Citation:

PANGAEA.973656

Name: Metal distribution for sediment samples of the cruise AT004
Published: 2024-11-29
License: https://creativecommons.org/licenses/by/4.0/

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Published: 2024-11-29 • DOI registered: 2024-12-28

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Abstract:

Offshore wind energy is a steadily growing sector contributing to the worldwide energy production. The impact of these offshore constructions on the marine environment, however, remains unclear in many aspects. In fact, little is known about potential emissions from corrosion protection systems such as organic coatings or galvanic anodes composed of Al and Zn alloys, used to protect offshore structures. In order to assess potential chemical emissions from offshore wind farms and their impact on the marine environment water and sediment were taken in and around offshore wind farms of the German Bight between 12.04.2021 and 23.04.2021 within the context of the Hereon-BSH project OffChEm II. The surface sediment samples were taken by a box grab, homogenized, freeze-dried and wet-sieved to gain the <20 µm grain size fraction. The <20 µm grain size fraction was acid digested and measured by ICP-MS/MS for their (trace) metal mass fractions.

Related to:

Ebeling, Anna; Wippermann, Dominik; Zimmermann, Tristan; Klein, Ole; Kirchgeorg, Torben; Weinberg, Ingo; Hasenbein, Simone; Plaß, Anna; Pröfrock, Daniel (2023): Investigation of potential metal emissions from galvanic anodes in offshore wind farms into North Sea sediments. Marine Pollution Bulletin, 194, 115396, https://doi.org/10.1016/j.marpolbul.2023.115396

Hasenbein, Simone; Zimmermann, Tristan; Klein, Ole; de la Granda Grandoso, Francisco; Köllner, Manuela; Schneehorst, Anja (2024): Oceanographic parameters for the sample stations of the cruise AT004 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.973582

Klein, Ole; Zimmermann, Tristan; Pröfrock, Daniel (2021): Improved determination of technologically critical elements in sediment digests by ICP-MS/MS using N2O as a reaction gas. Journal of Analytical Atomic Spectrometry, 36(7), 1524-1532, https://doi.org/10.1039/D1JA00088H

Wippermann, Dominik; Pieper, Andrea; Zimmermann, Tristan; Klein, Ole; Pröfrock, Daniel: Trace metal distribution for water samples of the cruise AT004 [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.973612

Wippermann, Dominik; Zimmermann, Tristan; Klein, Ole; Pröfrock, Daniel (2024): Grain size distribution for sediment samples of the cruise AT004 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.973616

Zimmermann, Tristan; von der Au, Marcus; Reese, Anna; Klein, Ole; Hildebrandt, Lars; Pröfrock, Daniel (2020): Substituting HF by HBF 4 – an optimized digestion method for multi-elemental sediment analysis via ICP-MS/MS. Analytical Methods, 12(30), 3778-3787, https://doi.org/10.1039/D0AY01049A

Project(s):

Helmholtz-Zentrum Hereon (Hereon)

Coverage:

Median Latitude: 54.552763 * Median Longitude: 6.618340 * South-bound Latitude: 53.523016 * West-bound Longitude: 3.343307 * North-bound Latitude: 55.921855 * East-bound Longitude: 8.718262

Date/Time Start: 2021-04-13T07:48:00 * Date/Time End: 2021-04-20T09:19:00

Minimum DEPTH, sediment/rock: 0 m * Maximum DEPTH, sediment/rock: 0 m

Event(s):

AT004_Stat_S_001_BC (AT004_Stat_S_001) * Latitude: 53.883232 * Longitude: 8.718262 * Date/Time: 2021-04-13T07:48:00 * Location: German Bight * Campaign: (AT004) * Basis: Atair * Method/Device: Box corer (BC)

AT004_Stat_S_002_BC (AT004_Stat_S_002) * Latitude: 54.066585 * Longitude: 8.127276 * Date/Time: 2021-04-13T19:42:00 * Elevation: -20.5 m * Location: German Bight * Campaign: (AT004) * Basis: Atair * Method/Device: Box corer (BC)

AT004_Stat_S_003_BC (AT004_Stat_S_003) * Latitude: 54.073998 * Longitude: 7.175509 * Date/Time: 2021-04-14T06:33:00 * Elevation: -35.0 m * Location: German Bight * Campaign: (AT004) * Basis: Atair * Method/Device: Box corer (BC)

