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Martyn Rosco, Melanie; Dean, Joshua F; Meisel, Ove H.; van Logtestijn, Richard; Lambert, Thibault; Materić, Dušan; Karsanaev, Sergei; Maximov, Trofim C; Vonk, Jorien E; Weedon, James T: Dissolved organic matter (DOM) composition and dissolved greenhouse gas concentrations (CO₂, CH₄, N₂O) in Arctic freshwater ecosystems, NE Siberia (2016–2017) [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.993666 (dataset in review)

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Abstract:
This dataset contains measurements of dissolved organic matter (DOM) composition and dissolved greenhouse gas concentrations (carbon dioxide (CO₂), methane (CH₄), and nitrous oxide (N₂O)) collected from freshwater ecosystems in the Kytalyk Nature Reserve, northeastern Siberia, during the summer months of July–August 2016 and July 2017. Samples were obtained from a range of aquatic environments, including ponds, lakes, and fluvial systems, representing spatial variability across an Arctic tundra landscape underlain by continuous permafrost. The dataset includes dissolved organic carbon (DOC) concentrations, stable carbon isotope composition of DOC (δ¹³C-DOC), optical properties of chromophoric and fluorescent DOM derived from absorbance and excitation–emission matrix spectroscopy, and environmental parameters such as water temperature, pH, specific conductivity, and dissolved iron (Fe). Dissolved gas concentrations were determined using headspace equilibration followed by gas chromatography. Optical DOM indices include absorbance coefficients, spectral slopes, and fluorescence-based indices derived from parallel factor analysis. A subset of samples (n = 11) was analyzed using thermal desorption proton transfer reaction mass spectrometry to characterize DOM molecular composition. These data include bulk molecular metrics (e.g. hydrogen-to-carbon and oxygen-to-carbon ratios, average carbon number, and oxidative state of carbon) and relative contributions of compound classes such as aliphatics, aromatics, and highly unsaturated compounds. The data were collected to characterize DOM composition and dissolved greenhouse gas concentrations across different freshwater ecosystem types in an Arctic permafrost region and to support analyses of spatial variability in biogeochemical properties. The dataset provides a comprehensive set of physicochemical and spectroscopic measurements for use in studies of carbon and nitrogen cycling in Arctic freshwater systems.
Related to:
Rosco, Melanie Martyn (submitted): Distinctive DOM patterns coupled to CO₂, CH₄ and N₂O concentrations across freshwater ecosystems in the NE Siberian Arctic tundra. Biogeosciences
Coverage:
Median Latitude: 70.812430 * Median Longitude: 147.440019 * South-bound Latitude: 70.493348 * West-bound Longitude: 147.293631 * North-bound Latitude: 70.849270 * East-bound Longitude: 147.517610
Date/Time Start: 2016-07-31T00:00:00 * Date/Time End: 2017-07-17T00:00:00
Event(s):
2016_F05 * Latitude: 70.831670 * Longitude: 147.517290 * Date/Time Start: 2016-08-01T00:00:00 * Date/Time End: 2016-08-08T00:00:00 * Comment: Fluvial site
2016_F06 * Latitude: 70.831380 * Longitude: 147.517610 * Date/Time Start: 2016-08-01T00:00:00 * Date/Time End: 2016-08-08T00:00:00 * Comment: Fluvial site
2016_F07 * Latitude: 70.829970 * Longitude: 147.511840 * Date/Time Start: 2016-08-01T00:00:00 * Date/Time End: 2016-08-08T00:00:00 * Comment: Fluvial site
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventMartyn Rosco, Melanie
