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Seemann, Fabian; Jenrich, Maren; Lindemann, Justin; Weiner, Mikaela; Hefter, Jens; Meyer, Hanno; Grosse, Guido; Jones, Benjamin; Strauss, Jens (2025): n-Alkane biomarker, carbon, nitrogen and d13C data from the Barrow Peninsula (northern Alaska) before and after a one-year long incubation experiment [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.982646 (DOI registration in progress)

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Published: 2025-06-11

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Abstract:
We conducted a one-year long incubation experiment with sediment samples from the Barrow Peninsula (Utqiagvik, Alaska). In 2022 sediments were cored in two thermokarst lakes (East and West Twin Lake), one drained lake basin and an undisturbed upland. Additionally, sediment samples were taken from Elson Lagoon and a semi-open lagoon. On in total 20 chosen depths of all cores, n-alkane biomarker analyses were conducted. Parallelly, carbon, nitrogen and carbon isotopic analyses were carried out. Subsequently, ten lacustrine and terrestrial samples were incubated for one year under aerobic and dark conditions at 10°C. At the end of the experiment, the initial analyses were repeated. The biomarker and elemental analyses were conducted at the Permafrost Research Section (AWI Potsdam) and the isotope data has been generated in the ISOLAB Facility (AWI Potsdam).
Keyword(s):
Alaska; alkanes; Biomarker; carbon isotope ratio (δ13C); cryopegs; incubation experiment; Nitrogen; Organic carbon; Permafrost; sediment; talik
Related to:
Seemann, Fabian; Jenrich, Maren; Lindemann, Justin; Eulenburg, Antje; Weiner, Mikaela; Mollenhauer, Gesine; Meyer, Hanno; Overduin, Pier Paul; Grosse, Guido; Jones, Benjamin; Strauss, Jens (2025): Sediment and pore water investigations in thermokarst terrain near Utqiagvik, Alaska [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.974136 (Reference data sheet)
Additional metadata:
SENSOR: Metadata for mass spectrometer ThermoFisher Scientific Delta-V-Advantage at current Version. Alfred Wegener Institut Helmholtz Centre for Polar and Marine Research, hdl:10013/sensor.1df540c8-1409-43bf-a237-9af0cd871fca
Further details:
SENSOR: Metadata for laboratory ISOLAB Facility - Stable Isotope Laboratory Potsdam at current Version. Alfred Wegener Institut Helmholtz Centre for Polar and Marine Research, hdl:10013/sensor.ddc92f54-4c63-492d-81c7-696260694001
Project(s):
Funding:
National Science Foundation (NSF), grant/award no. OPP-1806213
National Science Foundation (NSF), grant/award no. OPP-2336164
Coverage:
Median Latitude: 71.276018 * Median Longitude: -156.458843 * South-bound Latitude: 71.263200 * West-bound Longitude: -156.496990 * North-bound Latitude: 71.290080 * East-bound Longitude: -156.423550
Date/Time Start: 2022-04-19T00:00:00 * Date/Time End: 2022-04-22T00:00:00
Minimum DEPTH, sediment/rock: 2.0 m * Maximum DEPTH, sediment/rock: 186.0 m
Event(s):
AK-Land_2022_NorthSlope_BRW22_DLB_001 * Latitude: 71.277200 * Longitude: -156.443110 * Date/Time: 2022-04-22T00:00:00 * Recovery: 1.42 m * Campaign: AK-Land_2022_NorthSlope (Perma-X Lagoons Alaska 2022) * Basis: AWI Arctic Land Expedition * Method/Device: SIPRE corer (SIPREC) * Comment: SIPRE corer (7.5 cm diameter)
AK-Land_2022_NorthSlope_BRW22_EL_001 * Latitude: 71.290080 * Longitude: -156.472000 * Date/Time: 2022-04-21T00:00:00 * Recovery: 2.26 m * Location: Alaskan North Slope * Campaign: AK-Land_2022_NorthSlope (Perma-X Lagoons Alaska 2022) * Basis: AWI Arctic Land Expedition * Method/Device: Vibra-corer * Comment: Vibra corer (7.5 cm diameter)
AK-Land_2022_NorthSlope_BRW22_ETL_001 * Latitude: 71.275300 * Longitude: -156.464450 * Date/Time: 2022-04-20T00:00:00 * Recovery: 1.38 m * Location: Alaskan North Slope * Campaign: AK-Land_2022_NorthSlope (Perma-X Lagoons Alaska 2022) * Basis: AWI Arctic Land Expedition * Method/Device: Vibra-corer * Comment: Vibra corer (7.5 cm diameter; 118 cm compressed)
Comment:
F.S. and M.J. received funding from the German Federal Environmental Foundation (Deutsche Bundesstiftung Umwelt).
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventSeemann, Fabian
2Sample code/labelSample labelSeemann, FabianCore name
3PositionPositionSeemann, FabianSample position
4StatusStatusSeemann, Fabian
5DEPTH, sediment/rockDepth sedmSeemann, FabianGeocode – mean sample depth
6Depth, sediment/rock, top/minimumDepth sed topmSeemann, Fabianlayer top
