/* DATA DESCRIPTION: Citation: Benaltabet, Tal; Gosnell, Kathleen; de Souza, Gregory F; Jasinski, Dominik; Rickli, Jörg Dominik; O'Sullivan, Edel Mary; Steiner, Zvi; Achterberg, Eric Pieter; Vance, Derek (2026): Zn and Pb isotope compositions and elemental ratios in aerosols from the South Pacific Ocean during SONNE cruise SO289 (GEOTRACES section GP21) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.991542 Abstract: This dataset contains Zn and Pb isotope compositions (δ66Zn, 206Pb/207Pb, 208Pb/206Pb) and elemental ratios (Zn/P, Zn/Al, Zn/Mn, Pb/Al) in marine particles and aerosols (labile and refractory fractions) from the South Pacific Ocean samples collected during the SONNE cruise SO289 (GEOTRACES section GP21; February 23 - April 4, 2022). Seawater (6-8 L) was collected using trace metal clean Niskin bottles and subsequently filtered through 0.2 µm pore size filters to collect marine particles. Atmospheric aerosols (> PM 10) were collected using a high-volume aerosol collector for 48 – 72 hour intervals. Labile particulate phases in marine particles and aerosols were extracted using a mild acetic acid + hydroxylamine hydrochloride leach (Berger et al., 2008). Refractory particulate phases were digested using a HNO3-HF mixture (Al-Hashem et al., 2022). Samples were analyzed for elemental abundances using an Element XR high-resolution ICP-MS. Samples for Zn and Pb isotope analysis were purified by column chromatography (Bermin et al., 2006; Lugmair & Galer, 1992) and measured on a Neptune Plus multi-collector ICP-MS. Keyword(s): aerosols; anthropogenic tracers; GEOTRACES; Marine particles; Pb isotopes; South Pacific Ocean; Zn isotope Related to: Al-Hashem, Ali A; Beck, A J; Krisch, Stephan; Menzel Barraqueta, Jan-Lukas; Steffens, Tim; Achterberg, Eric Pieter (accepted): Particulate Trace Metal Sources, Cycling, and Distributions on the Southwest African Shelf. Global Biogeochemical Cycles, 36(11), https://doi.org/10.1029/2022GB007453 Berger, Carolyn J M; Lippiatt, Sherry M; Lawrence, Michael G; Bruland, Kenneth W (2008): Application of a chemical leach technique for estimating labile particulate aluminum, iron, and manganese in the Columbia River plume and coastal waters off Oregon and Washington. Journal of Geophysical Research: Oceans, 113(C2), 2007JC004703, https://doi.org/10.1029/2007JC004703 Bermin, J; Vance, Derek; Archer, Corey; Statham, P J (2006): The determination of the isotopic composition of Cu and Zn in seawater. Chemical Geology, 226(3-4), 280-297, https://doi.org/10.1016/j.chemgeo.2005.09.025 Lugmair, G W; Galer, Stephen J G (1992): Age and isotopic relationships among the angrites Lewis Cliff 86010 and Angra dos Reis. Geochimica et Cosmochimica Acta, 56(4), 1673-1694, https://doi.org/10.1016/0016-7037(92)90234-A Project(s): Global marine biogeochemical cycles of trace elements and their isotopes (GEOTRACES) (URI: https://www.geotraces.org/) Coverage: MEDIAN LATITUDE: -31.250000 * MEDIAN LONGITUDE: -122.550000 * SOUTH-BOUND LATITUDE: -36.700000 * WEST-BOUND LONGITUDE: -172.000000 * NORTH-BOUND LATITUDE: -25.800000 * EAST-BOUND LONGITUDE: -73.100000 DATE/TIME START: 2022-02-22T00:00:00 * DATE/TIME END: 2022-03-31T00:00:00 