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Dugerdil, Lucas; Ménot, Guillemette; Peyron, Odile; Egamberdieva, Dilfuza; Jouffroy-Bapicot, Isabelle; Vannière, Boris; Alimov, Jakhongir; Luneau, Elise; Lhuillier, Johanna; Joannin, Sébastien (2025): Branched Glycerol Dialkyl Glycerol Tetraethers (brGDGTs) from Lake Fazilman, Uzbekistan [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.987391 (DOI registration in progress), In: Dugerdil, L et al. (2025): Holocene multi-proxy analyses from Lake Fazilman, Uzbekistan: pollen, NPPs, GDGTs, XRF, magnetic susceptibility, climate and vegetation quantitative reconstructions [dataset bundled publication]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.987394 (DOI registration in progress)

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Published: 2025-12-09

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Abstract:
This data table contains the concentration of the major branched Glycerol Dialkyl Glycerol Tetraethers (brGDGTs) of a 227 cm-long core core from Lake Fazilman (Fazilman kul, 40.550406 N, 66.589361 E; 1637 m a.s.l.), collected in July 2021 with a 50 cm Russian corer. Mainly, each sample of one cm³ of sediment, after a 24 hours lyophilization and weighing, was crushed. The total lipid content (TLC) was twice extracted from the sediment with a DCM:MeOH (3:1) solvent extraction catalysed by microwave at 70 °C and under pressure. Then, to separate GDGTs from other lipids, the TLC was filtered on SPE cartridges and concentrated in vials. External C46 GDGTs were added as internal standard in order to estimate the Fazilman GDGTs absolute concentration (Huguet et al., 2006). GDGTs were injected in hexane:iso-propanol (99.8:0.2) solvent for a high performance liquid chromatography mass spectrometry (HPLC-APCI-MS, Agilent 1200) analysis in LGLTPE-ENS de Lyon laboratory. Then each compound was manually integrated using the m/z ratio and relative abundances in order to identify brGDGTs 5-, 6- (De Jonge et al., 2014) and 7-methyls (Ding et al., 2016). Following De Jonge et al. (2014), the Roman numerals represent different GDGT structures. The different 5-, 6- and 7- isomers are given. The data are in fractional abundances. The sample depth is given in centimeters and the age in year calibrated BP (age-depth model performed with BACON and the IntCal20 calibration curve based on 15 radiocarbon dating; Blaauw et al., 2011; Reimer et al., 2020). The data table also contains the climate reconstructions obtains from ensemble modelling based on several linear calibration and Boosted Regression Trees (BRT) machine learning models. For more details on the statistical method, please refer to Dugerdil et al. (in review). The climate parameters correspond to Mean Annual Air Temperature (MAAT, °C), Aridity Index (AI, no unit), Mean Average temperature of months above Freezing (MAF, °C) and the Mean Precipitation of the Colder Quarter (MPCOQ, mm.yr-1).
Keyword(s):
Arid Central Asia; biomization scheme; climate reconstruction; GDGTs; Holocene; human impact; Magnetic susceptibility; plant functional traits; Pollen; Uzbekistan; XRF
Related to:
Blaauw, Maarten; Christen, Andrés (2011): Flexible paleoclimate age-depth models using an autoregressive gamma process. Bayesian Analysis, 6(3), 457-474, https://doi.org/10.1214/11-BA618
De Jonge, Cindy; Hopmans, Ellen C; Zell, Claudia; Kim, Jung-Hyun; Schouten, Stefan; Sinninghe Damsté, Jaap S (2014): Occurrence and abundance of 6-methyl branched glycerol dialkyl glycerol tetraethers in soils: Implications for palaeoclimate reconstruction. Geochimica et Cosmochimica Acta, 141, 97-112, https://doi.org/10.1016/j.gca.2014.06.013
Ding, Su; Schwab, Valérie F; Ueberschaar, Nico; Roth, Vanessa-Nina; Lange, Markus; Xu, Yunping; Gleixner, Gerd; Pohnert, Georg (2016): Identification of novel 7-methyl and cyclopentanyl branched glycerol dialkyl glycerol tetraethers in lake sediments. Organic Geochemistry, 102, 52-58, https://doi.org/10.1016/j.orggeochem.2016.09.009
Dugerdil, Lucas; Peyron, Odile; Ménot, Guillemette; Egamberdieva, Dilfuza; Alimov, Jakhongir; Leroy, Suzanne A G; Garnier, Eric; Nowak, Arkadiusz; Joannin, Sébastien (2025): First paleoenvironmental calibrations for modern pollen rain of Tajikistan and Uzbekistan: A case study of pollen - vegetation functional biogeography of Arid Central Asia. Global and Planetary Change, 252, 104857, https://doi.org/10.1016/j.gloplacha.2025.104857
