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Arosio, Tito; Nicolussi, Kurt; Moseley, Gina Elaine; Nyfeler, Peter; Pilcher, Thomas; Smith, M Paul; Hajdas, Irka; Leuenberger, Markus Christian (2024): Greenland triple tree ring isotope records [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.974034 (DOI registration in progress)

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Abstract:
Stable isotope ratios from tree rings are important proxies of past climate variations. We have analysed non-dated wood material from a larch (Larix sp.) recovered from glacial tills in the valley bottom of Grottedal, Kronprins Christian Land, North-East Greenland National Park (80.3°N, 21.5°W). The wood samples were radiocarbon dated using AMS 14C analysis at ETH Zürich. Results indicate that the samples are older than 48.5 ka and 49.7 ka BP. We analysed the δ13C, δ18O and δ2H isotope ratios of alpha-cellulose obtained from blocks of 10 annual rings for the Greenland sample and annual rings for the Iceland sample. Cellulose was extracted following the modified Jayme-Wise method (Boettger et al., 2007). The isotopes values were determined using conventional Isotope Ratio Mass Spectrometry (Isoprime 100) coupled to a pyrolysis unit (HEKAtech GmbH, Germany), which is similar to the previously used TC/EA (for technical details see (Leuenberger, 2007). This approach was extended to measurements of non-exchangeable hydrogen of alpha-cellulose using the on-line equilibration method (Filot et al., 2006; Loader et al., 2015). The results are reported in per mil (‰) relative to the Vienna Pee Dee Belemnite (VPDB) for carbon and to Vienna Standard Mean Ocean Water (VSMOW) for hydrogen and oxygen (Coplen, 1994).
Keyword(s):
Carbon stable isotopes; Greenland; Hydrogen stable isotopes; Larch; Larix; Oxygen stable isotopes; Tree ring; Tree ring isotopes
Related to:
Arosio, Tito; Büntgen, Ulf; Nicolussi, Kurt; Moseley, Gina Elaine; Saurer, Matthias; Pilcher, Thomas; Smith, M Paul; Gutierrez, Emilia; Andreu-Hayles, Laia; Hajdas, Irka; Leuenberger, Markus Christian; Bebchuck, Tatiana (accepted): Tree-ring δ18O and δ2H stable isotopes reflect the Global Meteoric Water Line. Frontiers in Earth Science, https://doi.org/10.3389/feart.2024.1440064
References:
Boettger, Tatjana; Haupt, Marika; Knöller, Kay; Weise, Stephan M; Waterhouse, John S; Rinne, Katja T; Loader, Neil J; Sonninen, Eloni; Jungner, H; Masson-Delmotte, Valerie; Stievenard, Michel; Guillemin, Marie-Thérèse; Pierre, Monique; Pazdur, A; Leuenberger, Markus Christian; Filot, Marc S; Saurer, Matthias; Reynolds, Christina E; Helle, Gerd; Schleser, Gerhard Hans (2007): Wood Cellulose Preparation Methods and Mass Spectrometric Analyses of δ 13 C, δ 18 O, and Nonexchangeable δ 2 H Values in Cellulose, Sugar, and Starch: An Interlaboratory Comparison. Analytical Chemistry, 79(12), 4603-4612, https://doi.org/10.1021/ac0700023
Coplen, Tyler B (1994): Reporting of stable hydrogen, carbon, and oxygen isotopic abundances (Technical Report). Pure and Applied Chemistry, 66(2), 273-276, https://doi.org/10.1351/pac199466020273
Filot, Marc S; Leuenberger, Markus Christian; Pazdur, A; Boettger, Tatjana (2006): Rapid online equilibration method to determine the D/H ratios of non‐exchangeable hydrogen in cellulose. Rapid Communications in Mass Spectrometry, 20(22), 3337-3344, https://doi.org/10.1002/rcm.2743
Leuenberger, Markus Christian (2007): To What Extent Can Ice Core Data Contribute to the Understanding of Plant Ecological Developments of the Past? In: Stable Isotopes as Indicators of Ecological Change, Terrestrial Ecology, 1, Elsevier, 211-233, https://doi.org/10.1016/S1936-7961(07)01014-7
Loader, Neil J; Street-Perrott, F Alayne; Daley, Timothy J; Hughes, Paul D M; Kimak, A; Levanič, T; Mallon, Gunnar; Mauquoy, Dmitri; Robertson, Iain; Roland, Thomas P; van Bellen, Simon; Ziehmer, M M; Leuenberger, Markus Christian (2015): Simultaneous Determination of Stable Carbon, Oxygen, and Hydrogen Isotopes in Cellulose. Analytical Chemistry, 87(1), 376-380, https://doi.org/10.1021/ac502557x
Additional metadata:
Funding:
Austrian Science Fund (FWF), grant/award no. 10.55776/Y1162: Northeast Greenland Speleothem project
Austrian Science Fund (FWF), grant/award no. I-1183-N19: Alpine Holocene Triple Tree Ring Isotope Record
Greenland National Museum & Archives, grant/award no. 2019/01: Greenland National Museum and Archives 2019/01
Greenland National Museum & Archives, grant/award no. C-19-32: KNNO Expedition Permit C-19-32
Greenland National Museum & Archives, grant/award no. VU-00150: Scientific Survey Licence VU-00150
Swiss National Science Foundation (SNF), grant/award no. SNF 200020_172550: Klima- und Umweltphysik: Isotope im Erdklimasystem (icoCEP)
Swiss National Science Foundation (SNF), grant/award no. SNF 200021L_144255: Alpine Jahrringisotopen Zeitreihen im Holozän
Swiss National Science Foundation (SNF), grant/award no. SNF P500PN 210716: Advanced studies of Tree-ring stable isoTopes for pAleoClimate - ATTAC
Coverage:
Latitude: 80.300000 * Longitude: -21.500000
Date/Time Start: 2019-07-07T00:00:00 * Date/Time End: 2019-07-07T00:00:00
Minimum Elevation: 326.0 m * Maximum Elevation: 326.0 m
Event(s):
Grottedal * Latitude: 80.300000 * Longitude: -21.500000 * Date/Time: 2019-07-07T00:00:00 * Elevation: 326.0 m * Location: Kronprins Christian Land, North-East Greenland National Park * Method/Device: Sampling by hand (HAND)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1AGEAgeka BPArosio, TitoGeocode
2Cambial years, rangeCambial yearsArosio, Tito
3CelluloseCellulose%Arosio, Tito
4Larix sp., δDLarix sp. δD‰ SMOWArosio, TitoIsoprime 100 dual inlet mass spectrometervs. VSMOW
5Larix sp., δ13CLarix sp. δ13C‰ PDBArosio, TitoIsoprime 100 dual inlet mass spectrometer
6Larix sp., δ18OLarix sp. δ18O‰ SMOWArosio, TitoIsoprime 100 dual inlet mass spectrometervs. VSMOW
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
200 data points

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