Parameter(s):

#	Name	Short Name	Unit	Method/Device	Comment
1	Event label	Event
2	Sample code/label	Sample label
3	International Generic Sample Number	IGSN
4	Optional event label	Event 2
5	Station label	Station
6	DEPTH, sediment/rock	Depth sed	m		Geocode
7	Latitude of event	Latitude
8	Longitude of event	Longitude
9	Date/Time of event	Date/Time
10	Method/Device of event	Method/Device
11	Elevation of event	Elevation	m
12	Chromium	Cr	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
13	Chromium, limit of detection	Cr LOD	µg/kg
14	Chromium, limit of quantification	Cr LOQ	µg/kg
15	Chromium, uncertainty	Cr unc	±
16	Cobalt	Co	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
17	Cobalt, limit of detection	Co LOD	µg/kg
18	Cobalt, limit of quantification	Co LOQ	µg/kg
19	Cobalt, uncertainty	Co unc	±
20	Nickel	Ni	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
21	Nickel, limit of detection	Ni LOD	µg/kg
22	Nickel, limit of quantification	Ni LOQ	µg/kg
23	Nickel, uncertainty	Ni unc	±
24	Copper	Cu	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
25	Copper, limit of detection	Cu LOD	µg/kg
26	Copper, limit of quantification	Cu LOQ	µg/kg
27	Copper, uncertainty	Cu unc	±
28	Zinc	Zn	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
29	Zinc, limit of detection	Zn LOD	µg/kg
30	Zinc, limit of quantification	Zn LOQ	µg/kg
31	Zinc, uncertainty	Zn unc	±
32	Gallium	Ga	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
33	Gallium, limit of detection	Ga LOD	µg/kg
34	Gallium, limit of quantification	Ga LOQ	µg/kg
35	Gallium, uncertainty	Ga unc	±
36	Aluminium	Al3+	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
37	Aluminium, limit of detection	Al LOD	µg/kg
38	Aluminium, limit of quantification	Al LOQ	µg/kg
39	Aluminium, uncertainty	Al unc	±
40	Potassium	K+	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
41	Potassium, limit of detection	K LOD	µg/kg
42	Potassium, limit of quantification	K LOQ	µg/kg
43	Potassium, uncertainty	K unc	±
44	Calcium	Ca	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
45	Calcium, limit of detection	Ca LOD	µg/kg
46	Calcium, limit of quantification	Ca LOQ	µg/kg
47	Calcium, uncertainty	Ca unc	±
48	Magnesium	Mg	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
49	Magnesium, limit of detection	Mg LOD	µg/kg
50	Magnesium, limit of quantification	Mg LOQ	µg/kg
51	Magnesium, uncertainty	Mg unc	±
52	Iron	Fe	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
53	Iron, limit of detection	Fe LOD	µg/kg
54	Iron, limit of quantification	Fe LOQ	µg/kg
55	Iron, uncertainty	Fe unc	±
56	Manganese	Mn	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
57	Manganese, limit of detection	Mn LOD	µg/kg
58	Manganese, limit of quantification	Mn LOQ	µg/kg
59	Manganese, uncertainty	Mn unc	±
60	Barium	Ba	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
61	Barium, limit of detection	Ba LOD	µg/kg
62	Barium, limit of quantification	Ba LOQ	µg/kg
63	Barium, uncertainty	Ba unc	±
64	Thulium	Tm	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
65	Thulium, limit of detection	Tm LOD	µg/kg
66	Thulium, limit of quantification	Tm LOQ	µg/kg
67	Thulium, uncertainty	Tm unc	±
68	Ytterbium	Yb	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
69	Ytterbium, limit of detection	Yb LOD	µg/kg
70	Ytterbium, limit of quantification	Yb LOQ	µg/kg
71	Ytterbium, uncertainty	Yb unc	±
72	Lutetium	Lu	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
73	Lutetium, limit of detection	Lu LOD	µg/kg
74	Lutetium, limit of quantification	Lu LOQ	µg/kg
75	Lutetium, uncertainty	Lu unc	±
76	Tantalum	Ta	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
77	Tantalum, limit of detection	Ta LOD	µg/kg
78	Tantalum, limit of quantification	Ta LOQ	µg/kg
79	Tantalum, uncertainty	Ta unc	±
80	Lithium	Li	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