Event(s): SO289_0_Underway-8 (GP21-aerosols) * LATITUDE START: -36.700000 * LONGITUDE START: -73.100000 * LATITUDE END: -25.800000 * LONGITUDE END: -172.000000 * DATE/TIME START: 2022-02-22T00:00:00 * DATE/TIME END: 2022-03-03T00:00:00 * CAMPAIGN: SO289 (GEOTRACES GP21) * BASIS: Sonne_2 (URI: https://uol.de/icbm/forschungsplattformen-schiffe/sonne) * METHOD/DEVICE: Aerosol sampler (AEROS) Parameter(s): Sample code/label (Sample label) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) DATE/TIME (Date/Time) * GEOCODE * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: start DATE/TIME (Date/Time) * GEOCODE * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: end LATITUDE (Latitude) * GEOCODE * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: start LATITUDE (Latitude) * GEOCODE * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: end LONGITUDE (Longitude) * GEOCODE * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: start LONGITUDE (Longitude) * GEOCODE * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: end Aluminium [ng/m**3] (Al) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: labile Aluminium [ng/m**3] (Al) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: refractory Aluminium [ng/m**3] (Al) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: bulk Manganese [ng/m**3] (Mn) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: labile Manganese [ng/m**3] (Mn) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: refractory Manganese [ng/m**3] (Mn) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: bulk Zinc [ng/m**3] (Zn) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: labile Zinc [ng/m**3] (Zn) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: refractory Zinc [ng/m**3] (Zn) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: bulk Lead [ng/m**3] (Pb) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: labile Lead [ng/m**3] (Pb) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: refractory Lead [ng/m**3] (Pb) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: Pb bulk (ng/m3) δ66Zn [‰] (δ66Zn) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: labile δ66Zn, standard deviation [±] (δ66Zn std dev) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: labile δ66Zn [‰] (δ66Zn) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: refractory δ66Zn, standard deviation [±] (δ66Zn std dev) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: refractory Lead-206/Lead-207 ratio (206Pb/207Pb) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: labile Lead-206/Lead-207 ratio, error [±] (206Pb/207Pb e) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: labile Lead-206/Lead-207 ratio (206Pb/207Pb) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: refractory Lead-206/Lead-207 ratio, error [±] (206Pb/207Pb e) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: refractory Lead-208/Lead-206 ratio (208Pb/206Pb) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: labile Lead-208/Lead-206 ratio, error [±] (208Pb/206Pb e) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: labile Lead-208/Lead-206 ratio (208Pb/206Pb) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: refractory