Dugerdil, Lucas; Peyron, Odile; Violle, Cyrille; Joannin, Sébastien; Ménot, Guillemette; Denelle, Pierre; Bruelheide, Helge; Chytrý, Milan; Field, Richard; Hatim, Mohamed Z; Gholizadeh, Hamid; Dolezal, Jiri; Pillar, Valério D; Shaltout, Kamal H; Schrodt, Franziska; Garnier, Eric (2025): Functional Signatures of Surface Pollen and Vegetation Are Broadly Similar: Good News for Past Reconstructions of Vegetation. Journal of Biogeography, 52(5), e15100, https://doi.org/10.1111/jbi.15100
Guiot, Joel (1990): Methodology of the last climatic cycle reconstruction in France from pollen data. Palaeogeography, Palaeoclimatology, Palaeoecology, 80(1), 49-69, https://doi.org/10.1016/0031-0182(90)90033-4
Huguet, Carme; Hopmans, Ellen C; Febo-Ayala, Wilma; Thompson, David H; Sinninghe Damsté, Jaap S; Schouten, Stefan (2006): An improved method to determine the absolute abundance of glycerol dibiphytanyl glycerol tetraether lipids. Organic Geochemistry, 37(9), 1036-1041, https://doi.org/10.1016/j.orggeochem.2006.05.008
Liu, Xiao-Lei; Summons, Roger E; Hinrichs, Kai-Uwe (2012): Extending the known range of glycerol ether lipids in the environment: structural assignments based on tandem mass spectral fragmentation patterns. Rapid Communications in Mass Spectrometry, 26(19), 2295-2302, https://doi.org/10.1002/rcm.6355
Peyron, Odile; Guiot, Joël; Cheddadi, Rachid; Tarasov, Pavel E; Reille, Maurice; de Beaulieu, Jacques-Louis; Bottema, Sytze; Andrieu, Valérie (1998): Climatic Reconstruction in Europe for 18,000 YR B.P. from Pollen Data. Quaternary Research, 49(2), 183-196, https://doi.org/10.1006/qres.1997.1961
Prentice, Iain Colin; Guiot, Joel; Huntley, Brian; Jolly, Dominique; Cheddadi, Rachid (1996): Reconstructing biomes from palaeoecological data: a general method and its application to European pollen data at 0 and 6 ka. Climate Dynamics, 12(3), 185-194, https://doi.org/10.1007/BF00211617
Reimer, Paula J; Austin, William EN; Bard, Edouard; Bayliss, Alex; Blackwell, Paul G; Ramsey, Christopher Bronk; Butzin, Martin; Cheng, Hai; Edwards, R Lawrence; Friedrich, Michael; Grootes, Pieter Meiert; Guilderson, Thomas P; Hajdas, Irka; Heaton, Timothy J; Hogg, Alan G; Hughen, Konrad A; Kromer, Bernd; Manning, Sturt W; Muscheler, Raimund; Palmer, Jonathan G; Pearson, Charlotte; van der Plicht, Johannes; Reimer, Ron W; Richards, David A; Scott, E Marian; Southon, John R; Turney, Chris S M; Wacker, Lukas; Adolphi, Florian; Büntgen, Ulf; Capano, Manuela; Fahrni, Simon M; Fogtmann-Schulz, Alexandra; Friedrich, Ronny; Köhler, Peter; Kudsk, Sabrina; Miyake, Fusa; Olsen, Jesper; Reinig, Frederick; Sakamoto, Minoru; Sookdeo, Adam; Talamo, Sahra (2020): The IntCal20 Northern Hemisphere Radiocarbon Age Calibration Curve (0–55 cal kBP). Radiocarbon, 62(4), 725-757, https://doi.org/10.1017/RDC.2020.41
Salonen, J Sakari; Seppä, Heikki; Luoto, Miska; Bjune, Anne Elisabeth; Birks, H John B (2012): A North European pollen–climate calibration set: analysing the climatic responses of a biological proxy using novel regression tree methods. Quaternary Science Reviews, 45, 95-110, https://doi.org/10.1016/j.quascirev.2012.05.003
Tarasov, Pavel E; Cheddadi, Rachid; Guiot, Joel; Bottema, Sytze; Peyron, Odile; Belmonte, Jordina; Ruiz-Sanchez, Vittoria; Saadi, Fatima; Brewer, Simon (1998): A method to determine warm and cool steppe biomes from pollen data; application to the Mediterranean and Kazakhstan regions. Journal of Quaternary Science, 13(4), 335-344, https://doi.org/10.1002/(SICI)1099-1417(199807/08)13:4%3C335::AID-JQS375%3E3.0.CO;2-A
ter Braak, Cajo J F; Juggins, Steve; Birks, H John B; van der Voet, Hilko (1993): Weighted averaging partial least squares regression (WA-PLS): Definition and comparison with other methods for species-environment calibration. Multivariate Environmental Statistics, G. P. Patil, and C. R. Rao (eds). Amsterdam: Elsevier Science Publishers B.V. (North-Holland), 525-560
Funding:
Agence Nationale de la Recherche (ANR), grant/award no. ANR-22-CE27-0018-02: STEPABILITY
Coverage:
Latitude: 40.550406 * Longitude: 66.589361
