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Kneuker, Tilo; Mann, Thomas; Dohrmann, Reiner; Ufer, Kristian; Blumenberg, Martin; Erbacher, Jochen; Bornemann, André; Schuck, Bernhard; Zimmerli, Géraldine Nicole; Pollok, Lukas: Organic parameters obtained from Metzingen core [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.987520 (dataset in review), In: Kneuker, T et al.: Whole rock mineralogy and organic parameters of Opalinus Clay: insights from sediment cores from the Swabian Alb (southern Germany) [dataset bundled publication]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.987405 (dataset in review)

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Abstract:
The total carbon (TC), total organic carbon (TOC), and total sulfur (TS) were determined using a LECO CS-230 system (Laboratory Equipment Corporation). Samples were heated up to 2000 °C under an oxygen atmosphere and an infrared detector subsequently measured the amount of produced CO2 and SO2. TOC was measured the same way after removing inorganic carbonates using 10 % HCl solution at 80 °C. Rock-Eval Pyrolyses were performed on a Rock-Eval-6 analyser (Vinci Technologies) using up to 180 mg initial sample material and a standard program (Espitalié et al., 1977; Lafargue et al., 1998), starting isothermal with 300°C for 3 min, succeeded by a heating rate of 25°C/min up to 650°C. Standard deviations for hydrogen indices (HI) and Tmax values are ± 5 % and ± 2°C, respectively.
Keyword(s):
cation exchange capacity; Clay formation; clay mineral; Claystone; mineralogy; Opalinus Clay; Organic and inorganic carbon concentrations; rock eval; Swabian Alb; whole-rock mineralogy
References:
Espitalié, J; Laporte, J L; Madec, M; Marquis, F; Leplat, P; Paulet, J; Boutefeu, A (1977): Méthode rapide de caractérisation des roches mètres, de leur potentiel pétrolier et de leur degré d'évolution. Revue de l'Institut Francais du Pétrole, 32(1), 23-42, https://doi.org/10.2516/ogst:1977002
Lafargue, E; Marquis, F; Pillot, D (1998): Rock-Eval 6 Applications in Hydrocarbon Exploration, Production, and Soil Contamination Studies. Revue de l'Institut Francais du Pétrole, 53(4), 421-437, https://doi.org/10.2516/ogst:1998036
Funding:
Federal Institute for Geosciences and Natural Resources (BGR), grant/award no. A-0703029.A: Sequence stratigraphy of the Aalenian in southern Germany (SEPIA)
Coverage:
Latitude: 48.511490 * Longitude: 9.264640
Date/Time Start: 2019-11-01T00:00:00 * Date/Time End: 2019-11-01T00:00:00
Minimum DEPTH, sediment/rock: 70.79 m * Maximum DEPTH, sediment/rock: 219.76 m
Event(s):
SEPIA-Metzingen * Latitude: 48.511490 * Longitude: 9.264640 * Date/Time: 2019-11-01T00:00:00 * Elevation: 468.0 m * Location: Baden-Württemberg * Method/Device: Drilling/drill rig (DRILL) * Comment: Altitude: m above NN
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventKneuker, TiloBorehole
2DEPTH, sediment/rockDepth sedmKneuker, TiloGeocode
3Sample code/labelSample labelKneuker, Tilo
4Carbon, totalTC%Blumenberg, MartinElement Analyser CS, LECO CS 230wt%
5Carbon, inorganic, totalTIC%Blumenberg, MartinElement Analyser CS, LECO CS 230wt%
6Carbon, organic, totalTOC%Blumenberg, MartinElement Analyser CS, LECO CS 230wt%
7Sulfur, totalTS%Blumenberg, MartinElement Analyser CS, LECO CS 230wt%
8Hydrocarbon yield, S1, per unit sediment massS1 HC/sedmg/gBlumenberg, MartinRock-Eval 6 (Vinci Technologies)
9Hydrocarbon yield, S2, per unit sediment massS2 HC/sedmg/gBlumenberg, MartinRock-Eval 6 (Vinci Technologies)
10Carbon dioxide yield, S3, per unit sediment massS3 CO2/sedmg/gBlumenberg, MartinRock-Eval 6 (Vinci Technologies)
11Pyrolysis temperature maximumTmax°CBlumenberg, MartinRock-Eval 6 (Vinci Technologies)
12Hydrogen index, mass HC, per unit mass total organic carbonHI, HC/TOCmg/gBlumenberg, MartinRock-Eval 6 (Vinci Technologies)
13Oxygen index, mass CO2, per unit mass total organic carbonOI, CO2/TOCmg/gBlumenberg, MartinRock-Eval 6 (Vinci Technologies)
14Production index, S1/(S1+S2)PIBlumenberg, MartinCalculated
15Carbon dioxide yield, S3/Hydrocarbon yield, S2S3/S2Blumenberg, MartinCalculated
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
985 data points

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