81	Lithium, limit of detection	Li LOD	µg/kg
82	Lithium, limit of quantification	Li LOQ	µg/kg
83	Lithium, uncertainty	Li unc	±
84	Selenium	Se	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
85	Selenium, limit of detection	Se LOD	µg/kg
86	Selenium, limit of quantification	SeLOQ	µg/kg
87	Selenium, uncertainty	Se	±
88	Gadolinium	Gd	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
89	Gadolinium, limit of detection	Gd LOD	µg/kg
90	Gadolinium, limit of quantification	Gd LOQ	µg/kg
91	Gadolinium, uncertainty	Gd unc	±
92	Terbium	Tb	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
93	Terbium, limit of detection	Tb LOD	µg/kg
94	Terbium, limit of quantification	Tb LOQ	µg/kg
95	Terbium, uncertainty	Tb unc	±
96	Dysprosium	Dy	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
97	Dysprosium, limit of detection	Dy LOD	µg/kg
98	Dysprosium, limit of quantification	Dy LOQ	µg/kg
99	Dysprosium, uncertainty	Dy unc	±
100	Holmium	Ho	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
101	Holmium, limit of detection	Ho LOD	µg/kg
102	Holmium, limit of quantification	Ho LOQ	µg/kg
103	Holmium, uncertainty	Ho unc	±
104	Erbium	Er	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
105	Erbium, limit of detection	Er LOD	µg/kg
106	Erbium, limit of quantification	Er LOQ	µg/kg
107	Erbium, uncertainty	Er unc	±
108	Zirconium	Zr	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
109	Zirconium, limit of detection	Zr LOD	µg/kg
110	Zirconium, limit of quantification	Zr LOQ	µg/kg
111	Zirconium, uncertainty	Zr unc	±
112	Lanthanum	La	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
113	Lanthanum, limit of detection	La LOD	µg/kg
114	Lanthanum, limit of quantification	La LOQ	µg/kg
115	Lanthanum, uncertainty	La unc	±
116	Europium	Eu	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
117	Europium, limit of detection	Eu LOD	µg/kg
118	Europium, limit of quantification	Eu LOQ	µg/kg
119	Europium, uncertainty	Eu unc	±
120	Niobium	Nb	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
121	Niobium, limit of detection	Nb LOD	µg/kg
122	Niobium, limit of quantification	Nb LOQ	µg/kg
123	Niobium, uncertainty	Nb unc	±
124	Cerium	Ce	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
125	Cerium, limit of detection	Ce LOD	µg/kg
126	Cerium, limit of quantification	Ce LOQ	µg/kg
127	Cerium, uncertainty	Ce unc	±
128	Praseodymium	Pr	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
129	Praseodymium, limit of detection	Pr LOD	µg/kg
130	Praseodymium, limit of quantification	Pr LOQ	µg/kg
131	Praseodymium, uncertainty	Pr unc	±
132	Neodymium	Nd	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
133	Neodymium, limit of detection	Nd LOD	µg/kg
134	Neodymium, limit of quantification	Nd LOQ	µg/kg
135	Neodymium, uncertainty	Nd unc	±
136	Samarium	Sm	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
137	Samarium, limit of detection	Sm LOD	µg/kg
138	Samarium, limit of quantification	Sm LOQ	µg/kg
139	Samarium, uncertainty	Sm unc	±
140	Thorium	Th	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
141	Thorium, limit of detection	Th LOD	µg/kg
142	Thorium, limit of quantification	Th LOQ	µg/kg
143	Thorium, uncertainty	Th unc	±
144	Uranium	U	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
145	Uranium, limit of detection	U LOD	µg/kg
146	Uranium, limit of quantification	U LOQ	µg/kg
147	Uranium, uncertainty	U unc	±
148	Phosphorus	P	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
149	Phosphorus, limit of detection	P LOD	µg/kg
150	Phosphorus, limit of quantification	PLOQ	µg/kg
151	Phosphorus, uncertainty	P unc	±
152	Scandium	Sc	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
153	Scandium, limit of detection	Sc LOD	µg/kg
154	Scandium, limit of quantification	Sc LOQ	µg/kg
155	Scandium, uncertainty	Sc unc	±
