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Santos, Ricardo N; Rodrigues, Teresa; Naughton, Filipa; Schefuß, Enno; Oliveira, Dulce; Moreno, João; Raposeiro, Pedro Miguel; Gil-Romera, Graciela; Morgan, Alistair; Leira, M; Domingues Gomes, Sandra; Ladd, S N; Trigo, Ricardo M; Ramos, Alexandre M; Hernández, Armand (2024): Plant wax biomarkers record from sediment core PEX19-01, Lake Peixão, Serra da Estrela, Portugal [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.972149

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Abstract:
These data comprise a downcore record (PEX19-01) of plant wax n-alkanes (concentration and compound-specific δ2H and δ13C isotopes) from Lake Peixão (40°20'35" N, 7°36'19" W), a small alpine lake located at 1677 meters above sea level in the Serra da Estrela Mountain, Portugal. The lake covers an area of 0.02 km² with a maximum water depth of approximately 5 meters. Characterized as oligotrophic, slightly acidic, and monomictic, Lake Peixão's settings and location present an ideal setting for paleoenvironmental studies between Atlantic and Mediterranean-influenced climates. Sediment cores were collected at a depth of about 4 meters during a field campaign from June 10 to June 14, 2019, using a UWITEC© piston coring system from a floating platform, and a short core (PEX15-01C; 1.23 m long) using a UWITEC gravity coring system (see Moreno et al., 2023). According to the age model by Hernández et al., 2023, the studied section of the sediment core (upper 120 cm) spans the last 2000 years with a mean resolution of 30 ± 10 years for n-alkane samples.
This study aims to reconstruct past vegetation and climate dynamics in western Iberia and to address the lack of long-term climate data. It focuses on understanding the interactions between Mediterranean and Atlantic influences on Western Iberia during key climatic periods such as the Roman Period, Early Middle Ages, Medieval Climate Anomaly, Little Ice Age, and the Industrial Era to the present day. This knowledge is crucial for predicting future climate scenarios and understanding the adaptive responses of alpine ecosystems to climatic variability.
The sediment samples were collected every 2 cm, resulting in 60 samples weighing between 0.4 and 0.6 grams each. Plant-wax n-alkanes were extracted and analyzed at the BioGeoChemistry Lab, IPMA in Lisbon, Portugal. The total lipid extracts underwent various purification and analysis steps, including ultrasonic bath extraction, hydrolysis with potassium hydroxide in methanol, and separation using silica gel columns. Concentrations were measured using gas chromatography with flame ionization detection (GC-FID). Compound-specific isotope analyses (δ13C n-alk and δ2H n-alk) were conducted using gas chromatography-isotope ratio mass spectrometry (GC-IRMS) at MARUM, University of Bremen, Germany (see Santos et al., 2022).
Keyword(s):
Lake Peixão; lake sediments; last 2000 years; leaf waxes; lipid biomarkers; Mediterranean mountain; mountain lakes; n-alkanes; North Atlantic; Organic Geochemistry; Paleoclimate; plant waxes; Portugal; Serra da Estrela; Stable carbon and hydrogen isotopes of plant-waxes; Western Iberia
Supplement to:
Santos, Ricardo N; Rodrigues, Teresa; Naughton, Filipa; Schefuß, Enno; Oliveira, Dulce; Moreno, João; Raposeiro, Pedro Miguel; Gil-Romera, Graciela; Morgan, Alistair; Leira, M; Gomes, Sandra D; Ladd, S N; Trigo, Ricardo M; Ramos, Alexandre M; Hernández, Armand (2024): Understanding the Atlantic influence on climate and vegetation dynamics in western Iberia over the last 2000 years. Quaternary Science Reviews, 337, 108796, https://doi.org/10.1016/j.quascirev.2024.108796
Funding:
Coverage:
Latitude: 40.343044 * Longitude: -7.605371
Date/Time Start: 2019-06-10T00:00:00 * Date/Time End: 2019-06-10T00:00:00
Minimum DEPTH, sediment/rock: 0.00 m * Maximum DEPTH, sediment/rock: 1.20 m
Event(s):
PEX19-01 * Latitude: 40.343044 * Longitude: -7.605371 * Date/Time: 2019-06-10T00:00:00 * Elevation: 1677.0 m * Lake water depth: 5 m * Method/Device: Gravity corer, UWITEC (GCUWI)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1DEPTH, sediment/rockDepth sedmSantos, Ricardo NGeocode
2AGEAgeka BPSantos, Ricardo NGeocode – cal. kiloyears before present (1950 CE)
3Calendar age, medianCal age mediana AD/CESantos, Ricardo N
4δ Deuterium, n-alkanes, C25δD n-alkanes C25Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
5δ Deuterium, n-alkanes, C25, standard deviationδD n-alkanes C25 std dev±Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
6δ Deuterium, n-alkanes, C27δD n-alkanes C27Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
7δ Deuterium, n-alkanes, C27, standard deviationδD n-alkanes C27 std dev±Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
8δ Deuterium, n-alkanes, C29δD n-alkanes C29Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
9δ Deuterium, n-alkanes, C29, standard deviationδD n-alkanes C29 std dev±Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
10δ Deuterium, n-alkanes, C31δD n-alkanes C31Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
11δ Deuterium, n-alkanes, C31, standard deviationδD n-alkanes C31 std dev±Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
12δ Deuterium, n-alkanes, C33δD n-alkanes C33Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
13δ Deuterium, n-alkanes, C33, standard deviationδD n-alkanes C33 std dev±Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
14n-Alkane C25, δ13CC25 δ13C‰ PDBSantos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
15n-Alkane C25, δ13C, standard deviationC25 δ13C std dev±Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
16n-Alkane C27, δ13CC27 δ13C‰ PDBSantos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
17n-Alkane C27, δ13C, standard deviationC27 δ13C std dev±Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
18n-Alkane C29, δ13CC29 δ13C‰ PDBSantos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
19n-Alkane C29, δ13C, standard deviationC29 δ13C std dev±Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
20n-Alkane C31, δ13CC31 δ13C‰ PDBSantos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
21n-Alkane C31, δ13C, standard deviationC31 δ13C std dev±Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
22n-Alkane C33, δ13CC33 δ13C‰ PDBSantos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
23n-Alkane C33, δ13C, standard deviationC33 δ13C std dev±Santos, Ricardo NGas chromatography - isotope ratio mass spectrometry (GC-IRMS)
24Average chain length, n-Alkanes, C27-C33ACL 27-33Santos, Ricardo N
25Carbon Preference Index, n-Alkanes (C27-C33)CPI 27-33Santos, Ricardo N
26Aquatic portionPaqSantos, Ricardo N
27n-Alkane C17C17ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
28n-Alkane C18C18ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
29n-Alkane C19C19ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
30n-Alkane C20C20ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
31n-Alkane C21C21ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
32n-Alkane C22C22ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
33n-Alkane C23C23ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
34n-Alkane C24C24ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
35n-Alkane C25C25ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
36n-Alkane C26C26ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
37n-Alkane C27C27ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
38n-Alkane C28C28ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
39n-Alkane C29C29ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
40n-Alkane C30C30ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
41n-Alkane C31C31ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
42n-Alkane C32C32ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
43n-Alkane C33C33ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
44n-Alkane C34C34ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
45n-Alkane C35C35ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)
46n-Alkane C36C36ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)internal standard
47n-Alkane C40C40ng/gSantos, Ricardo NGas chromatography - Flame Ionization Detection (GC-FID)internal standard
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
2221 data points

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