Date/Time Start: 2021-07-01T00:00:00 * Date/Time End: 2021-07-01T00:00:00
Minimum DEPTH, sediment/rock: 0.00 m * Maximum DEPTH, sediment/rock: 2.27 m
Event(s):
Faz-21 * Latitude: 40.550406 * Longitude: 66.589361 * Date/Time: 2021-07-01T00:00:00 * Elevation: 1637.0 m * Recovery: 227 cm * Method/Device: Russian corer (RUSC) * Comment: 50 cm russian corer
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Sample code/labelSample labelDugerdil, Lucas
2DEPTH, sediment/rockDepth sedmDugerdil, LucasGeocode
3Calendar ageCal ageka BPDugerdil, LucasAge, 14C calibrated, Bacon and IntCal20according to Blaauw et al., 2011; Reimer et al., 2020
4Branched glycerol dialkyl glycerol tetraether, IIIa (5)brGDGT IIIa (5)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIIa_5Me)
5Branched glycerol dialkyl glycerol tetraether, IIIa (6)brGDGT IIIa (6)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIIa_6Me)
6Branched glycerol dialkyl glycerol tetraether, IIIa (7)brGDGT IIIa (7)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIIa_7Me)
7Branched glycerol dialkyl glycerol tetraether, IIIb (5)brGDGT IIIb (5)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIIb_5Me)
8Branched glycerol dialkyl glycerol tetraether, IIIb (6)brGDGT IIIb (6)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIIb_6Me)
9Branched glycerol dialkyl glycerol tetraether, IIIb (7)brGDGT IIIb (7)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIIb_7Me)
10Branched glycerol dialkyl glycerol tetraether, IIIc (5)brGDGT IIIc (5)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIIc_5Me)
11Branched glycerol dialkyl glycerol tetraether, IIIc (6)brGDGT IIIc (6)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIIc_6Me)
12Branched glycerol dialkyl glycerol tetraether, IIIc (7)brGDGT IIIc (7)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIIc_7Me)
13Branched glycerol dialkyl glycerol tetraether, IIa (5)brGDGT IIa (5)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIa_5Me)
14Branched glycerol dialkyl glycerol tetraether, IIa (6)brGDGT IIa (6)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIa_6Me)
15Branched glycerol dialkyl glycerol tetraether, IIa (7)brGDGT IIa (7)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIa_7Me)
16Branched glycerol dialkyl glycerol tetraether, IIb (5)brGDGT IIb (5)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIb_5Me)
17Branched glycerol dialkyl glycerol tetraether, IIb (6)brGDGT IIb (6)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIb_6Me)
18Branched glycerol dialkyl glycerol tetraether, IIb (7)brGDGT IIb (7)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIb_7Me)
19Branched glycerol dialkyl glycerol tetraether, IIc (5)brGDGT IIc (5)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIc_5Me)
20Branched glycerol dialkyl glycerol tetraether, IIc (6)brGDGT IIc (6)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIc_6Me)
21Branched glycerol dialkyl glycerol tetraether, IIc (7)brGDGT IIc (7)%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance, f(IIc_7Me)
22Branched glycerol dialkyl glycerol tetraether, IabrGDGT Ia%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance
23Branched glycerol dialkyl glycerol tetraether, IbbrGDGT Ib%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance
24Branched glycerol dialkyl glycerol tetraether, IcbrGDGT Ic%Dugerdil, LucasHigh Performance Liquid Chromatography (HPLC-APCI-MS)fractional abundance
25Temperature, air, annual meanMAAT°CDugerdil, LucasEnsemble reconstruction; linear calibration and Boosted Regression Tree (BRT) modelsbrGDGT-based reconstruction
26Aridity indexAridity indexDugerdil, LucasEnsemble reconstruction; linear calibration and Boosted Regression Tree (BRT) modelsbrGDGT-based reconstruction
27Temperature, air, mean of months, above freezingMAF°CDugerdil, LucasEnsemble reconstruction; linear calibration and Boosted Regression Tree (BRT) modelsbrGDGT-based reconstruction
28Precipitation, meanPrecip meanmmDugerdil, LucasEnsemble reconstruction; linear calibration and Boosted Regression Tree (BRT) modelsbrGDGT-based reconstruction of MPCOQ (Mean Precipitation of the COldest Quarter)
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
1620 data points

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