Novak, Joseph B; Abell, Jordan; Kinsley, Christopher: Quaternary trace metals data from ODP Site 198-1208 [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.983610 (dataset in review), In: Novak, JB et al.: 4.5 million years of deep ocean carbon isotope gradients and trace metals redox data [dataset bundled publication]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.983612 (dataset in review)
Coverage:
Latitude: 36.127167 * Longitude: 158.201583
Date/Time Start: 2001-09-14T00:00:00 * Date/Time End: 2001-09-17T00:00:00
Minimum Elevation: -3345.7 m * Maximum Elevation: -3345.7 m
Event(s):
198-1208 * Latitude: 36.127167 * Longitude: 158.201583 * Date/Time Start: 2001-09-14T00:00:00 * Date/Time End: 2001-09-17T00:00:00 * Elevation: -3345.7 m * Penetration: 392.3 m * Recovery: 345.9 m * Location: North Pacific Ocean * Campaign: Leg198 * Basis: Joides Resolution * Method/Device: Composite Core (COMPCORE) * Comment: 42 cores; 392.3 m cored; 0 m drilled; 88.2% recovery
Comment:
Method description:
Sample depths, ages, and Th concentrations have been previously published for the both the late Quaternary (Abell et al., 2023; Kinsley et al., 2022) and Pliocene-early Pleistocene (Abell et al., 2021).
Because the late Quaternary data are based on measurements of distinct isotopes of U/Th (238U and 232Th) and not bulk concentrations of these elements, the lithogenic correction for these samples is made using activity ratios.
Here we assume an activity ratio of 0.5. While the (U/Th)lith activity ratio for Pacific sediments is typically assumed to be higher at 0.7 (Henderson & Anderson, 2003), use of this value would produce negative Uauth concentrations.
A ratio of 0.5 does not lead to negative Uauth concentrations, and is consistent with estimates for other ocean basin (Henderson & Anderson, 2003).
In order to make consistent comparison within a site across time, we convert this (U/Th)lith activity ratio to a concentration ratio (0.16125) for calculating Uauth concentrations within the 2.5–4.5 Ma window.
This value is only slightly lower than if we adopted the U concentration of upper continental crust (2.8 ppm; Taylor & McLennan, 1995) and the Th concentration of fine-grained dust (14 ppm; McGee et al., 2016).
We note that any value higher than this would also produce negative Uauth concentrations in this interval, lending confidence in our selected lithogenic (U/Th) ratio.
Parameter(s):
| # | Name | Short Name | Unit | Principal Investigator | Method/Device | Comment |
|---|---|---|---|---|---|---|
| 1 | AGE | Age | ka BP | Novak, Joseph B | See description in dataset comment | Geocode |
| 2 | Uranium, authigenic | U auth | mg/kg | Novak, Joseph B | See description in dataset comment | |
| 3 | Uranium, authigenic, standard deviation | U auth std dev | ± | Novak, Joseph B | See description in dataset comment |
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
320 data points