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Adam, Sean Mark Peter; Julich, Dorit; Benning, Raphael; Jackisch, Conrad: Physicochemical soil property data for archive samples of the Saxon agricultural soil monitoring program [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.984779 (dataset in review), In: Adam, SMP et al.: SaxSSL: A mid-infrared Soil Spectral Library for the agricultural soils of Saxony, Germany [dataset bundled publication]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.984699 (dataset in review)

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Abstract:
The continuous agricultural soil monitoring program (BDF) by the Saxon State Office for Environment, Agriculture, and Geology (LfULG) is operational since 1995, collecting and analysing samples periodically from 60 monitoring sites across Saxony, Germany. This dataset provides physicochemical soil property data for 920 archive samples available from the Saxon soil information system FIS Boden, including soil organic carbon, total nitrogen, various total and extractable elemental contents, soil pH, cation exchange capacity, and particle size distribution. Additional soil physical data (bulk density, soil water retention) have been merged from undisturbed sample data, resulting in a total of 123 variables, though with varying availability. This dataset provides the majority of reference data for the mid-infrared soil spectral library for agricultural soils in Saxony, Germany.
Keyword(s):
Agriculture; diffuse reflectance Fourier transform infrared spectroscopy; Infrared Spectroscopy; Organic carbon; soil carbon; soil monitoring; soil spectral library; stepped thermal analysis
References:
Ad-hoc-Arbeitsgruppe Boden (2005): Bodenkundliche Kartieranleitung (KA5), 5th edition. Bundesanstalt für Geowissenschaften und Rohstoffe, Hannover, Germany, https://www.bafg.de/SharedDocs/Downloads/DE/baggergut/kartieranleitung.pdf?__blob=publicationFile&v=1
Mehra, O P; Jackson, M L (1958): Iron Oxide Removal from Soils and Clays by a Dithionite-Citrate System Buffered with Sodium Bicarbonate. Clays and Clay Minerals, 7, 317-327, https://doi.org/10.1346/CCMN.1958.0070122
Documentation:
Pickert, Enrico; Benning, Raphael; Stephani, Anne; Scherer, Volker; Kochan, Nils (2021): Fachinformationssystem Boden: UBoden.net Benutzerhandbuch. Sächsisches Landesamt für Umwelt, Landwirtschaft und Geologie (LfULG)
Coverage:
Median Latitude: 51.107907 * Median Longitude: 13.407493 * South-bound Latitude: 50.463161 * West-bound Longitude: 12.153755 * North-bound Latitude: 51.522479 * East-bound Longitude: 14.914174
Date/Time Start: 1995-05-26T00:00:00 * Date/Time End: 2017-05-04T00:00:00
Minimum DEPTH, soil: 0.030 m * Maximum DEPTH, soil: 0.910 m
Event(s):
BDF01_LA * Latitude: 51.477034 * Longitude: 12.883189 * Date/Time Start: 2006-10-24T00:00:00 * Date/Time End: 2017-03-16T00:00:00 * Penetration: 0.68 m * Method/Device: Soil pit (SPIT) * Comment: soil pit disturbed sample; coordinates are rounded to resolution of approx. 1km
BDF02 * Latitude: 51.473115 * Longitude: 13.185771 * Penetration: 0.6 m * Comment: coordinates are rounded to resolution of approx. 1km
BDF02_FA * Latitude: 51.473115 * Longitude: 13.185771 * Date/Time Start: 1995-09-15T00:00:00 * Date/Time End: 2017-03-15T00:00:00 * Penetration: 0.6 m * Method/Device: Soil corer * Comment: area sample, 6x small-bore soil cores, combined to mixed sample; coordinates are rounded to resolution of approx. 1km
Comment:
L: Soil pit sample
A, B, C: Area sample replicates; At each BDF sampling campaign, 3 mixed samples (from respective 6 individual sampling points) are collected
P, M : test sample, mixed sample (for archive samples)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventJulich, Dorit
2Sample code/labelSample labelJulich, Dorit
3Sample code/label 2Sample label 2Julich, Dorit
4DATE/TIMEDate/TimeJulich, DoritGeocode
5Profile IDProfile IDJulich, Dorit
6Depth, soil, minimumDepth soil minmJulich, Dorit
