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Benaltabet, Tal; Gosnell, Kathleen; de Souza, Gregory F; Jasinski, Dominik; Rickli, Jörg Dominik; O'Sullivan, Edel Mary; Steiner, Zvi; Achterberg, Eric Pieter; Vance, Derek (2026): Zn and Pb isotope compositions and elemental ratios in aerosols from the South Pacific Ocean during SONNE cruise SO289 (GEOTRACES section GP21) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.991542

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Published: 2026-03-02DOI registered: 2026-03-31

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Abstract:
This dataset contains Zn and Pb isotope compositions (δ66Zn, 206Pb/207Pb, 208Pb/206Pb) and elemental ratios (Zn/P, Zn/Al, Zn/Mn, Pb/Al) in marine particles and aerosols (labile and refractory fractions) from the South Pacific Ocean samples collected during the SONNE cruise SO289 (GEOTRACES section GP21; February 23 - April 4, 2022). Seawater (6-8 L) was collected using trace metal clean Niskin bottles and subsequently filtered through 0.2 µm pore size filters to collect marine particles. Atmospheric aerosols (> PM 10) were collected using a high-volume aerosol collector for 48 – 72 hour intervals.
Labile particulate phases in marine particles and aerosols were extracted using a mild acetic acid + hydroxylamine hydrochloride leach (Berger et al., 2008). Refractory particulate phases were digested using a HNO3-HF mixture (Al-Hashem et al., 2022). Samples were analyzed for elemental abundances using an Element XR high-resolution ICP-MS. Samples for Zn and Pb isotope analysis were purified by column chromatography (Bermin et al., 2006; Lugmair & Galer, 1992) and measured on a Neptune Plus multi-collector ICP-MS.
Keyword(s):
aerosols; anthropogenic tracers; GEOTRACES; Marine particles; Pb isotopes; South Pacific Ocean; Zn isotope
Related to:
Al-Hashem, Ali A; Beck, A J; Krisch, Stephan; Menzel Barraqueta, Jan-Lukas; Steffens, Tim; Achterberg, Eric Pieter (accepted): Particulate Trace Metal Sources, Cycling, and Distributions on the Southwest African Shelf. Global Biogeochemical Cycles, 36(11), https://doi.org/10.1029/2022GB007453
Berger, Carolyn J M; Lippiatt, Sherry M; Lawrence, Michael G; Bruland, Kenneth W (2008): Application of a chemical leach technique for estimating labile particulate aluminum, iron, and manganese in the Columbia River plume and coastal waters off Oregon and Washington. Journal of Geophysical Research: Oceans, 113(C2), 2007JC004703, https://doi.org/10.1029/2007JC004703
Bermin, J; Vance, Derek; Archer, Corey; Statham, P J (2006): The determination of the isotopic composition of Cu and Zn in seawater. Chemical Geology, 226(3-4), 280-297, https://doi.org/10.1016/j.chemgeo.2005.09.025
Lugmair, G W; Galer, Stephen J G (1992): Age and isotopic relationships among the angrites Lewis Cliff 86010 and Angra dos Reis. Geochimica et Cosmochimica Acta, 56(4), 1673-1694, https://doi.org/10.1016/0016-7037(92)90234-A
Coverage:
Median Latitude: -31.250000 * Median Longitude: -122.550000 * South-bound Latitude: -36.700000 * West-bound Longitude: -172.000000 * North-bound Latitude: -25.800000 * East-bound Longitude: -73.100000
Date/Time Start: 2022-02-22T00:00:00 * Date/Time End: 2022-03-31T00:00:00
Event(s):
SO289_0_Underway-8 (GP21-aerosols) * Latitude Start: -36.700000 * Longitude Start: -73.100000 * Latitude End: -25.800000 * Longitude End: -172.000000 * Date/Time Start: 2022-02-22T00:00:00 * Date/Time End: 2022-03-03T00:00:00 * Campaign: SO289 (GEOTRACES GP21) * Basis: Sonne_2 * Method/Device: Aerosol sampler (AEROS)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample code/labelSample labelBenaltabet, Tal
DATE/TIMEDate/TimeBenaltabet, TalGeocode – start
DATE/TIMEDate/TimeBenaltabet, TalGeocode – end
LATITUDELatitudeBenaltabet, TalGeocode – start
LATITUDELatitudeBenaltabet, TalGeocode – end
LONGITUDELongitudeBenaltabet, TalGeocode – start
LONGITUDELongitudeBenaltabet, TalGeocode – end
AluminiumAlng/m3Benaltabet, Tallabile
AluminiumAlng/m3Benaltabet, Talrefractory
10 AluminiumAlng/m3Benaltabet, Talbulk
11 ManganeseMnng/m3Benaltabet, Tallabile
12 ManganeseMnng/m3Benaltabet, Talrefractory
13 ManganeseMnng/m3Benaltabet, Talbulk
14 ZincZnng/m3Benaltabet, Tallabile
15 ZincZnng/m3Benaltabet, Talrefractory
16 ZincZnng/m3Benaltabet, Talbulk
17 LeadPbng/m3Benaltabet, Tallabile
18 LeadPbng/m3Benaltabet, Talrefractory
19 LeadPbng/m3Benaltabet, TalPb bulk (ng/m3)
20 δ66Znδ66ZnBenaltabet, Tallabile
21 δ66Zn, standard deviationδ66Zn std dev±Benaltabet, Tallabile
22 δ66Znδ66ZnBenaltabet, Talrefractory
23 δ66Zn, standard deviationδ66Zn std dev±Benaltabet, Talrefractory
24 Lead-206/Lead-207 ratio206Pb/207PbBenaltabet, Tallabile
25 Lead-206/Lead-207 ratio, error206Pb/207Pb e±Benaltabet, Tallabile
26 Lead-206/Lead-207 ratio206Pb/207PbBenaltabet, Talrefractory
27 Lead-206/Lead-207 ratio, error206Pb/207Pb e±Benaltabet, Talrefractory
28 Lead-208/Lead-206 ratio208Pb/206PbBenaltabet, Tallabile
29 Lead-208/Lead-206 ratio, error208Pb/206Pb e±Benaltabet, Tallabile
30 Lead-208/Lead-206 ratio208Pb/206PbBenaltabet, Talrefractory
31 Lead-208/Lead-206 ratio, error208Pb/206Pb e±Benaltabet, Talrefractory
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
282 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Sample label

