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Bhattacharya, Tripti; Fastovich, David; Maupin, Christopher; Thompson, Alexandra; Feng, Ran; Zhu, Jiang; McClymont, Erin L; Bong, Hayoung; LeGrande, Allegra N; Dee, Sylvia G; Fiorella, Richard (2026): Modern coretop leaf wax hydrogen and carbon isotopes from west coast of North America [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.993439

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Published: 2026-04-14DOI registered: 2026-05-13

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Abstract:
This dataset consists of hydrogen (δD) and carbon isotope (δ13C) measurements of long-chain leaf wax n-acids from core tops (e.g. recent sediments) off the coast of western North America, spanning a latitudinal range of 20 to 60 degrees north. The dataset also includes chain length metrics like average chain length and carbon preference index. These data were collected to evaluate the degree of correlation between modern sedimentary leaf wax hydrogen isotopes and observed precipitation isotopes in a latitudinal range of 20 to 60 degrees north along the coast of western North America. Second, the data were collected to evaluate whether leaf wax hydrogen and carbon isotopes reflect large-scale gradients in ecological and climatological variables. Samples were processed by standard methods for biomarker extraction, purification and quantification, and isotopes were measured via gas chromatograph-isotope ratio mass spectrometry. Results of this study showed that a major transition in leaf wax hydrogen isotopic composition occurs at the latitude of the east Pacific storm track.
Keyword(s):
carbon isotope; compound-specific biomarker isotopes; hydrogen isotope; Leaf wax; North Pacific; western North America
Supplement to:
Bhattacharya, Tripti; Fastovich, David; Maupin, Christopher; Thompson, Alexandra; Feng, Ran; Zhu, Jiang; McClymont, Erin L; Bong, Hayoung; LeGrande, Allegra N; Dee, Sylvia G; Fiorella, Richard (accepted): Leaf wax hydrogen isotopes reflect storm track position over western North America. Paleoceanography and Paleoclimatology
Funding:
Alfred P. Sloan Foundation, grant/award no. FG-2023-20259: Understanding Pliocene Hydroclimate
National Science Foundation (NSF), grant/award no. AGS-2303568: Collaborative Research: Reducing Model Uncertainty by Improving Understanding of Pacific Meridional Climate Structure during Past Warm Intervals
National Science Foundation (NSF), grant/award no. OCE-2237502: Biomarker perspectives on the sensitivity of western North American precipitation to climate change
Coverage:
Median Latitude: 40.755256 * Median Longitude: -123.600147 * South-bound Latitude: 23.110000 * West-bound Longitude: -143.150000 * North-bound Latitude: 59.183000 * East-bound Longitude: -110.190000
Date/Time Start: 1961-08-02T00:00:00 * Date/Time End: 2004-08-29T00:00:00
Minimum Elevation: -3455.0 m * Maximum Elevation: -3.0 m
Event(s):
BAP-82-096-GC  * Latitude: 25.268000 * Longitude: -112.268000 * Date/Time: 1982-06-03T00:00:00 * Elevation: -480.0 m * Method/Device: Gravity corer (GC)
BB291-019-PG-GC  * Latitude: 46.822000 * Longitude: -124.605000 * Date/Time: 1961-08-02T00:00:00 * Elevation: -112.0 m * Method/Device: Gravity corer (GC)
BB291-034-034  * Latitude: 43.495000 * Longitude: -124.700000 * Date/Time: 1961-08-06T00:00:00 * Elevation: -585.0 m * Method/Device: Gravity corer (GC)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Event labelEventBhattacharya, TriptiLabel used at repository for each core
Depth, top/minDepth topmBhattacharya, TriptiIn sample
Depth, bottom/maxDepth botmBhattacharya, TriptiIn sample
Sample repositorySample repositoryBhattacharya, TriptiLocation where each core is presently stored/location from which each sample was requested
Sample typeSamp typeBhattacharya, TriptiDevice used to sample each core originaly
n-Alkanoic acid C28, δDC28 Alk Acid δD‰ SMOWBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
n-Alkanoic acid C28, δD, analytical errorC28 Alk Acid δD analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
n-Alkanoic acid C30, δDC30 Alk Acid δD‰ SMOWBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
n-Alkanoic acid C30, δD, analytical errorC30 Alk Acid δD analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
10 n-Alkanoic acid C32, δDC32 Alk Acid δD‰ SMOWBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
11 n-Alkanoic acid C32, δD, analytical errorC32 Alk Acid δD analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
12 n-Alkanoic acid C28, δ13CC28 Alk Acid δ13C‰ PDBBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
13 n-Alkanoic acid C28, δ13C, analytical errorC28 Alk Acid δ13C analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
14 n-Alkanoic acid C30, δ13CC30 Alk Acid δ13C‰ PDBBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
15 n-Alkanoic acid C30, δ13C, analytical errorC30 Alk Acid δ13C analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
16 n-Alkanoic acid C32, δ13CC32 Alk Acid δ13C‰ PDBBhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
17 n-Alkanoic acid C32, δ13C, analytical errorC32 Alk Acid δ13C analytical e±Bhattacharya, TriptiGas chromatography - isotope ratio mass spectrometry (GC-IRMS), Thermo Fisher Scientific, DELTA V Plus
18 Carbon Preference IndexCPIBhattacharya, TriptiGas chromatography - Flame Ionization Detection (GC-FID), Thermo Scientific, Trace 1310
19 Average chain lengthACLBhattacharya, TriptiGas chromatography - Flame Ionization Detection (GC-FID), Thermo Scientific, Trace 1310
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
443 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Event