7DEPTH, soilDepth soilmJulich, DoritGeocode
8Depth, soil, maximumDepth soil maxmJulich, Dorit
9Land useLand useJulich, Dorit
10Soil typeSoil typeJulich, DoritSoil classification according to Ad-Hoc-AG Boden 2005 (KA5)
11Soil horizonSoil horiJulich, DoritSoil classification according to Ad-Hoc-AG Boden 2005 (KA5)
12Soil texture classificationSoil texture classJulich, DoritSoil classification according to Ad-Hoc-AG Boden 2005 (KA5)
13SamplingSamplingJulich, DoritSampling type: LA = soil pit, FA: area sample, 6x small-bore soil cores
14Aluminium, dithionite extractableAlDmg/gJulich, DoritDithionite extraction according to Mehra & Jackson (1960) on fine soil fraction < 2 mm, analyzed by AAS (2000-2001), otherwise ICP-OES
15Aluminium, oxalate extractableAlOxmg/gJulich, DoritICP-OES [else], AAS [2000], H2C2O4 extraction
16AluminiumAlmg/kgJulich, DoritEnergy Dispersive X-ray Analysis (EDAX), pressed tablet [else]; Atomic Absorption Spectroscopy (AAS) ; Microwave extraction with HF-HClO4 according to Ruppert
17Aluminium, aqua regia extractableAlARmg/kgJulich, Doritaqua regia digestion followed by ICP-OESaqua regia extraction according to DIN 38414-S7, DIN ISO 11466, and DIN EN 13346
18ArsenicAsmg/kgJulich, DoritEnergy dispersive X-ray analysis, EDAX
19Arsenic, aqua regia extractableAsARmg/kgJulich, DoritICP-MSaqua regia extraction according to DIN 38414-S7, DIN ISO 11466, and DIN EN 13346
20Arsenic, ammonium nitrate extractableAsANµg/kgJulich, DoritICP-MSammonium nitrate extraction according to DIN 19730 (1997)
21BoronBmg/kgJulich, DoritICP-MSafter HF/HNO3/H2O2 microwave digestion
22BariumBamg/kgJulich, DoritEnergy dispersive X-ray analysis, EDAX
23BerylliumBemg/kgJulich, DoritICP-MSafter HF/HNO3/H2O2 microwave digestion
24BismuthBimg/kgJulich, DoritICP-MSafter HF/HNO3/H2O2 microwave digestion
25CalciumCamg/kgJulich, DoritEnergy Dispersive X-ray Analysis (EDAX), pressed tablet [since 2002]; AAS [until 2002]; Microwave extraction with HF-HClO4 according to Ruppert ; HF-HNO3-HCl microwave extraction [else]
26Calcium, aqua regia extractableCaARmg/kgJulich, Doritaqua regia digestion followed by ICP-OESaqua regia extraction according to DIN 38414-S7, DIN ISO 11466, and DIN EN 13346
27Cadmium, aqua regia extractableCdARmg/kgJulich, DoritICP-MS [since 2002], AAS [until 2002], aqua regia extraction according to DIN 38414-S7; DIN ISO 11466; DIN EN 13346
28Cadmium, ammonium nitrate extractableCdANµg/kgJulich, DoritICP-MSammonium nitrate extraction according to DIN 19730 (1997)
29CadmiumCdmg/kgJulich, DoritAtomic absorption spectrometry (AAS)HF/HNO3/H2O2 microwave extraction [since 2002], Microwave extraction with HF-HClO4 according to Ruppert [until 2002]
30CobaltComg/kgJulich, DoritICP-MSafter HF/HNO3/H2O2 microwave digestion
31Cobalt, ammonium nitrate extractableCoANµg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
32Chromium, ammonium nitrate extractableCrANµg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
33Chromium, aqua regia extractableCrARmg/kgJulich, DoritICP-MS [since 2002], AAS [until 2002], aqua regia extraction according to DIN 38414-S7; DIN ISO 11466; DIN EN 13346
34ChromiumCrmg/kgJulich, DoritEnergy Dispersive X-ray Analysis (EDAX), pressed tablet [else]; AAS [1995], Microwave extraction with HF-HClO4 according to Ruppert
35Copper, ammonium nitrate extractableCuANµg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
36CopperCumg/kgJulich, DoritICP-MSafter HF/HNO3/H2O2 microwave digestion
37Copper, aqua regia extractableCuARmg/kgJulich, DoritEnergy Dispersive X-ray Analysis (EDAX), pressed tablet [else]; AAS [1995], Microwave extraction with HF-HClO4 according to Ruppert
38FluorineFmg/kgJulich, DoritETAAS, direct [2016]; Melted digestion with Na2CO3-K2CO3, ion sensitve electrode
39Iron, aqua regia extractableFeARmg/kgJulich, Doritaqua regia digestion followed by ICP-OESaqua regia extraction according to DIN 38414-S7, DIN ISO 11466, and DIN EN 13346