7Depth, sediment/rock, bottom/maximumDepth sed botmSeemann, Fabianlayer bottom
8Carbon, totalTC%Seemann, FabianCarbon Analyzer, Elementar, soli TOC cube
9Carbon, organic, totalTOC%Seemann, FabianCarbon Analyzer, Elementar, soli TOC cube
10Nitrogen, totalTN%Seemann, FabianNitrogen Analyzer, Elementar, rapid MAX N exceed
11Carbon/Nitrogen ratioC/NSeemann, Fabian
12δ13C, organic carbonδ13C Corg‰ PDBSeemann, FabianMass specrometer, ThermoFischer, Delta-VISOLAB Potsdam - SENSOR; see references
13n-Eicosane, per unit sediment massC20/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
14n-Eicosane, per unit mass total organic carbonC20/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
155alpha-androstane, per unit sediment mass5a-Androstane/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
165alpha-androstane, per unit mass total organic carbon5a-Androstane/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
17n-Heneicosane, per unit sediment massC21/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
18n-Heneicosane, per unit mass total organic carbonC21/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
19n-Docosane, per unit sediment massC22/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
20n-Docosane, per unit mass total organic carbonC22/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
21n-Tricosane, per unit sediment massC23/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
22n-Tricosane, per unit mass total organic carbonC23/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
23n-Tetracosane, per unit sediment massC24/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
24n-Tetracosane, per unit mass total organic carbonC24/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
25n-Pentacosane, per unit sediment massC25/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
26n-Pentacosane, per unit mass total organic carbonC25/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
27n-Hexacosane, per unit sediment massC26/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
28n-Hexacosane, per unit mass total organic carbonC26/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
29n-Heptacosane, per unit sediment massC27/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
30n-Heptacosane, per unit mass total organic carbonC27/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
31n-Octacosane, per unit sediment massC28/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
32n-Octacosane, per unit mass total organic carbonC28/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
33n-Nonacosane, per unit sediment massC29/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
34n-Alkane C29, per unit mass total organic carbonC29/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
35n-Triacontane, per unit sediment massC30/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
36n-Triacontane, per unit mass total organic carbonC30/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
37n-Hentriacontane, per unit sediment massC31/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
38n-Hentriacontane, per unit mass total organic carbonC31/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
39n-Dotriacontane, per unit sediment massC32/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
40n-Dotriacontane, per unit mass total organic carbonC32/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
41n-Tritriacontane, per unit sediment massC33/sedµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
42n-Tricontane, per unit mass total organic carbonC33/TOCµg/gSeemann, FabianGas chromatography mass spectrometry (GC-MS), Thermo Fisher Scientific, Gas Chromatograph, TRACE 1310; coupled with Single Quadrupole Mass Spectrometer, ISQ 7000
43Average chain length, n-Alkanes, C23-C33ACL 23-33Seemann, Fabian(δi23-33*Ci23-33)/(δCi23-33)
44Carbon Preference Index, n-Alkanes (C23-C33)CPI 23-33Seemann, Fabian(δodd nC23-nC31)+(δodd nC25-nC33)/2*(δeven nC24-32)
45Odd-over-even predominance, sum odd numbered/sum even numbered n-alkanes ratioOEP n-alkSeemann, Fabian(nC27+nC29+nC31+nC33)/(nC26+nC28+nC30+nC32)
46Aquatic n-alkane proxy (C23+C33)/(C23+C25+C29+C31)PaqSeemann, Fabian
47Index of waxy n-alkanes to total hydrocarbons (C27+C29+C31)/(C23+C25+C29+C31)PwaxSeemann, Fabian
48n-Alkanes, (C31+C33)/(C27+C31+C33) ratio(C31+C33)/(C27+C31+C33)Seemann, Fabian
49CommentCommentSeemann, Fabian
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
1379 data points

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