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Drapeau, Hayley; Tank, Suzanne E; Cavaco, Maria; Serbu, Jessica A; St. Louis, V L; Bhatia, Maya P (2025): Organic carbon concentration, absorbance and fluorescent characteristics, and isotopic composition of river water sourced from four glacially-fed rivers in the Canadian Rocky Mountains (2019-2021) [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.975984 (DOI registration in progress)

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Published: 2025-03-07

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Abstract:
Climate change is accelerating the warming of mountain glacial systems, leading to increased water fluxes and the enhanced export of glacially-derived sediment and organic matter (OM). Glacial OM represents an aged yet potentially bioavailable carbon pool that differs in composition from OM found in non-glacially sourced waters. Despite its significance, the composition of riverine OM from glacial headwaters to downstream reaches remains poorly understood in the Canadian Rockies. This dataset presents dissolved OM composition data derived from UV-vis spectroscopy including five calculated spectroscopic parameters (a254, S275_295, BIX, HIX, FI) and model outputs from parallel factor analysis of excitation-emission spectra (C1, C2, C3, C4). This data is supplemented with dissolved and particulate organic carbon concentrations and isotopic characteristics, and water isotope data. Data were collected over three summers (2019-2021) before, during, and after glacial ice melt along stream transects spanning 0-100 km downstream of glacial termini on the eastern slopes of the Canadian Rocky Mountains. Samples were obtained from the Bow River, North Saskatchewan River, and Sunwapta-Athabasca River. Paired microbial samples are archived at the NCBI database, under accession number PRJNA995204.
Supplement to:
Drapeau, Hayley; Tank, Suzanne E; Cavaco, Maria; Serbu, Jessica A; St.Louis, Vincent; Bhatia, Maya P (in press): Shifts in organic matter character and microbial assemblages from glacial headwaters to downstream reaches in the Canadian Rocky Mountains. Biogeosciences
Drapeau, Hayley; Tank, Suzanne E; Cavaco, Maria; St.Louis, Vincent; Bhatia, Maya P; Serbu, Jessica A (preprint): Shifts in organic matter character and microbial community structure from glacial headwaters to downstream reaches in Canadian Rocky Mountain rivers. https://doi.org/10.5194/bg-2023-121
Funding:
Alberta Conservation Association, grant/award no. 030‐00‐90‐140 / 1068: Impacts of glaciers on microbial biodiversity, food webs, and carbon cycling in Banff and Jasper National Parks
Government of Canada, grant/award no. 29000-RES0046243: From the Mountains to Our Tables: Freshwater Security in Three Canadian Eastern Rocky Mountain Watersheds
Coverage:
Median Latitude: 52.128699 * Median Longitude: -117.085982 * South-bound Latitude: 51.284950 * West-bound Longitude: -118.042556 * North-bound Latitude: 52.812056 * East-bound Longitude: -115.983500
Date/Time Start: 2019-05-14T00:00:00 * Date/Time End: 2021-09-16T00:00:00
Minimum Elevation: 1060.0 m * Maximum Elevation: 2063.0 m
Event(s):
AR1_R19-25 * Latitude: 52.594869 * Longitude: -117.805439 * Date/Time: 2019-07-15T00:00:00 * Elevation: 1240.0 m * Location: Rocky Mountains, Canada * Method/Device: Sampling river (RIVER)
AR1_R19-39 * Latitude: 52.594869 * Longitude: -117.805439 * Date/Time: 2019-08-19T00:00:00 * Elevation: 1240.0 m * Location: Rocky Mountains, Canada * Method/Device: Sampling river (RIVER)
AR1_R19-53 * Latitude: 52.594869 * Longitude: -117.805439 * Date/Time: 2019-10-11T00:00:00 * Elevation: 1240.0 m * Location: Rocky Mountains, Canada * Method/Device: Sampling river (RIVER)
