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Zeppenfeld, Sebastian; Schmidt, Leon (2025): Dissolved and particulate carbohydrates and inorganic ions in the sea surface microlayer and bulk water of Kongsfjorden (Autumn 2021/Spring 2022) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.982606

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Published: 2025-05-23DOI registered: 2025-06-25

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Abstract:
Sea surface microlayer (SML) and bulk water samples were collected from various locations in Kongsfjorden (Svalbard) during autumn 2021 and spring 2022. SML samples were obtained using the glass plate method, while corresponding bulk water samples (1 m depth) were collected with a telescopic rod. The following chemical parameters were analyzed: dissolved free carbohydrates (DFCHO), dissolved combined carbohydrates (DCCHO), particulate combined carbohydrates (PCCHO), and major inorganic ions. DFCHO and DCCHO concentrations were determined from filtered seawater (0.2 µm) after desalination via electrodialysis, followed by high-performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD). PCCHO concentrations were measured from 0.2 µm polycarbonate membrane filters. All carbohydrate fractions (DFCHO, DCCHO, PCCHO) were quantified as the sum of individual monosaccharides, including arabinose, glucose, galactose, glucosamine, galactosamine, muramic acid, galacturonic acid, and others.
Keyword(s):
Arctic; carbohydrates; DCCHO; DFCHO; Kongsfjorden; Ny-Ålesund; PCCHO; sea surface microlayer; seawater; SML; Svalbard
Related to:
Zeppenfeld, Sebastian (2025): Marine Carbohydrates and Other Sea Spray Aerosol Constituents Across Altitudes in the Lower Troposphere of Ny-Ålesund, Svalbard. npj Climate and Atmospheric Science
Project(s):
Funding:
German Research Foundation (DFG), grant/award no. 268020496: TRR 172: ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes, and Feedback Mechanisms
Coverage:
Median Latitude: 78.939466 * Median Longitude: 12.096350 * South-bound Latitude: 78.900100 * West-bound Longitude: 11.917980 * North-bound Latitude: 78.980020 * East-bound Longitude: 12.341250
Date/Time Start: 2021-09-28T10:00:00 * Date/Time End: 2022-05-12T13:46:00
Minimum DEPTH, water: 0.00 m * Maximum DEPTH, water: 1.00 m
Event(s):
Kongsfjorden_SML_2021 * Latitude Start: 78.900100 * Longitude Start: 12.341250 * Latitude End: 78.980020 * Longitude End: 11.917980 * Date/Time Start: 2021-09-28T00:00:00 * Date/Time End: 2021-10-02T00:00:00 * Location: Kongsfjorden, Spitsbergen, Arctic * Campaign: TROPOS_NYA_autumn_2021 * Basis: AWIPEV * Method/Device: Dinghi (DI)
Kongsfjorden_SML_2022 * Latitude Start: 78.900100 * Longitude Start: 12.341250 * Latitude End: 78.980020 * Longitude End: 11.917980 * Date/Time Start: 2022-05-04T00:00:00 * Date/Time End: 2022-05-12T00:00:00 * Location: Kongsfjorden, Spitsbergen, Arctic * Campaign: TROPOS_NYA_spring_2022 * Basis: AWIPEV * Method/Device: Dinghi (DI)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Sample IDSample IDZeppenfeld, Sebastian
DEPTH, waterDepth watermZeppenfeld, SebastianGeocode
DATE/TIMEDate/TimeZeppenfeld, SebastianGeocode
LATITUDELatitudeZeppenfeld, SebastianGeocode
LONGITUDELongitudeZeppenfeld, SebastianGeocode
FucoseFucµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
RhamnoseRhaµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
ArabinoseAraµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
GalactoseGalµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
10 GlucoseGlcµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
11 XyloseXylµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
12 MannoseManµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
13 FructoseFruµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
14 Carbohydrates, dissolved, neutral freeDFCHOµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DFCHO
15 FucoseFucµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
16 GalactosamineGalNµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
17 RhamnoseRhaµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
18 ArabinoseAraµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
19 GlucosamineGlcNµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
20 GalactoseGalµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
21 GlucoseGlcµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
22 XyloseXylµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
23 MannoseManµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
24 Muramic acidMurµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
25 Galacturonic acidGalAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
26 Glucuronic acidGlcAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
27 Mannuronic acidManAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
28 Carbohydrates, dissolved combinedDCCHOµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)DCCHO
29 FucoseFucµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
30 GalactosamineGalNµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
31 RhamnoseRhaµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
32 ArabinoseAraµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
33 GlucosamineGlcNµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
34 GalactoseGalµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
35 GlucoseGlcµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
36 XyloseXylµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
37 MannoseManµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
38 Muramic acidMurµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
39 Galacturonic acidGalAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
40 Glucuronic acidGlcAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
41 Mannuronic acidManAµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
42 Carbohydrates, particulate combinedPCCHOµg/lZeppenfeld, SebastianHigh performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD)PCCHO
43 ChlorideCl-mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
44 Sulfate[SO4]2-µg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
45 SodiumNa+mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
46 Ammonium[NH4]+mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
47 PotassiumK+mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
48 MagnesiumMg2+mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
49 CalciumCa2+mg/lZeppenfeld, SebastianIon chromatograph, Thermo Scientific, Dionex ICS-6000
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
990 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Sample ID