Date/Time
(start)

Date/Time
(end)

Latitude
(start)

Latitude
(end)

Longitude
(start)

Longitude
(end)

Al [ng/m3]
(labile)

Al [ng/m3]
(refractory)
10 
Al [ng/m3]
(bulk)
11 
Mn [ng/m3]
(labile)
12 
Mn [ng/m3]
(refractory)
13 
Mn [ng/m3]
(bulk)
14 
Zn [ng/m3]
(labile)
15 
Zn [ng/m3]
(refractory)
16 
Zn [ng/m3]
(bulk)
17 
Pb [ng/m3]
(labile)
18 
Pb [ng/m3]
(refractory)
19 
Pb [ng/m3]
(Pb bulk (ng/m3))
20 
δ66Zn []
(labile)
21 
δ66Zn std dev [±]
(labile)
22 
δ66Zn []
(refractory)
23 
δ66Zn std dev [±]
(refractory)
24 
206Pb/207Pb
(labile)
25 
206Pb/207Pb e [±]
(labile)
26 
206Pb/207Pb
(refractory)
27 
206Pb/207Pb e [±]
(refractory)
28 
208Pb/206Pb
(labile)
29 
208Pb/206Pb e [±]
(labile)
30 
208Pb/206Pb
(refractory)
31 
208Pb/206Pb e [±]
(refractory)
BC12022-02-222022-02-24-36.7-32.5-73.1-72.05.573.178.60.620.711.340.70.51.20.1090.0820.191-0.120.04-0.050.041.17650.00051.17760.00052.08400.00012.08370.0001
BC22022-02-242022-02-26-32.5-32.5-72.0-76.631.076.5107.50.990.851.840.30.30.60.0220.0190.0410.320.040.210.041.17620.00051.18110.00052.08430.00012.08180.0001
BC32022-02-272022-02-28-32.5-32.5-79.0-82.00.80.80.010.020.030.60.41.00.0060.0030.0090.290.040.270.041.18980.00051.17610.00052.05650.00012.08130.0001
BC42022-03-022022-03-04-32.5-32.5-88.0-94.00.21.01.20.020.030.050.50.30.80.0070.0040.0110.250.040.210.041.21530.00051.21060.00052.01750.00012.02730.0001
492022-03-042022-03-06-32.5-32.5-94.0-100.00.40.40.010.000.010.70.51.20.0040.0030.0060.160.040.150.041.16080.00051.15310.00052.09630.00012.10910.0001
502022-03-062022-03-08-32.5-31.4-100.0-108.00.40.40.000.000.000.20.40.70.0010.0030.0040.260.040.230.041.14910.00051.15910.00052.12560.00012.10810.0001
B142022-03-082022-03-10-31.4-31.4-108.0-113.00.20.10.40.0010.0010.0020.130.040.180.041.11370.00052.17580.0001
512022-03-102022-03-12-31.4-31.4-113.0-119.00.50.50.000.010.011.21.32.40.0020.0030.0060.210.040.140.041.15550.00051.16530.00052.10810.00012.09360.0001
522022-03-122022-03-14-31.4-31.4-119.0-126.50.10.70.80.120.070.180.60.30.90.0230.0110.0340.120.040.150.041.16030.00051.15510.00052.09460.00012.10300.0001
532022-03-142022-03-18-31.4-31.4-128.0-138.00.70.70.010.010.011.31.42.70.0060.0050.0110.260.040.250.041.17740.00051.15150.00052.06180.00012.09600.0001
BA72022-03-182022-03-21-31.4-26.2-138.0-152.00.20.60.60.100.060.160.0070.0040.0120.140.040.130.041.16950.00051.16860.00052.08350.00012.08640.0001
BB42022-03-312022-03-03-25.9-25.8-177.2-172.00.10.90.90.010.020.030.30.20.50.0030.0020.0050.210.040.200.041.09800.00051.08620.00052.16990.00012.18930.0001