Comment:
Further funding information:
* Campus Alberta Innovates Program, Web: https://www.alberta.ca/campus-alberta-innovation-program, Award: Campus Alberta Innovates Program Chair funding to MPB and SET
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventTank, Suzanne E
2Latitude of eventLatitudeTank, Suzanne E
3Longitude of eventLongitudeTank, Suzanne E
4Date/Time of eventDate/TimeTank, Suzanne E
5SiteSiteTank, Suzanne E
6Sample IDSample IDTank, Suzanne E
7SeasonSeasonTank, Suzanne EMelt Season
8Year of samplingYear samplTank, Suzanne E
9DistanceDistancekmTank, Suzanne EDistance from glacier termini
10Distance descriptionDist descrTank, Suzanne E
11RiverRiverTank, Suzanne E
12Carbon, organic, dissolvedDOCmg/lTank, Suzanne EShimadzu TOC-L Total Organic Carbon Analyser series (Shimadzu TOC-L)
13Carbon, organic, particulatePOCmg/lTank, Suzanne EElement analyser CNS, vario EL Cube
14Δ14C, dissolved organic carbonΔ14C DOCTank, Suzanne Esee commentfollowing standard methods at the Andre E Lalonde AMS Laboratory (2019) and National Ocean Sciences AMS Facility (NOSAMS; 2020, 2021)
15Δ14C, particulate organic carbonΔ14C POCTank, Suzanne Esee commentfollowing standard methods at the Andre E Lalonde AMS Laboratory (2019) and National Ocean Sciences AMS Facility (NOSAMS; 2020, 2021)
16δ13C, dissolved organic carbonδ13C DOC‰ PDBTank, Suzanne ETotal Organic Carbon Analyzers, Xylem, OI Analytical Aurora 1030W TOC Analyzer [SKU: 322110] coupled to a DELTA V Plus Advantage isotope ratio mass spectrometer
17LaboratoryLabTank, Suzanne EAnalyzed at
18δ13C, particulate organic carbonδ13C POC‰ PDBTank, Suzanne Esee commentElementar vario EL cube elemental analyzer and DELTA V Plus Advantage isotope ratio mass spectrometer with ConFlo III interface
19δ18O, waterδ18O H2O‰ SMOWTank, Suzanne Esee commentPicarro L2130 isotope and gas concentration analyzer
20Δδ DeuteriumΔδDTank, Suzanne Esee commentPicarro L2130 isotope and gas concentration analyzer
21Deuterium excessd xsTank, Suzanne ECalculated according to Dansgaard (1964)
22Absorption coefficient, 254 nmac2541/mTank, Suzanne EWater Treatment Plant Analyzer, HORIBA Scientific, Aqualog
23Spectral slope of colored dissolved organic matter absorption, 275-295 nmS275-2951/nmTank, Suzanne ECalculated according to Helms et al. (2008)
24Biological indexBIXTank, Suzanne ECalculated according to Huguet et al. (2009)
25Humification indexHIXTank, Suzanne ECalculated according to Huguet et al. (2009)
26Fluorescence indexFITank, Suzanne ECalculated according to McKnight et al. (2001)
27Fluorescence intensity, parallel factor analysis component 1Fluorescence intens PARAFAC C1RUTank, Suzanne EParallel factor fluorescence spectroscopy (PARAFAC) according to Murphy et al. (2013)As proportion of total peak fluorescence
28Fluorescence intensity, parallel factor analysis component 2Fluorescence intens PARAFAC C2RUTank, Suzanne EParallel factor fluorescence spectroscopy (PARAFAC) according to Murphy et al. (2013)As proportion of total peak fluorescence
29Fluorescence intensity, parallel factor analysis component 3Fluorescence intens PARAFAC C3RUTank, Suzanne EParallel factor fluorescence spectroscopy (PARAFAC) according to Murphy et al. (2013)As proportion of total peak fluorescence
30Fluorescence intensity, parallel factor analysis component 4Fluorescence intens PARAFAC C4RUTank, Suzanne EParallel factor fluorescence spectroscopy (PARAFAC) according to Murphy et al. (2013)As proportion of total peak fluorescence
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
4701 data points

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