000.419687-1.357084-0.1113110.3747000.0369144.992237
CAN680.6855.100.6677890.1129070.1142880.0534520.0290820.0224820.1090750.0082330.0113120.0009660.0018500.0002640.0006610.4021160.0148870.0106030.0157970.0032360.0035100.0106340.0002680.0007560.3376360.0477080.01574029.7035220.2712530.427273-1.305709-0.0964900.3777270.0432705.073923
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