Depth water [m]

Date/Time

Latitude

Longitude

Fuc [µg/l]
(DFCHO, High performance anion...)

Rha [µg/l]
(DFCHO, High performance anion...)

Ara [µg/l]
(DFCHO, High performance anion...)

Gal [µg/l]
(DFCHO, High performance anion...)
10 
Glc [µg/l]
(DFCHO, High performance anion...)
11 
Xyl [µg/l]
(DFCHO, High performance anion...)
12 
Man [µg/l]
(DFCHO, High performance anion...)
13 
Fru [µg/l]
(DFCHO, High performance anion...)
14 
DFCHO [µg/l]
(DFCHO, High performance anion...)
15 
Fuc [µg/l]
(DCCHO, High performance anion...)
16 
GalN [µg/l]
(DCCHO, High performance anion...)
17 
Rha [µg/l]
(DCCHO, High performance anion...)
18 
Ara [µg/l]
(DCCHO, High performance anion...)
19 
GlcN [µg/l]
(DCCHO, High performance anion...)
20 
Gal [µg/l]
(DCCHO, High performance anion...)
21 
Glc [µg/l]
(DCCHO, High performance anion...)
22 
Xyl [µg/l]
(DCCHO, High performance anion...)
23 
Man [µg/l]
(DCCHO, High performance anion...)
24 
Mur [µg/l]
(DCCHO, High performance anion...)
25 
GalA [µg/l]
(DCCHO, High performance anion...)
26 
GlcA [µg/l]
(DCCHO, High performance anion...)
27 
ManA [µg/l]
(DCCHO, High performance anion...)
28 
DCCHO [µg/l]
(DCCHO, High performance anion...)
29 
Fuc [µg/l]
(PCCHO, High performance anion...)
30 
GalN [µg/l]
(PCCHO, High performance anion...)
31 
Rha [µg/l]
(PCCHO, High performance anion...)
32 
Ara [µg/l]
(PCCHO, High performance anion...)
33 
GlcN [µg/l]
(PCCHO, High performance anion...)
34 
Gal [µg/l]
(PCCHO, High performance anion...)
35 
Glc [µg/l]
(PCCHO, High performance anion...)
36 
Xyl [µg/l]
(PCCHO, High performance anion...)
37 
Man [µg/l]
(PCCHO, High performance anion...)
38 
Mur [µg/l]
(PCCHO, High performance anion...)
39 
GalA [µg/l]
(PCCHO, High performance anion...)
40 
GlcA [µg/l]
(PCCHO, High performance anion...)
41 
ManA [µg/l]
(PCCHO, High performance anion...)
42 
PCCHO [µg/l]
(PCCHO, High performance anion...)
43 
Cl- [mg/l]
(Ion chromatograph, Thermo Sci...)
44 
[SO4]2- [µg/l]
(Ion chromatograph, Thermo Sci...)
45 
Na+ [mg/l]
(Ion chromatograph, Thermo Sci...)
46 
[NH4]+ [mg/l]
(Ion chromatograph, Thermo Sci...)
47 
K+ [mg/l]
(Ion chromatograph, Thermo Sci...)
48 
Mg2+ [mg/l]
(Ion chromatograph, Thermo Sci...)
49 
Ca2+ [mg/l]
(Ion chromatograph, Thermo Sci...)
Bulk 11.002021-09-28T10:00:0078.9374611.999030.000.000.080.071.530.060.000.001.742.441.402.802.081.994.729.522.050.000.000.000.000.0027.010.770.160.530.800.342.5317.478.141.980.150.000.000.0032.8621817.02772.911407.6144.4296.8768.3762.2