2SiteSiteMartyn Rosco, Melanie
3DATE/TIMEDate/TimeMartyn Rosco, MelanieGeocode
4AreaAream2Martyn Rosco, Melanie
5Temperature, waterTemp°CMartyn Rosco, Melanie
6pHpHMartyn Rosco, Melanie
7ConductivityCondµS/cmMartyn Rosco, Melanie
8Carbon dioxide, dissolvedCO2 dissµmol/lMartyn Rosco, MelanieGas chromatograph (8610C, SRI Instruments, Torrance, USA)
9Methane, dissolvedCH4 dissµmol/lMartyn Rosco, MelanieGas chromatograph (8610C, SRI Instruments, Torrance, USA)
10Nitrous oxideN2Oµmol/lMartyn Rosco, MelanieGas chromatograph (8610C, SRI Instruments, Torrance, USA)
11Carbon, organic, dissolvedDOCµmol/lMartyn Rosco, MelanieTotal organic carbon analyzer, Aurora 1030, OI Analytical
12δ13C, dissolved organic carbonδ13C DOC‰ PDBMartyn Rosco, MelanieIsotope ratio mass spectrometry (IRMS), Thermo Scientific, Delta V Plus
13Absorption coefficient, 350 nmac3501/mMartyn Rosco, MelanieUV/VIS Spectrophotometer, PerkinElmer, Lambda 650
14Specific ultraviolet absorbance normalized to DOC, 254 nm, per mass carbonSUVA254l/mg/mMartyn Rosco, MelanieUV/VIS Spectrophotometer, PerkinElmer, Lambda 650
15Absorbance ratioAbsorbance ratioMartyn Rosco, MelanieUV/VIS Spectrophotometer, PerkinElmer, Lambda 650250:365 nm
16Spectral slope of colored dissolved organic matter absorption, 275-295 nmS275-2951/nmMartyn Rosco, MelanieUV/VIS Spectrophotometer, PerkinElmer, Lambda 650
17Spectral slope of colored dissolved organic matter absorption, 350-400 nmS350-4001/nmMartyn Rosco, MelanieUV/VIS Spectrophotometer, PerkinElmer, Lambda 650
18Spectral slope of colored dissolved organic matter absorption ratioSDOM ratioMartyn Rosco, MelanieUV/VIS Spectrophotometer, PerkinElmer, Lambda 650
19Fluorescence intensityFluorescenceMartyn Rosco, Melanietotal
20AbundanceAbund%Martyn Rosco, Melanieof component C1; relative
21AbundanceAbund%Martyn Rosco, Melanieof component C2; relative
22AbundanceAbund%Martyn Rosco, Melanieof component C3; relative
23AbundanceAbund%Martyn Rosco, Melanieof component C4; relative
24AbundanceAbund%Martyn Rosco, Melanieof component C5; relative
25Fluorescence indexFIMartyn Rosco, MelanieParallel factor analysis (PARAFAC)
26Freshness indexFIXMartyn Rosco, MelanieParallel factor analysis (PARAFAC)
27Humification indexHIXMartyn Rosco, MelanieParallel factor analysis (PARAFAC)
28Iron, dissolvedFe dissmg/lMartyn Rosco, MelanieInductively Coupled Plasma Mass Spectrometer, Agilent 7700X
29Carbon, organic, dissolvedDOC%Martyn Rosco, MelanieProton transfer reaction mass spectrometry, TD-PTR-MS PTR-TOF 8000, Ionicon Analitik, Austria (PTR-MS)
30Hydrogen/Carbon ratioH/CMartyn Rosco, Melanie
31Oxygen/Carbon ratioO/CMartyn Rosco, Melanie
32Carbon, number of atomsC atoms#Martyn Rosco, Melanieaverage
33Carbon, nominal oxidation stateNOSCMartyn Rosco, Melanie
34Ion, organicIon organng/lMartyn Rosco, Melanie
35AbundanceAbund%Martyn Rosco, Melanieother components; relative
36AbundanceAbund%Martyn Rosco, Melaniealipharics; relative
37Aromatic compoundsAC%Martyn Rosco, Melanierelative abundance
38AbundanceAbund%Martyn Rosco, Melaniecondensed aromatics; relative
39Highly unsaturated compoundsHighly unsat comp%Martyn Rosco, Melaniehigh O/C; relative abundance
40Highly unsaturated compoundsHighly unsat comp%Martyn Rosco, Melanielow O/C; relative abundance
41AbundanceAbund%Martyn Rosco, Melaniepeptides; relative
42SugarsSugar%Martyn Rosco, Melanierelative abundance
43Chemodiversity indexChemodiv indexMartyn Rosco, Melanie
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
2472 data points

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