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Liao, Jin; Day, Christopher (2026): Calcium isotopes (δ44Ca) of stalagmite HS4 in Heshang Cave, Central China [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.992726 (DOI registration in progress)

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Published: 2026-03-16

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Abstract:
Stalagmite calcium (d44Ca) isotope data was used to reconstruct regional paleorainfall amount in the Central China between 4.6 kyr BP and 3.5 kyr BP. The stalagmite (HS4) was collected from Heshang Cave in the Middle Yangtze Valley, Central China (30º27′N, 110º25′E, 294 m.a.s.l). HS4 Stalagmite length in this study ranges between 112.63 and 151.03 cm. The working half of HS4 was slabbed. Micro drilling of 343 continuous samples was undertaken by using a New-Wave Micromill. Every eighth sample was measured for d44Ca. The measurement resolution is ~25 years. The data was measured using a Nu Instruments multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS) at the University of Oxford, Department of Earth Sciences in 2016.
Keyword(s):
Archaeological cultures; Calcium isotopes; Central China; speleothem; trace elements
Related to:
Liao, Jin; Day, Christopher; Hu, Chaoyong; Liu, Y; Henderson, Gideon M (2026): Precise chronology of hydrological changes at ∼4.2 kyr in Central China to assess the impact of flooding on Neolithic societies. National Science Review, 13(2), nwaf567, https://doi.org/10.1093/nsr/nwaf567
References:
Owen, R A; Day, C C; Hu, C-Y; Liu, Y-H; Pointing, M D; Blättler, Clara L; Henderson, G M (2016): Calcium isotopes in caves as a proxy for aridity: Modern calibration and application to the 8.2 kyr event. Earth and Planetary Science Letters, 443, 129-138, https://doi.org/10.1016/j.epsl.2016.03.027
Funding:
National Natural Science Foundation of China (NSFC), grant/award no. 41731177
National Natural Science Foundation of China (NSFC), grant/award no. 41902185
Coverage:
Latitude: 30.450000 * Longitude: 110.416700
Minimum DISTANCE: 115.70 cm * Maximum DISTANCE: 147.06 cm
Event(s):
Heshang_Cave_HS4 * Latitude: 30.450000 * Longitude: 110.416700 * Elevation: 294.0 m * Location: Yangtze Valley, Central China * Method/Device: Speleothem sample (SPS)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Sample numberSample noLiao, Jin
2AGEAgeka BPLiao, JinAge, Uranium-ThoriumGeocode – Measured with: Multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS), Nu Instruments, Plasma
3Age, errorAge e±Liao, JinAge, 14C calibration OxCal (Ramsey, 2008)2 standard deviation (2SD), 2 sigma
4DISTANCEDistancecmLiao, JinMeasuredGeocode – From top of HS4
5δ44/42 Caδ44/40 CaLiao, JinInductively coupled plasma mass spectrometer (ICP-MS), Attom, Nu InstrumentsWith respect to NIST SRM 915A
6δ44/42 Ca, errorδ44/40 Ca e±Liao, JinCalculated, 2 standard deviation (2SD)With respect to NIST SRM 915A; 2 sigma
7Rayleigh fractional model, crystallizationfLiao, JinAccording to Owen et al. (2016)Fraction of dissolved Ca remaining in solution
8Rayleigh fractional model, crystallization, errorf e±Liao, JinCalculated, 2 standard deviation (2SD)Fraction of dissolved Ca remaining in solution; 2 sigma
9Precipitation, annual totalPrecip annual totmm/aLiao, JinAccording to Owen et al. (2016)Derived rainfall calculated by the fraction of dissolved Ca remaining in solution
10Precipitation, annual total, errorPrecip annual total e±Liao, JinCalculated, 2 standard deviation (2SD)Derived rainfall calculated by the fraction of dissolved Ca remaining in solution; 2 sigma
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
344 data points

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