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Bhattacharya, Tripti; Fastovich, David; Maupin, Christopher; Thompson, Alexandra; Feng, Ran; Zhu, Jiang; McClymont, Erin L; Bong, Hayoung; LeGrande, Allegra N; Dee, Sylvia G; Fiorella, Richard (2026): Modern coretop leaf wax hydrogen and carbon isotopes from west coast of North America [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.993439

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Published: 2026-04-14DOI registered: 2026-05-13

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Abstract:
This dataset consists of hydrogen (δD) and carbon isotope (δ13C) measurements of long-chain leaf wax n-acids from core tops (e.g. recent sediments) off the coast of western North America, spanning a latitudinal range of 20 to 60 degrees north. The dataset also includes chain length metrics like average chain length and carbon preference index. These data were collected to evaluate the degree of correlation between modern sedimentary leaf wax hydrogen isotopes and observed precipitation isotopes in a latitudinal range of 20 to 60 degrees north along the coast of western North America. Second, the data were collected to evaluate whether leaf wax hydrogen and carbon isotopes reflect large-scale gradients in ecological and climatological variables. Samples were processed by standard methods for biomarker extraction, purification and quantification, and isotopes were measured via gas chromatograph-isotope ratio mass spectrometry. Results of this study showed that a major transition in leaf wax hydrogen isotopic composition occurs at the latitude of the east Pacific storm track.
Keyword(s):
carbon isotope; compound-specific biomarker isotopes; hydrogen isotope; Leaf wax; North Pacific; western North America
Supplement to:
Bhattacharya, Tripti; Fastovich, David; Maupin, Christopher; Thompson, Alexandra; Feng, Ran; Zhu, Jiang; McClymont, Erin L; Bong, Hayoung; LeGrande, Allegra N; Dee, Sylvia G; Fiorella, Richard (accepted): Leaf wax hydrogen isotopes reflect storm track position over western North America. Paleoceanography and Paleoclimatology
Funding:
Alfred P. Sloan Foundation, grant/award no. FG-2023-20259: Understanding Pliocene Hydroclimate
National Science Foundation (NSF), grant/award no. AGS-2303568: Collaborative Research: Reducing Model Uncertainty by Improving Understanding of Pacific Meridional Climate Structure during Past Warm Intervals
National Science Foundation (NSF), grant/award no. OCE-2237502: Biomarker perspectives on the sensitivity of western North American precipitation to climate change
Coverage:
Median Latitude: 40.755256 * Median Longitude: -123.600147 * South-bound Latitude: 23.110000 * West-bound Longitude: -143.150000 * North-bound Latitude: 59.183000 * East-bound Longitude: -110.190000
Date/Time Start: 1961-08-02T00:00:00 * Date/Time End: 2004-08-29T00:00:00
Minimum Elevation: -3455.0 m * Maximum Elevation: -3.0 m
Event(s):
BAP-82-096-GC * Latitude: 25.268000 * Longitude: -112.268000 * Date/Time: 1982-06-03T00:00:00 * Elevation: -480.0 m * Method/Device: Gravity corer (GC)
BB291-019-PG-GC * Latitude: 46.822000 * Longitude: -124.605000 * Date/Time: 1961-08-02T00:00:00 * Elevation: -112.0 m * Method/Device: Gravity corer (GC)
BB291-034-034 * Latitude: 43.495000 * Longitude: -124.700000 * Date/Time: 1961-08-06T00:00:00 * Elevation: -585.0 m * Method/Device: Gravity corer (GC)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventBhattacharya, TriptiLabel used at repository for each core
2Depth, top/minDepth topmBhattacharya, TriptiIn sample
3Depth, bottom/maxDepth botmBhattacharya, TriptiIn sample
4Sample repositorySample repositoryBhattacharya, TriptiLocation where each core is presently stored/location from which each sample was requested
5Sample typeSamp typeBhattacharya, TriptiDevice used to sample each core originaly
6n-Alkanoic acid C28, δDC28 Alk Acid δD‰ SMOWBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
7n-Alkanoic acid C28, δD, analytical errorC28 Alk Acid δD analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
8n-Alkanoic acid C30, δDC30 Alk Acid δD‰ SMOWBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
9n-Alkanoic acid C30, δD, analytical errorC30 Alk Acid δD analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
10n-Alkanoic acid C32, δDC32 Alk Acid δD‰ SMOWBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
11n-Alkanoic acid C32, δD, analytical errorC32 Alk Acid δD analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
12n-Alkanoic acid C28, δ13CC28 Alk Acid δ13C‰ PDBBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
13n-Alkanoic acid C28, δ13C, analytical errorC28 Alk Acid δ13C analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
14n-Alkanoic acid C30, δ13CC30 Alk Acid δ13C‰ PDBBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
15n-Alkanoic acid C30, δ13C, analytical errorC30 Alk Acid δ13C analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
16n-Alkanoic acid C32, δ13CC32 Alk Acid δ13C‰ PDBBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
17n-Alkanoic acid C32, δ13C, analytical errorC32 Alk Acid δ13C analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
18Carbon Preference IndexCPIBhattacharya, TriptiGas chromatography - Flame Ionization Detection (GC-FID), Thermo Scientific, Trace 1310
19Average chain lengthACLBhattacharya, TriptiGas chromatography - Flame Ionization Detection (GC-FID), Thermo Scientific, Trace 1310
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
443 data points

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