Depth top [m]

Depth bot [m]

Sample repository

Samp type

C28 Alk Acid δD [‰ SMOW]

C28 Alk Acid δD analytical e [±]

C30 Alk Acid δD [‰ SMOW]

C30 Alk Acid δD analytical e [±]
10 
C32 Alk Acid δD [‰ SMOW]
11 
C32 Alk Acid δD analytical e [±]
12 
C28 Alk Acid δ13C [‰ PDB]
13 
C28 Alk Acid δ13C analytical e [±]
14 
C30 Alk Acid δ13C [‰ PDB]
15 
C30 Alk Acid δ13C analytical e [±]
16 
C32 Alk Acid δ13C [‰ PDB]
17 
C32 Alk Acid δ13C analytical e [±]
18 
CPI
19 
ACL
MV99-06-GC 00.02Lamont-Doherty Earth Observatorygravity core-112.31.6-127.41.0-100.62.0-25.30.1-28.30.3-27.60.35.226.1
NV871-04-GCA 00.02Lamont-Doherty Earth Observatorygravity core-101.10.7-129.20.4-26.30.2-30.40.1-30.30.16.026.7
NV924-09-GCA 00.02Lamont-Doherty Earth Observatorygravity core-152.20.9-146.90.4-148.41.2-31.60.1-32.40.1-32.90.44.926.5
NV899-07-GC 00.02Lamont-Doherty Earth Observatorygravity core-119.52.3-139.90.3-125.70.8-29.40.1-31.60.1-31.80.15.226.5
MV99-18-GC 00.02Lamont-Doherty Earth Observatorygravity core-132.31.4-131.70.5-136.01.1-24.50.2-27.60.1-28.20.06.126.8
MV99-29-GC 00.02Lamont-Doherty Earth Observatorygravity core-125.00.6-126.31.7-129.00.6-27.50.1-30.30.1-30.30.14.926.2
MV99-35-GC 00.02Lamont-Doherty Earth Observatorygravity core-130.80.8-130.93.0-138.31.8-25.00.0-28.20.1-28.60.16.326.9
NV896-30-GCA 00.02Lamont-Doherty Earth Observatorygravity core-140.31.5-135.90.7-137.61.3-31.40.2-32.70.1-33.20.15.226.1
NV899_05_GC 00.02Lamont-Doherty Earth Observatorygravity core-127.60.1-140.20.4-142.50.0-30.60.3-32.20.1-32.50.35.226.5
MV99-08 00.02Lamont-Doherty Earth Observatorypiston core-118.71.6-133.12.5-141.02.16.826.6
NV924-19 00.02Lamont-Doherty Earth Observatorygravity core-118.03.7-134.40.7-145.30.7-29.00.1-31.40.1-30.70.16.426.8
MV99_09 00.02Lamont-Doherty Earth Observatorygravity core-118.62.8-128.90.8-149.34.4-24.20.0-26.90.1-27.40.34.926.3
HB9601 00.02Lamont-Doherty Earth Observatorygravity core-158.30.7-177.11.7-132.02.2-30.70.1-31.70.1-32.00.26.526.3
NV912-05 00.02Lamont-Doherty Earth Observatorygravity core-150.10.8-164.91.4-161.43.05.426.6
NV982-02SS 00.02Lamont-Doherty Earth Observatorygrab-175.32.5-174.21.5-155.918.03.726.1
HB96-07-GC 00.02Lamont-Doherty Earth Observatorygravity core-149.70.8-160.50.2-146.30.46.326.4
NV967-9-SS 00.02Lamont-Doherty Earth Observatorygravity core-152.12.9-165.52.6-166.52.74.926.7
BB311-026-026-GC 00.02Oregon State Universitygravity core-142.71.5-150.30.1-147.03.5-31.60.2-32.70.1-33.00.15.526.1
Y6511-69-GC 00.02Oregon State Universitypiston core-115.40.8-169.82.6-149.20.25.325.9
RR0207-10GC 00.02Oregon State Universitygravity core-106.53.0-149.00.1-137.81.55.726.1
BB291-034-034 00.02Oregon State Universitygravity core-128.93.8-163.31.56.626.1
Y6506-134-GC 00.02Oregon State Universitygravity core
W7809C-34-GC 00.02Oregon State Universitygravity core-132.90.7-161.72.1-157.75.426.4
Y6508-38-GC 00.02Oregon State Universitygravity core
BB291-019-PG-GC 00.02Oregon State Universitygravity core
BB312-019-019 00.02Oregon State Universitygravity core-181.70.8-183.42.3-177.31.3-31.90.2-32.40.1-33.00.15.326.1
TT090-042-009-GC 00.02Oregon State Universitygravity core-182.40.4-184.00.4-181.83.0-31.20.3-31.70.3-31.80.25.427.1
BAP-82-096-GC 00.02Oregon State Universitygravity core-114.12.9-131.53.3-112.22.16.126.4
EW0408-20-GC 00.02Oregon State Universitygravity core-145.90.7-173.12.7-161.05.15.526.1
EW0408-08-GC 00.02Oregon State Universitygravity core-154.81.6-174.42.9-161.50.4-29.10.3-31.40.2-31.00.15.326.3
LPFG01ST-039-G 00.02Scripps Institute of Oceanographygravity core
LPFG01ST-035-G 00.02Scripps Institute of Oceanographygravity core
LPFG01ST-030-G 00.02Scripps Institute of Oceanographygravity core
LPFG01ST-026G 00.02Scripps Institute of Oceanographygravity core