Sabino, Mathia; Nogarotto, Alessio; Noormets, Riko; Chauhan, Teena; Mollenhauer, Gesine; Hefter, Jens; Tesi, Tommaso: CuO oxidation products (lignin phenols and cutin acids) of upper slope marine sediments deposited over the last 30 thousand years north of the Svalbard archipelago [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.983939 (dataset in review)
Abstract:
The dataset presented was used to reconstruct the origin of terrestrial material deposited during the last 30 thousand years on the upper continental slope of the Svalbard archipelago, north of Nordaustlandet (81°16'N, 26°13'E). The material analyzed consisted in muddy sediments from the 4.66 m long gravity core HH11-09GC, retrieved at a water depth of 488 m in September 2011 during a scientific cruise of the R/V Helmer Hanssen. Data on lignin phenols and cutin acids were obtained oxidizing with cupric oxide (CuO) 250-300 mg of dry sediment of 77 samples. The analytical procedure followed Goñi & Montgomery (2000) using a Microwave Accelerated Reaction System (MARS) 6 from CEM. Chromatographic analyses to identify and quantify each compound of interest were performed on an Agilent 7820A Gas Chromatograph coupled with a 5977B Mass Selective Detector in single ion monitoring (SIM), equipped with a Trajan SGE 30 m× 320 μm (0.25 μm-thick film) PB-1 capillary column. The analytical procedures were carried in the organic geochemistry laboratories of Institute of Polar Sciences of the National Research Council in Bologna, Italy. Lignin phenols and cutin acids were used individually or to obtain ratios that provided insights on the degradation state and the origin of terrestrial material archived within the marine sediments.
Keyword(s):
Supplement to:
Sabino, Mathia; Nogarotto, Alessio; Noormets, Riko; Chauhan, Teena; Mollenhauer, Gesine; Hefter, Jens; Tesi, Tommaso (submitted): Geochemical Characterization of Permafrost Organic Carbon-Rich Unit Deposited During the Bølling-Allerød in Northern Svalbard Marine Sediments. Journal of Geophysical Research: Biogeosciences
Related to:
Goñi, Miguel A; Montgomery, Shelagh (2000): Alkaline CuO Oxidation with a Microwave Digestion System: Lignin Analyses of Geochemical Samples. Analytical Chemistry, 72(14), 3116-3121, https://doi.org/10.1021/ac991316w
Funding:
Helmholtz Association of German Research Centres (HGF), grant/award no. PIE-0018: German-Italian partnership project between AWI and CNR-ISP on Chronologies for Polar Paleoclimate Archives (PAIGE)
Coverage:
Latitude: 81.267000 * Longitude: 26.217000
Date/Time Start: 2011-09-01T00:00:00 * Date/Time End: 2011-09-01T00:00:00
Minimum DEPTH, sediment/rock: 0.02 m * Maximum DEPTH, sediment/rock: 3.16 m
Event(s):
HH11-09GC * Latitude: 81.270000 * Longitude: 26.220000 * Date/Time: 2011-09-01T00:00:00 * Elevation: -488.0 m * Location: Yermak Plateau * Campaign: HH2011 (HH11) * Basis: Helmer Hanssen * Method/Device: Gravity corer (GC)
Comment:
The research is part of the Programma di Ricerche in Artico, project PAST-HEAT (PermAfroSt Thawing: what Happened to the largest tErrestrial cArbon pool during lasT deglaciation?)
Parameter(s):
| # | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
|---|---|---|---|---|---|---|
| 1 | Sample code/label | Sample label | Sabino, Mathia | |||
| 2 | LATITUDE | Latitude | Sabino, Mathia | Geocode – Latitude N | ||
| 3 | LONGITUDE | Longitude | Sabino, Mathia | Geocode – Longitude E | ||
| 4 | DEPTH, sediment/rock | Depth sed | m | Sabino, Mathia | Geocode | |
| 5 | Lignin, per unit mass organic carbon | Lig/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 6 | Cutin, per unit mass organic carbon | Cut/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 7 | Cutin/Lignin ratio | Cut/Lig | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | ||
| 8 | Syringaldehyde per unit mass organic carbon | Syr/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 9 | Acetosyringone per unit mass organic carbon | AcetSy/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 10 | Syringic acid per unit mass organic carbon | SAc/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 11 | Vanillin per unit mass organic carbon | VA/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 12 | Acetovanillone per unit mass organic carbon | AV/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 13 | Vanillic acid per unit mass organic carbon | VAc/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 14 | p-Coumaric acid per unit mass organic carbon | p-Coumaric acid/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 15 | Ferulic acid per unit mass organic carbon | C10H10O4/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 16 | p-Hydroxybenzaldehyde per unit mass organic carbon | PAL/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 17 | p-Hydroxyacetophenone per unit mass organic carbon | PON/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 18 | p-Hydroxybenzoic acid per unit mass organic carbon | PAD/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 19 | 3,5-dihydroxybenzoic acid per unit mass organic carbon | 3,5-Bd/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 20 | Syringyl phenols per unit mass organic carbon | S/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 21 | Vanillyl phenols per unit mass organic carbon | V/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 22 | Cinnamyl phenols per unit mass organic carbon | C/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 23 | p-Hydroxyl phenols per unit mass organic carbon | P/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 24 | Syringyl phenols/vanillyl phenols ratio | S/V | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | ||
| 25 | Cinnamyl phenols/vanillyl phenols ratio | C/V | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | ||
| 26 | p-Hydroxyl phenols/vanillyl phenols ratio | P/V | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | ||
| 27 | Syringic acid/syringaldehyde ratio | (Ad/Al)s | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | ||
| 28 | Vanillic acid/vanillin ratio | (Ad/Al)v | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | ||
| 29 | 3,5-dihydroxybenzoic acid/vanillyl phenols ratio | 3,5-Bd/V | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | ||
| 30 | p-Hydroxyacetophenone/p-hydroxyl phenols ratio | PON/P | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | ||
| 31 | 16-Hydroxyhexadecanoic acid, per unit mass organic carbon | C16:0 16-OH/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 32 | 1,16-Hexadecanedioic acid, per unit mass organic carbon | C16:0-diacid/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 33 | 18-Hydroxy-9-octadecenoic acid, per unit mass organic carbon | C18:1 18-OH/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 34 | 10,16-Dihydroxyhexadecanoic acid, per unit mass organic carbon | 10,16-DHHA/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 35 | 9,16-Dihydroxyhexadecanoic acid, per unit mass organic carbon | 9,16-DHHA/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 36 | 8,16-Dihydroxyhexadecanoic acid, per unit mass organic carbon | 8,16-DHHA/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 37 | 7-hydroxy-Hexadecane-1,16-dioic acid, per unit mass organic carbon | 7-HHDA/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] | |
| 38 | 8-hydroxy-Hexadecane-1,16-dioic acid, per unit mass organic carbon | 7-HHDA/OC | mg/g | Sabino, Mathia | Microwave Accelerated Reaction System, CEM, MARS 6; followed by Gas chromatograph (GC), Agilent, 7820A [Trajan SGE PB-1 column, 30 m × 0.32 mm × 0.25 μm film thickness]; coupled with Mass Selective Detector (MSD) Agilent 5977B [single ion monitoring SIM] |
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
2688 data points
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