40Iron, oxalate extractableFeOxmg/gJulich, DoritICP-OES [else], AAS [2000], H2C2O4 extraction
41Iron, dithionite extractableFeDmg/gJulich, DoritDithionite extraction according to Mehra & Jackson (1960) analyzed by AAS (2000-2001), otherwise ICP-OES
42IronFemg/kgJulich, DoritEnergy Dispersive X-ray Analysis (EDAX), pressed tablet [else]; AAS [1995], Microwave extraction with HF-HClO4 according to Ruppert
43Mercury, ammonium nitrate extractableHgANµg/kgJulich, DoritICP-MS [since 2012], CV-AAS [until 2012], Ammonium nitrate extraction according to DIN19730
44MercuryHgmg/kgJulich, DoritDirect mercury analyzer
45Mercury, aqua regia extractableHgARmg/kgJulich, DoritICP-MS [since 2008] CV-AAS [until 2008], aqua regia extraction according to DIN 38414-S7; DIN ISO 11466; DIN EN 13346
46PotassiumKmg/kgJulich, DoritAAS [1995], Microwave extraction with HF-HClO4 according to Ruppert; EDAX, pressed tablet [else]
47Potassium, aqua regia extractableKARmg/kgJulich, DoritICP-OES [else], AAS [2000], aqua regia extraction according to DIN 38414-S7; DIN ISO 11466; DIN EN 13346
48LithiumLimg/kgJulich, DoritICP-MSafter HF/HNO3/H2O2 microwave digestion
49MagnesiumMgmg/kgJulich, DoritAAS [1995], Microwave extraction with HF-HClO4 according to Ruppert; EDAX, pressed tablet [else]
50Magnesium, calcium chloride extractableMgCCmg/kgJulich, DoritAtomic absorption spectrometry (AAS)after CaCl2 extraction
51Magnesium, aqua regia extractableMgARmg/kgJulich, DoritICP-OES [else], AAS [2000], aqua regia extraction according to DIN 38414-S7; DIN ISO 11466; DIN EN 13346
52ManganeseMnmg/kgJulich, DoritAAS [1995], Microwave extraction with HF-HClO4 according to Ruppert; EDAX, pressed tablet [else]
53Manganese, aqua regia extractableMnARmg/kgJulich, DoritICP-OES [else], AAS [1995, 2000], aqua regia extraction DIN 38414-S7; DIN ISO 11466; DIN EN 13346
54Manganese, dithionite extractableMnDmg/gJulich, DoritICP-OES [else], AAS [2000-2001], Na2S2O4 extraction according to Mehra & Jackson 1960
55Manganese, exchangeableMn exchmg/kgJulich, DoritAtomic absorption spectrometry (AAS)MgCl2/NaSO3 exchangable and easily reducable Manganese according to VDLUFA
56Manganese, oxalate extractableMnOxmg/gJulich, DoritICP-OES [else], AAS [2000], H2C2O4 extraction
57Manganese, ammonium nitrate extractableMnANµg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
58MolybdenumMomg/kgJulich, DoritICP-MSafter HF/HNO3/H2O2 microwave digestion
59Molybdenum, ammonium nitrate extractableMoANµg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
60Molybdenum, aqua regia extractableMoARmg/kgJulich, DoritICP-MS [since 1995], AAS [until 1995] aqua regia extraction DIN 38414-S7; DIN ISO 11466; DIN EN 13346
61SodiumNamg/kgJulich, DoritEDAX, pressed tablet [else]; AAS [1995], Microwave extraction with HF-HClO4 according to Ruppert
62Nickel, aqua regia extractableNiARmg/kgJulich, DoritICP-MS [since 1995], ICP-OES [until 1995] aqua regia extraction DIN 38414-S7; DIN ISO 11466; DIN EN 13346
63Nickel, dithionite extractableNiDµg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
64NickelNimg/kgJulich, DoritEDAX, pressed tablet [else]; AAS [1995], Microwave extraction with HF-HClO4 according to Ruppert
65Phosphorus, aqua regia extractablePARmg/kgJulich, Doritaqua regia digestion followed by ICP-OESaqua regia extraction according to DIN 38414-S7, DIN ISO 11466, and DIN EN 13346
66Lead, aqua regia extractablePbARmg/kgJulich, DoritICP-MS [since 2002], ICP-OES [until 2002] aqua regia extraction DIN 38414-S7; DIN ISO 11466; DIN EN 13346
67LeadPbmg/kgJulich, DoritEDAX, pressed tablet [else]; AAS [1995], Microwave extraction with HF-HClO4 according to Ruppert
68Lead, ammonium nitrate extractablePbANµg/kgJulich, DoritICP-MS [since 2000], CV-AAS [until 2000], Ammonium nitrate extraction according to DIN19730
69AntimonySbmg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
70Antimony, aqua regia extractableSbARmg/kgJulich, Doritaqua regia digestion followed by ICP-OESaqua regia extraction according to DIN 38414-S7, DIN ISO 11466, and DIN EN 13346