SML 10.002021-09-28T10:00:0078.9374611.999030.000.000.261.5513.560.210.000.0015.583.621.994.253.613.7815.4257.829.500.000.000.000.750.00100.740.900.220.811.550.998.7445.1443.659.640.290.000.000.00111.9317451.52138.58610.287.7305.1687.3539.9
Bulk 21.002021-09-29T09:20:0078.9273012.008740.000.000.000.001.200.000.000.001.203.411.693.412.542.475.7413.203.280.640.000.000.000.0036.390.880.160.420.230.331.534.851.650.930.000.000.000.0010.9918718.72335.99392.952.0324.8680.9431.6
SML 20.002021-09-29T09:20:0078.9273012.008740.000.000.110.438.460.000.000.009.003.341.974.693.673.1810.2839.225.440.000.000.000.000.0071.790.650.170.590.520.984.9520.726.312.370.000.000.000.0037.2617120.82038.28672.386.7242.3684.3291.0
Bulk 31.002021-09-29T09:40:0078.9342211.929330.000.000.000.000.870.000.000.000.873.511.563.212.332.345.4110.644.820.000.000.000.000.0033.821.210.230.530.300.451.556.731.860.630.000.000.000.0013.4917016.92112.88202.791.9261.3680.7312.1
SML 30.002021-09-29T09:40:0078.9342211.929330.000.000.070.145.210.000.000.005.423.002.004.193.772.727.9129.037.440.000.000.000.000.0060.061.230.270.750.670.933.4413.895.291.800.180.000.180.0028.6321875.28999.011155.9103.3569.51067.83716.0
Bulk 41.002021-10-02T11:30:0078.9484712.079800.000.000.000.001.610.000.000.001.612.641.622.772.422.064.8616.774.090.000.000.000.000.0037.230.620.140.390.260.241.439.203.770.740.000.000.000.0016.7919256.72473.09079.7141.9694.9816.6437.3
SML 40.002021-10-02T11:30:0078.9484712.079800.000.000.000.007.340.000.000.007.343.181.543.292.722.316.4525.384.100.000.000.000.000.0048.975.351.182.821.472.617.1630.639.033.230.430.001.190.0065.1019304.42074.29545.3352.8297.91377.02226.5
Bulk 51.002021-10-02T12:30:0078.9638812.202340.000.000.000.001.220.000.000.001.222.101.102.161.661.762.985.761.400.000.000.000.000.0018.910.570.140.330.220.271.136.621.320.420.000.000.000.0011.0221334.32521.110431.6135.2589.31070.5841.5
SML 50.002021-10-02T12:30:0078.9638812.202340.000.150.000.077.370.000.001.849.442.211.232.672.131.964.6421.711.970.000.000.000.000.0038.531.080.310.750.430.683.3817.945.281.430.000.000.000.0031.2717293.11972.69250.3103.4265.41003.81034.1
Bulk 61.002022-05-04T09:36:0078.9327511.968420.000.000.000.000.700.000.000.000.701.370.851.341.261.222.696.671.340.000.000.000.000.0016.740.840.211.343.380.333.8813.304.201.590.000.000.000.0029.0820934.02483.411102.668.2392.9771.1386.3
