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Zeppenfeld, Sebastian; Schmidt, Leon (2025): Dissolved and particulate carbohydrates and inorganic ions in the sea surface microlayer and bulk water of Kongsfjorden (Autumn 2021/Spring 2022) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.982606

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Published: 2025-05-23DOI registered: 2025-06-25

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Abstract:
Sea surface microlayer (SML) and bulk water samples were collected from various locations in Kongsfjorden (Svalbard) during autumn 2021 and spring 2022. SML samples were obtained using the glass plate method, while corresponding bulk water samples (1 m depth) were collected with a telescopic rod. The following chemical parameters were analyzed: dissolved free carbohydrates (DFCHO), dissolved combined carbohydrates (DCCHO), particulate combined carbohydrates (PCCHO), and major inorganic ions. DFCHO and DCCHO concentrations were determined from filtered seawater (0.2 µm) after desalination via electrodialysis, followed by high-performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD). PCCHO concentrations were measured from 0.2 µm polycarbonate membrane filters. All carbohydrate fractions (DFCHO, DCCHO, PCCHO) were quantified as the sum of individual monosaccharides, including arabinose, glucose, galactose, glucosamine, galactosamine, muramic acid, galacturonic acid, and others.
Keyword(s):
Arctic; carbohydrates; DCCHO; DFCHO; Kongsfjorden; Ny-Ålesund; PCCHO; sea surface microlayer; seawater; SML; Svalbard
Related to:
Zeppenfeld, Sebastian (2025): Marine Carbohydrates and Other Sea Spray Aerosol Constituents Across Altitudes in the Lower Troposphere of Ny-Ålesund, Svalbard. npj Climate and Atmospheric Science
Project(s):
Funding:
German Research Foundation (DFG), grant/award no. 268020496: TRR 172: ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes, and Feedback Mechanisms
Coverage:
Median Latitude: 78.939466 * Median Longitude: 12.096350 * South-bound Latitude: 78.900100 * West-bound Longitude: 11.917980 * North-bound Latitude: 78.980020 * East-bound Longitude: 12.341250
Date/Time Start: 2021-09-28T10:00:00 * Date/Time End: 2022-05-12T13:46:00
Minimum DEPTH, water: 0.00 m * Maximum DEPTH, water: 1.00 m
Event(s):
Kongsfjorden_SML_2021 * Latitude Start: 78.900100 * Longitude Start: 12.341250 * Latitude End: 78.980020 * Longitude End: 11.917980 * Date/Time Start: 2021-09-28T00:00:00 * Date/Time End: 2021-10-02T00:00:00 * Location: Kongsfjorden, Spitsbergen, Arctic * Campaign: TROPOS_NYA_autumn_2021 * Basis: AWIPEV * Method/Device: Dinghi (DI)
Kongsfjorden_SML_2022 * Latitude Start: 78.900100 * Longitude Start: 12.341250 * Latitude End: 78.980020 * Longitude End: 11.917980 * Date/Time Start: 2022-05-04T00:00:00 * Date/Time End: 2022-05-12T00:00:00 * Location: Kongsfjorden, Spitsbergen, Arctic * Campaign: TROPOS_NYA_spring_2022 * Basis: AWIPEV * Method/Device: Dinghi (DI)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Sample IDSample IDZeppenfeld, Sebastian
2DEPTH, waterDepth watermZeppenfeld, SebastianGeocode
3DATE/TIMEDate/TimeZeppenfeld, SebastianGeocode
4LATITUDELatitudeZeppenfeld, SebastianGeocode
5LONGITUDELongitudeZeppenfeld, SebastianGeocode
6FucoseFucµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
7RhamnoseRhaµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
8ArabinoseAraµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
9GalactoseGalµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
10GlucoseGlcµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
11XyloseXylµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
12MannoseManµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
13FructoseFruµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
14Carbohydrates, dissolved, neutral freeDFCHOµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
15FucoseFucµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
16GalactosamineGalNµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
17RhamnoseRhaµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
18ArabinoseAraµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
19GlucosamineGlcNµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
20GalactoseGalµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
21GlucoseGlcµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
22XyloseXylµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
23MannoseManµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
24Muramic acidMurµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
25Galacturonic acidGalAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
26Glucuronic acidGlcAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
27Mannuronic acidManAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
28Carbohydrates, dissolved combinedDCCHOµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
29FucoseFucµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
30GalactosamineGalNµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
31RhamnoseRhaµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
32ArabinoseAraµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
33GlucosamineGlcNµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
34GalactoseGalµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
35GlucoseGlcµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
36XyloseXylµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
37MannoseManµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
38Muramic acidMurµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
39Galacturonic acidGalAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
40Glucuronic acidGlcAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
41Mannuronic acidManAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
42Carbohydrates, particulate combinedPCCHOµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
43ChlorideCl-mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
44Sulfate[SO4]2-µg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
45SodiumNa+mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
46Ammonium[NH4]+mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
47PotassiumK+mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
48MagnesiumMg2+mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
49CalciumCa2+mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
990 data points

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