156	Titanium	Ti	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
157	Titanium, limit of detection	Ti LOD	µg/kg
158	Titanium, limit of quantification	Ti LOQ	µg/kg
159	Titanium, uncertainty	Ti unc	±
160	Vanadium	V	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
161	Vanadium, limit of detection	V LOD	µg/kg
162	Vanadium, limit of quantification	V LOQ	µg/kg
163	Vanadium, uncertainty	V unc	±
164	Indium	In	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
165	Indium, limit of detection	In LOD	µg/kg
166	Indium, limit of quantification	In LOQ	µg/kg
167	Indium, uncertainty	In unc	±
168	Antimony	Sb	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
169	Antimony, limit of detection	Sb LOD	µg/kg
170	Antimony, limit of quantification	Sb LOQ	µg/kg
171	Antimony, uncertainty	Sb unc	±
172	Caesium	Cs	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
173	Caesium, limit of detection	Cs LOD	µg/kg
174	Caesium, limit of quantification	Cs LOQ	µg/kg
175	Caesium, uncertainty	Cs unc	±
176	Thallium	Tl	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
177	Thallium, limit of detection	Tl LOD	µg/kg
178	Thallium, limit of quantification	Tl LOQ	µg/kg
179	Thallium, uncertainty	Tl unc	±
180	Lead	Pb	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
181	Lead, limit of detection	Pb LOD	µg/kg
182	Lead, limit of quantification	Pb LOQ	µg/kg
183	Lead, uncertainty	Pb unc	±
184	Bismuth	Bi	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
185	Bismuth, limit of detection	Bi LOD	µg/kg
186	Bismuth, limit of quantification	Bi LOQ	µg/kg
187	Bismuth, uncertainty	Bi unc	±
188	Germanium	Ge	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
189	Germanium, limit of detection	Ge LOD	µg/kg
190	Germanium, limit of quantification	Ge LOQ	µg/kg
191	Germanium, uncertainty	Ge unc	±
192	Arsenic	As	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
193	Arsenic, limit of detection	As LOD	µg/kg
194	Arsenic, limit of quantification	As LOQ	µg/kg
195	Arsenic, uncertainty	As unc	±
196	Rubidium	Rb	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
197	Rubidium, limit of detection	Rb LOD	µg/kg
198	Rubidium, limit of quantification	Rb LOQ	µg/kg
199	Rubidium, uncertainty	Rb unc	±
200	Strontium	Sr	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
201	Strontium, limit of detection	Sr LOD	µg/kg
202	Strontium, limit of quantification	Sr LOQ	µg/kg
203	Strontium, uncertainty	Sr unc	±
204	Molybdenum	Mo	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
205	Molybdenum, limit of detection	Mo LOD	µg/kg
206	Molybdenum, limit of quantification	Mo LOQ	µg/kg
207	Molybdenum, uncertainty	Mo unc	±
208	Cadmium	Cd	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
209	Cadmium, limit of detection	Cd LOD	µg/kg
210	Cadmium, limit of quantification	Cd LOQ	µg/kg
211	Cadmium, uncertainty	Cd unc	±
212	Tungsten	W	µg/kg	Element analysis grain size fraction < 20 microns via ICP-MS (total digest)	measured in sediment, <20 µm
213	Tungsten, limit of detection	W LOD	µg/kg
214	Tungsten, limit of quantification	W LOQ	µg/kg
215	Tungsten, uncertainty	W unc	±

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Status:

Curation Level: Enhanced curation (CurationLevelC)

Size:

8760 data points

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Datasets with similar metadata

Wippermann, D; Petrauskas, C; Faust, S et al. (2025): Metal distribution for sediment samples of the cruise AT010. https://doi.org/10.1594/PANGAEA.973676
Ebeling, A; Petrauskas, C; Kruse, M et al. (2023): Metal distribution for sediment samples of Ludwig Prandtl cruise LP20200629. https://doi.org/10.1594/PANGAEA.963886
Wippermann, D; Pieper, A; Zimmermann, T et al. (2025): Trace metal distribution for water samples of the cruise AT004. https://doi.pangaea.de/10.1594/PANGAEA.973612

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