Lead-208/Lead-206 ratio, error [±] (208Pb/206Pb e) * PI: Benaltabet, Tal (https://orcid.org/0000-0002-4236-9880) * COMMENT: refractory License: Creative Commons Attribution 4.0 International (CC-BY-4.0) (URI: https://creativecommons.org/licenses/by/4.0/) Status: Curation Level: Enhanced curation (URI: https://wiki.pangaea.de/wiki/Curation_levels) Size: 282 data points */ Sample label Date/Time (start) Date/Time (end) Latitude (start) Latitude (end) Longitude (start) Longitude (end) Al [ng/m**3] (labile) Al [ng/m**3] (refractory) Al [ng/m**3] (bulk) Mn [ng/m**3] (labile) Mn [ng/m**3] (refractory) Mn [ng/m**3] (bulk) Zn [ng/m**3] (labile) Zn [ng/m**3] (refractory) Zn [ng/m**3] (bulk) Pb [ng/m**3] (labile) Pb [ng/m**3] (refractory) Pb [ng/m**3] (Pb bulk (ng/m3)) δ66Zn [‰] (labile) δ66Zn std dev [±] (labile) δ66Zn [‰] (refractory) δ66Zn std dev [±] (refractory) 206Pb/207Pb (labile) 206Pb/207Pb e [±] (labile) 206Pb/207Pb (refractory) 206Pb/207Pb e [±] (refractory) 208Pb/206Pb (labile) 208Pb/206Pb e [±] (labile) 208Pb/206Pb (refractory) 208Pb/206Pb e [±] (refractory) BC1 2022-02-22 2022-02-24 -36.7 -32.5 -73.1 -72.0 5.5 73.1 78.6 0.62 0.71 1.34 0.7 0.5 1.2 0.109 0.082 0.191 -0.12 0.04 -0.05 0.04 1.1765 0.0005 1.1776 0.0005 2.0840 0.0001 2.0837 0.0001 BC2 2022-02-24 2022-02-26 -32.5 -32.5 -72.0 -76.6 31.0 76.5 107.5 0.99 0.85 1.84 0.3 0.3 0.6 0.022 0.019 0.041 0.32 0.04 0.21 0.04 1.1762 0.0005 1.1811 0.0005 2.0843 0.0001 2.0818 0.0001 BC3 2022-02-27 2022-02-28 -32.5 -32.5 -79.0 -82.0 0.8 0.8 0.01 0.02 0.03 0.6 0.4 1.0 0.006 0.003 0.009 0.29 0.04 0.27 0.04 1.1898 0.0005 1.1761 0.0005 2.0565 0.0001 2.0813 0.0001 BC4 2022-03-02 2022-03-04 -32.5 -32.5 -88.0 -94.0 0.2 1.0 1.2 0.02 0.03 0.05 0.5 0.3 0.8 0.007 0.004 0.011 0.25 0.04 0.21 0.04 1.2153 0.0005 1.2106 0.0005 2.0175 0.0001 2.0273 0.0001 49 2022-03-04 2022-03-06 -32.5 -32.5 -94.0 -100.0 0.4 0.4 0.01 0.00 0.01 0.7 0.5 1.2 0.004 0.003 0.006 0.16 0.04 0.15 0.04 1.1608 0.0005 1.1531 0.0005 2.0963 0.0001 2.1091 0.0001 50 2022-03-06 2022-03-08 -32.5 -31.4 -100.0 -108.0 0.4 0.4 0.00 0.00 0.00 0.2 0.4 0.7 0.001 0.003 0.004 0.26 0.04 0.23 0.04 1.1491 0.0005 1.1591 0.0005 2.1256 0.0001 2.1081 0.0001 B14 2022-03-08 2022-03-10 -31.4 -31.4 -108.0 -113.0 0.2 0.1 0.4 0.001 0.001 0.002 0.13 0.04 0.18 0.04 1.1137 0.0005 2.1758 0.0001 51 2022-03-10 2022-03-12 -31.4 -31.4 -113.0 -119.0 0.5 0.5 0.00 0.01 0.01 1.2 1.3 2.4 0.002 0.003 0.006 0.21 0.04 0.14 0.04 1.1555 0.0005 1.1653 0.0005 2.1081 0.0001 2.0936 0.0001 52 2022-03-12 2022-03-14 -31.4 -31.4 -119.0 -126.5 0.1 0.7 0.8 0.12 0.07 0.18 0.6 0.3 0.9 0.023 0.011 0.034 0.12 0.04 0.15 0.04 1.1603 0.0005 1.1551 0.0005 2.0946 0.0001 2.1030 0.0001 53 2022-03-14 2022-03-18 -31.4 -31.4 -128.0 -138.0 0.7 0.7 0.01 0.01 0.01 1.3 1.4 2.7 0.006 0.005 0.011 0.26 0.04 0.25 0.04 1.1774 0.0005 1.1515 0.0005 2.0618 0.0001 2.0960 0.0001 BA7 2022-03-18 2022-03-21 -31.4 -26.2 -138.0 -152.0 0.2 0.6 0.6 0.10 0.06 0.16 0.007 0.004 0.012 0.14 0.04 0.13 0.04 1.1695 0.0005 1.1686 0.0005 2.0835 0.0001 2.0864 0.0001 BB4 2022-03-31 2022-03-03 -25.9 -25.8 -177.2 -172.0 0.1 0.9 0.9 0.01 0.02 0.03 0.3 0.2 0.5 0.003 0.002 0.005 0.21 0.04 0.20 0.04 1.0980 0.0005 1.0862 0.0005 2.1699 0.0001 2.1893 0.0001