71Antimony, ammonium nitrate extractableSbANµg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
72Selenium, aqua regia extractableSeARmg/kgJulich, Doritaqua regia digestion followed by ICP-OESaqua regia extraction according to DIN 38414-S7, DIN ISO 11466, and DIN EN 13346
73SeleniumSemg/kgJulich, DoritICP-MSmicrowave extraction with HF-HNO3-HCl [since 2000], microwave extraction with HF-HNO3 according to Waldner [until 2000]
74TinSnmg/kgJulich, DoritEnergy dispersive X-ray analysis, EDAX
75ThoriumThmg/kgJulich, DoritEnergy dispersive X-ray analysis, EDAX
76TitaniumTimg/kgJulich, DoritEnergy dispersive X-ray analysis, EDAX
77ThalliumTlmg/kgJulich, DoritICP-MSmicrowave extraction with HF-HNO3-HCl [since 2000]; ETAAS, microwace extraction with HNO3 [until 2000]
78Thallium, aqua regia extractableTlARmg/kgJulich, DoritICP-MS [since 2002], ICP-OES [until 2002] aqua regia extraction DIN 38414-S7; DIN ISO 11466; DIN EN 13346
79Thallium, ammonium nitrate extractableTlANµg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
80UraniumUmg/kgJulich, DoritICP-MSmicrowave extraction with HF-HNO3-HCl [since 2000], microwave extraction with HF-HNO3 according to Waldner [until 2000]
81Uranium, ammonium nitrate extractableUANµg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
82VanadiumVmg/kgJulich, DoritEnergy dispersive X-ray analysis, EDAX
83TungstenWmg/kgJulich, DoritICP-MSmicrowave extraction with HF-HNO3-HCl [since 2000], microwave extraction with HF-HNO3 according to Waldner [until 2000]
84Zinc, ammonium nitrate extractableZnANµg/kgJulich, DoritICP-MSAmmonium nitrate extraction according to DIN19730
85ZincZnmg/kgJulich, DoritEDAX, pressed tablet [else]; AAS [1995], Microwave extraction with HF-HClO4 according to Ruppert
86Zinc, aqua regia extractableZnARmg/kgJulich, DoritICP-OES [since 2008], ICP-MS [until 2008],aqua regia extraction DIN 38414-S7; DIN ISO 11466; DIN EN 13346
87ZirconiumZrmg/kgJulich, DoritEnergy dispersive X-ray analysis, EDAX
88Effective aluminiun exchange capacityEff Al ex-capcmol/kgJulich, DoritICP-OES, Inductively coupled plasma - optical emission spectrometry1M NH4Cl according to Ulrich
89Effective calcium exchange capacityEff Ca ex-capcmol/kgJulich, DoritDIN ISO 13536:1997-04
90Potential calcium exchange capacityPot Ca ex-capcmol/kgJulich, DoritICP-OES, Inductively coupled plasma - optical emission spectrometry1M NH4Cl according to Ulrich
91Effective iron exchange capacityEff Fe ex-capcmol/kgJulich, DoritICP-OES, Inductively coupled plasma - optical emission spectrometry1M NH4Cl according to Ulrich
92Effective hydrogen exchange capacityEff H ex-capcmol/kgJulich, DoritICP-OES, Inductively coupled plasma - optical emission spectrometry1M NH4Cl according to Ulrich
93Effective potassium exchange capacityEff K ex-capcmol/kgJulich, DoritICP-OES, Inductively coupled plasma - optical emission spectrometry1M NH4Cl according to Ulrich
94Potential potassium exchange capacityPot K ex-capcmol/kgJulich, DoritDIN ISO 13536:1997-04
95Potential magnesium exchange capacityPot Mg ex-capcmol/kgJulich, DoritDIN ISO 13536:1997-04
96Effective magnesium exchange capacityEff Mg ex-capcmol/kgJulich, DoritICP-OES, Inductively coupled plasma - optical emission spectrometry1M NH4Cl according to Ulrich
97Effective manganese exchange capacityEff Mn ex-capcmol/kgJulich, DoritICP-OES, Inductively coupled plasma - optical emission spectrometry1M NH4Cl according to Ulrich
98Potential sodium exchange capacityPot Na ex-capcmol/kgJulich, DoritDIN ISO 13536:1997-04
99Effective sodium ion exchange capacityEff Na ex-capcmol/kgJulich, DoritICP-OES, Inductively coupled plasma - optical emission spectrometry1M NH4Cl according to Ulrich
100Calcium carbonateCaCO3%Julich, DoritElement analysis, Scheiblerweight-percent
101Potassium oxideK2Omg/kgJulich, DoritICP-OES, Inductively coupled plasma - optical emission spectrometryCalcium-Acetate-Lactate extraction according to VDLUFA