SML 60.002022-05-04T09:36:0078.9327511.968420.000.000.001.608.200.000.000.009.801.501.001.721.811.6112.6326.171.810.000.000.000.000.0048.251.190.261.183.130.484.2532.257.081.880.390.450.000.0052.5420634.12575.410344.164.6250.3863.5539.8
Bulk 71.002022-05-04T09:59:0078.9529511.917980.000.000.000.000.840.000.000.000.841.300.861.221.151.242.335.902.020.000.000.000.000.0016.030.510.120.712.020.172.175.302.530.690.000.000.000.0014.2021918.32746.410376.350.7301.2880.1286.0
SML 70.002022-05-04T09:59:0078.9529511.917980.000.000.000.547.770.000.000.008.311.991.104.015.941.9213.0631.356.050.000.000.000.000.0065.435.701.484.609.222.8215.1933.9311.696.160.371.151.682.0296.0020494.42477.510367.790.2250.4917.7362.1
Bulk 81.002022-05-06T12:04:0078.9222312.116320.000.000.000.000.410.000.000.000.411.290.791.250.921.231.664.011.000.000.000.000.000.0012.140.310.110.370.810.161.2810.521.650.540.000.000.000.0015.7520402.12942.910885.470.4311.3949.82093.9
SML 80.002022-05-06T12:04:0078.9222312.116320.000.000.000.003.100.000.000.003.101.590.932.042.001.494.4012.171.430.000.000.000.000.0026.060.620.210.531.050.462.1015.942.711.120.000.000.000.0024.7422118.02669.111104.4101.1527.5942.2313.0
Bulk 91.002022-05-06T12:36:0078.9347512.155620.000.000.000.000.320.000.000.000.321.230.891.291.231.612.514.281.520.000.000.000.000.0014.560.370.140.440.890.221.5824.662.800.900.000.000.000.0032.0020864.22401.911012.878.9430.8912.7930.4
SML 90.002022-05-06T12:36:0078.9347512.155620.000.000.000.001.130.000.000.001.131.461.032.292.371.915.3110.241.710.000.000.000.000.0026.340.590.170.500.910.371.8821.172.631.060.000.000.110.0029.4020811.62462.210324.6100.7584.01010.6407.5
Bulk 101.002022-05-11T11:45:0078.9800212.341020.000.000.000.000.890.000.000.000.891.290.961.291.251.263.026.241.510.000.000.000.000.0016.830.270.080.210.370.130.664.371.600.350.000.000.000.008.0424655.44046.411854.8210.4995.71015.9485.5
SML 100.002022-05-11T11:45:0078.9800212.341020.000.000.000.002.520.000.000.002.521.660.941.671.701.393.5324.271.920.000.000.000.000.0037.080.490.150.340.670.341.419.271.910.690.000.000.000.0015.2716609.41882.38372.754.0206.9672.0234.6
Bulk 111.002022-05-12T13:46:0078.9001012.341250.000.000.000.000.440.000.000.000.441.531.001.451.451.552.453.781.200.000.000.000.000.0014.400.340.100.260.550.170.826.061.560.380.000.000.000.0010.2324491.43203.012493.184.8484.9961.7333.5
SML 110.002022-05-12T13:46:0078.9001012.341250.000.000.000.001.650.000.000.001.651.561.061.761.351.563.289.561.440.000.000.000.000.0021.570.360.100.280.510.220.877.572.780.620.000.000.000.0013.3120743.22599.810632.1100.5338.3915.6277.4