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Birlo, Stella; Wienhues, Giulia; Zahajská, Petra; Grosjean, Martin; García, María Luján; Zolitschka, Bernd (2024): Elemental pigment (hyperspectral imaging) data of the varved sediment record (HZM19) from Holzmaar, Germany [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.965927

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Published: 2024-11-14DOI registered: 2024-12-13

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Abstract:
Hyperspectral image (HSI) scanning of the composite record from Holzmaar (HZM19) was measured using a Specim PFD-CL-65-V10 E line scan camera (University of Bern, Switzerland). Data were processed using the ENVI software following the workflow of Butz et al. (2015, doi10.1117/1.JRS.9.096031): data were white-corrected, masked for cracks in the sediment surface and Relative Absorption Band Depths (RABDs) were computed for 2mm wide subsets. RABD671 (band depths from 640 to 702 nm) for Total Chloropigments-a (TChl-a), RABD845 (790 - 900 nm) for Bacteriopheopigments-a (Bphe-a), and RABD620 (600 - 640 nm) for Phycocyanin (PhyCy). To translate HSI indices into absolute concentrations, a pigment extraction was performed at the University of Bern using 23 samples covering the full range of RABD671 and RABD845 index values. Ca 1 g of wet sediment was treated with 100 % acetone following the method of Lami et al. (1994, doi:10.1007/BF00684032) and extractions were measured using a Shimadzu UV-1800 spectrophotometer to obtain bulk concentrations of TChl-a and Bphe-a in µg/g dry sediment using a molar extinction coefficient for TChl-a and Bphe-a. A proxy-proxy calibration was carried out using an ordinary least square regression. After all, only 1.42 % and 0.77 % of datapoints are outside of the calibration ranges for Chl-a (calibration range: 12.75 – 1202.68 µg/g, intercept = -4799.52, slope= 4756,45, r² = 0.8, p-val = 0.00, RMSEP 10-fold = 169.03, RMSEP % = 14.05) and Bphe-a (calibration range 0.38 – 345.12 µg/g, intercept = -1295,8, slope= 1319,7, r² = 0.94, p-val = 0.00, RMSEP 10-fold = 25.26, RMSEP % = 7.32). Ages refer to Birlo et al. (2023) and the related dataset is Model D available via doi:10.1594/PANGAEA.949292.
Keyword(s):
Eifel; Holzmaar; HSI; Pigments; XRF
Supplement to:
García, María Luján; Birlo, Stella; Zahajská, Petra; Wienhues, Giulia; Grosjean, Martin; Zolitschka, Bernd (2024): Ecological responses to solar forcing during the Homerian Climate Anomaly recorded by varved sediments from Holzmaar, Germany. The Holocene, 09596836241275008, https://doi.org/10.1177/09596836241275008
Coverage:
Latitude: 50.116670 * Longitude: 6.883333
Date/Time Start: 2019-08-11T00:00:00 * Date/Time End: 2019-08-17T00:00:00
Minimum Elevation: 425.0 m * Maximum Elevation: 425.0 m
Event(s):
HZM19 * Latitude: 50.116670 * Longitude: 6.883333 * Date/Time Start: 2019-08-11T00:00:00 * Date/Time End: 2019-08-17T00:00:00 * Elevation: 425.0 m * Penetration: 14.50 m * Location: Holzmaar, West-Eifel Volcanic Field, Germany * Method/Device: Piston corer, UWITEC (PCUWI)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Core section labelSec labelBirlo, Stella
2Section positionSectmmBirlo, Stella
3Depth, compositeDepth compmcdBirlo, Stella
4Calendar age, meanCal age meanka BPBirlo, StellaCalculated, based on VT22 (Birlo et al., 2023)Model D
5Calendar age, minimum/youngCal age minka BPBirlo, StellaCalculated, based on VT22 (Birlo et al., 2023)Model D
6Calendar age, maximum/oldCal age maxka BPBirlo, StellaCalculated, based on VT22 (Birlo et al., 2023)Model D
7Relative absorption band depth, 620 nmRABD620Birlo, StellaMeasured
8Relative absorption band depth, 671 nmRABD671Birlo, StellaMeasured
9Relative absorption band depth, 845 nmRABD845Birlo, StellaMeasured
10Chloropigments, per unit sediment massChloropigm/sedµg/gBirlo, StellaHSI index, calibratedTotal
11Bacteriopheopigments, per unit sediment massBacteriopheopig/sedµg/gBirlo, Stella
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
1415832 data points

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