102Potassium oxideK2Omg/kgJulich, DoritICP-OES, Inductively coupled plasma - optical emission spectrometryDouble-Lactate extraction according to VDLUFA
103Phosphorus pentoxideP2O5mg/kgJulich, DoritICP-OES [since 2008], Photometer [until 2008], Double-Lactate extraction according to VDLUFA
104Phosphorus pentoxideP2O5mg/kgJulich, DoritAES [since 2004], Photometer [until 2004], Calcium-Acetate-Lactate extraction according to VDLUFA
105Potential acid exchange capacityH-valuecmol/kgJulich, DoritBaCl2, according to DIN19684, according to Mehlich, according to DIN ISO 13536
106Effective cation exchange capacityECECcmol/kgJulich, Dorit1M NH4Cl according to Ulrich, according to Meiwes
107Potential cation exchange capacityPCECcmol/kgJulich, DoritDIN ISO 13536:1997-04
108Potential base exchange capacityS-valuecmol/kgJulich, DoritDIN 19684-6:1997-12Mehlich BaCl2, according to DIN19684
109CarbonC%Julich, Doritweight-percent; Elemental analysis [CHNSO-Analyzer]
110NitrogenN%Julich, Doritweight-percent; According to Kjeldahl [until 2005], Elemental analysis [CHNSO-Analyzer, since 2005]
111PhosphorusP%Julich, DoritEnergy dispersive X-ray analysis, EDAXweight-percent
112Base saturationBS%Julich, DoritCalculatedpotential
113Base saturationBS%Julich, DoritCalculatedeffective
114Carbon, organicC org%Julich, DoritDIN ISO 10694:1996-08/DIN EN 13137: 2001-12/DIN EN 15936:2012-11weight-percent
115Water content, volumetricVWC%Julich, DoritDIN ISO 11465:1996-12; DIN EN 14346:2007-03
116Water massWater%Julich, DoritDIN ISO 11465:1996-12; DIN EN 14346:2007-03
117Size fraction > 2 mm, gravel>2 mm%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
118Size fraction 6.3-2.0 mm6.3-2.0 mm%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
119Size fraction 63-20 mm, coarse gravel63-20 mm%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
120Size fraction 20-6.3 mm20-6.3 mm%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
121Size fraction 2.000-0.063 mm, sand2000-63 µm%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
122Size fraction 0.200-0.063 mm, fine sand200-63 µm fS%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
123Size fraction 2.000-0.630 mm, coarse sand2000-630 µm%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
124Size fraction 0.630-0.200 mm, medium sand630-200 µm%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
125Size fraction 200-63 mm20-6.3 cm%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
126Size fraction < 0.002 mm, clay<2 µm%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
127Size fraction 0.063-0.002 mm, silt, mud63-2 µm%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
128Size fraction 0.0063-0.002 mm, fine silt6.3-2 µm fU%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
129Size fraction 0.063-0.020 mm, coarse silt63-20 µm gU%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
130Size fraction 0.020-0.0063 mm, medium silt20-6.3 µm mU%Julich, DoritParticle size distribution, according to DIN19683 and DIN ISO 11277
131pH calcium chloridepH CaCl2Julich, DoritMeasured in 0.01 mol/l CaCl2 according to VDLUFA (1991) method A 5.1.1
132Density, particlesDens partg/cm3Julich, DoritPycnometerdata merged from undisturbed samples
133Density, dry bulkDBDg/cm3Julich, Doritdata merged from undisturbed samples
134Soil water content, volumetricvol SWC%Julich, DoritData merged from undisturbed soil samples, collected using Sandbox sampler, Sand/Kaolin box sampler, and pressure membrane extractor.
135Soil water content, volumetricvol SWC%Julich, DoritData merged from undisturbed soil samples, collected using Sandbox sampler, Sand/Kaolin box sampler, and pressure membrane extractor.
136Soil water content, volumetricvol SWC%Julich, DoritData merged from undisturbed soil samples, collected using Sandbox sampler, Sand/Kaolin box sampler, and pressure membrane extractor.
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
87793 data points

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