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Choisnard, Noémie; Lemke, Josephin; Voss, Maren: Nitrate dual isotopes and nitrification rates in central Chile [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.986751 (dataset in review)

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Abstract:
This dataset presents data collected along a four-station transect sampled in January 2023 in the upwelling system offshore of Chile (36°S) during the MAPUCHE cruise SO296-2 aboard the R/V Sonne. Phosphate, nitrite, ammonium and nitrate concentrations were analyzed. Nitrate plus nitrite and nitrate δ15N (vs. AIR) and δ18O (vs. VSMOW) measurements have been performed using the denitrifier method (Weigand et al., 2016) on seawater samples. Samples for nitrate δ15N and δ18O were treated with sulfamic acid before isotope analysis to remove nitrite (Granger and Sigman, 2009). δ18O-nitrate values were additionally corrected for the changes in salinity (Knapp et al., 2008).δ15N-nitrite values were calculated using a mass balance and δ15N values before and after nitrite removal. This dataset also includes values of nitrification rates, measured using the tracer incubation method (Damashek et al., 2016).
Keyword(s):
Humboldt Current upwelling system; Nitrate isotopes; nitrate+nitrite; nitrification rate; oxygen minimum zones
Supplement to:
Choisnard, Noémie; Lemke, Josephin; Fabian, Jenny; Liskow, Iris; Schulz-Vogt, Heide N; Voss, Maren (submitted): Nitrate dual isotopes and nitrification rates in central Chile.
References:
Damashek, Julian; Casciotti, Karen L; Francis, Christopher A (2016): Variable Nitrification Rates Across Environmental Gradients in Turbid, Nutrient-Rich Estuary Waters of San Francisco Bay. Estuaries and Coasts, 39(4), 1050-1071, https://doi.org/10.1007/s12237-016-0071-7
Granger, Julie; Sigman, Daniel M (2009): Removal of nitrite with sulfamic acid for nitrate N and O isotope analysis with the denitrifier method. Rapid Communications in Mass Spectrometry, 23(23), 3753-3762, https://doi.org/10.1002/rcm.4307
Weigand, Mira Alexandra; Foriel, Julien; Barnett, Bruce; Oleynik, Sergey; Sigman, Daniel M (2016): Updates to instrumentation and protocols for isotopic analysis of nitrate by the denitrifier method. Rapid Communications in Mass Spectrometry, 30(12), 1365-1383, https://doi.org/10.1002/rcm.7570
Coverage:
Median Latitude: -36.495017 * Median Longitude: -73.200008 * South-bound Latitude: -36.545100 * West-bound Longitude: -73.383300 * North-bound Latitude: -36.433267 * East-bound Longitude: -73.049900
Date/Time Start: 2023-01-24T04:51:00 * Date/Time End: 2023-01-28T03:46:00
Minimum Elevation: -119.0 m * Maximum Elevation: -60.5 m
Event(s):
SO296/2_19-1 * Latitude: -36.485583 * Longitude: -73.232617 * Date/Time: 2023-01-24T04:51:00 * Elevation: -116.0 m * Location: South Pacific Ocean * Campaign: SO296/2 (MAPUCHE) * Basis: Sonne_2 * Method/Device: CTD/Rosette (CTD-RO) * Comment: Station 22
SO296/2_26-3 (Station_18) * Latitude: -36.516117 * Longitude: -73.134217 * Date/Time: 2023-01-24T16:34:00 * Elevation: -94.2 m * Location: South Pacific Ocean * Campaign: SO296/2 (MAPUCHE) * Basis: Sonne_2 * Method/Device: CTD/Rosette (CTD-RO) * Comment: Station 18; Pump-CTD
SO296/2_30-2 (Station_26) * Latitude: -36.433267 * Longitude: -73.383300 * Date/Time: 2023-01-26T03:10:00 * Elevation: -119.0 m * Location: South Pacific Ocean * Campaign: SO296/2 (MAPUCHE) * Basis: Sonne_2 * Method/Device: CTD/Rosette (CTD-RO) * Comment: Station 26; Pump-CTD
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventChoisnard, Noémie
2Latitude of eventLatitudeChoisnard, Noémie
3Longitude of eventLongitudeChoisnard, Noémie
4Date/Time of eventDate/TimeChoisnard, Noémie
5Station labelStationChoisnard, Noémie
6DEPTH, waterDepth watermChoisnard, NoémieGeocode – nrow
7Mixed layer depthMLDmChoisnard, NoémieCalculated
8Depth of the euphotic zonez(eu)mChoisnard, NoémieCalculated
9ELEVATIONElevationm a.s.l.Choisnard, NoémieGeocode – Bottom depth
10Pressure, waterPressdbarChoisnard, NoémieCTD, Sea-Bird, SBE 911plus
11Phosphate[PO4]3-µmol/lChoisnard, NoémieAuto analyzer, SEAL Analytical, QuAAtro
12Nitrite[NO2]-µmol/lChoisnard, NoémieAuto analyzer, SEAL Analytical, QuAAtro
13Ammonium[NH4]+µmol/lChoisnard, NoémieAuto analyzer, SEAL Analytical, QuAAtro
14SilicateSi(OH)4µmol/lChoisnard, NoémieAuto analyzer, SEAL Analytical, QuAAtro
15Nitrate[NO3]-µmol/lChoisnard, NoémieAuto analyzer, SEAL Analytical, QuAAtro
16Nitrification rateNitrificationnmol/l/hChoisnard, NoémieTracer incubation method (Damashek et al., 2016)
17Nitrification rate, standard deviationNitrifi rate std dev±Choisnard, NoémieCalculated
18Nitrification, limit of detectionNitrification LODnmol/l/hChoisnard, NoémieCalculated
19δ15N, nitrite + nitrateδ15N NO2+NO3‰ airChoisnard, NoémieDenitrifier method according to Weigand et al. (2016)
20δ18O, nitrite + nitrateδ18O NO2+NO3‰ SMOWChoisnard, NoémieDenitrifier method according to Weigand et al. (2016)
21δ15N, nitrateδ15N NO3‰ airChoisnard, NoémieDenitrifier method according to Weigand et al. (2016)
22δ18O, nitrateδ18O NO3‰ SMOWChoisnard, NoémieDenitrifier method according to Weigand et al. (2016) and (Granger and Sigman, 2009)
23δ15N, nitriteδ15N NO2‰ airChoisnard, NoémieCalculated
24Δ(15-18)δ15N-δ18OChoisnard, NoémieCalculated
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
693 data points

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