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Wei, Bingbing; Mollenhauer, Gesine; Grotheer, Hendrik; Holtappels, Moritz: Molecular composition of surface and bottom water solid-phase extraction extracted dissolved organic matter in the Irish Shelf of the North Atlantic during RV MARIA S. MERIAN cruise MSM107 [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.969105 (dataset in review)

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Abstract:
In May 2022, 2 surface water and 7 bottom water samples were collected with a Sea-Bird CTD rosette water sampler during the cruise MSM107 from the Northwest Irish Shelf. These water samples were first filtered through 0.4 μm glass fibre filters to remove particles on broad, from which dissolved organic matter (DOM) was extracted using solid-phase extraction (SPE). The SPE extracted DOM (SPE-DOM) were analyzed for 13C and 14C compositions using an isotope ratio mass spectrometer and a mini carbon dating system (MICADAS), respectively (doi:10.1594/PANGAEA.969095). The SPE-DOM were also analyzed for molecular composition using Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR-MS). Based on these analyses, we aim to understand the distribution pattern, dynamics, and transformation of DOM during its downslope transport, confirming the significance of DOC exported by lateral transport in the ocean's carbon cycle. Detailed dataset interpretation can be found in Wei et al. (2024, in preparation).
Keyword(s):
bottom water; FT-ICR-MS; Irish shelf; SPE-DOM
Related to:
Wei, Bingbing; Mollenhauer, Gesine; Grotheer, Hendrik; Holtappels, Moritz: Isotope composition of surface and bottom water solid-phase extraction extracted dissolved organic matter in the Irish Shelf of the North Atlantic during RV MARIA S. MERIAN cruise MSM107 [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.969095
Funding:
German Research Foundation (DFG), grant/award no. 390741603: EXC 2077: The Ocean Floor – Earth's Uncharted Interface
Coverage:
Median Latitude: 55.313798 * Median Longitude: -10.029722 * South-bound Latitude: 54.946383 * West-bound Longitude: -10.638433 * North-bound Latitude: 55.703300 * East-bound Longitude: -9.591650
Date/Time Start: 2022-05-21T00:00:00 * Date/Time End: 2022-05-29T00:00:00
Minimum Elevation: -2525.0 m * Maximum Elevation: -119.0 m
Event(s):
MSM107_1-2 (GeoB24801-2) * Latitude: 55.298590 * Longitude: -10.638950 * Date/Time: 2022-05-21T11:09:02 * Elevation: -2525.0 m * O2A Registry URI: sensor.awi.de * Location: North Atlantic Ocean * Campaign: MSM107 (ORGMAT) * Basis: Maria S. Merian * Method/Device: CTD/Rosette (CTD-RO)
MSM107_3-1 (GeoB24803-1) * Latitude: 54.946370 * Longitude: -9.829770 * Date/Time: 2022-05-21T21:22:26 * Elevation: -119.0 m * O2A Registry URI: sensor.awi.de * Location: North Atlantic Ocean * Campaign: MSM107 (ORGMAT) * Basis: Maria S. Merian * Method/Device: CTD/Rosette (CTD-RO)
MSM107_7-1 (GeoB24807-1) * Latitude: 55.145290 * Longitude: -10.287850 * Date/Time: 2022-05-23T12:07:13 * Elevation: -1620.0 m * O2A Registry URI: sensor.awi.de * Location: North Atlantic Ocean * Campaign: MSM107 (ORGMAT) * Basis: Maria S. Merian * Method/Device: CTD/Rosette (CTD-RO)
Comment:
NEG-IDEG: peak magnitudes of 5 compounds strongly negatively correlated with SPE-DOC Δ14C
POS-IDEG: peak magnitudes of 5 compounds strongly positively correlated with SPE-DOC Δ14C
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventWei, BingbingMSM107 station label
2Sample IDSample IDWei, Bingbingused in related paper
3Station labelStationWei, Bingbingstation name: O = open ocean station, S = shelf station, T = transect
4Station labelStationWei, BingbingGeoB station label
5LATITUDELatitudeWei, BingbingGeocode
6LONGITUDELongitudeWei, BingbingGeocode
7DATE/TIMEDate/TimeWei, BingbingGeocode
8ELEVATIONElevationm a.s.l.Wei, BingbingGeocode
9DEPTH, waterDepth watermWei, BingbingGeocode
10TypeTypeWei, Bingbing
11Number of compoundsCompounds#Wei, Bingbing
12Mass of molecular formulasm/zWei, Bingbing
13Double bond equivalentDBEWei, Bingbing
14Aromaticity index, modifiedAI modWei, Bingbing
15Hydrogen/Carbon ratioH/CWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
16Oxygen/Carbon ratioO/CWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
17Compounds, highly aromaticHAC%Wei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
18Compounds, highly unsaturatedComp h unsaturated%Wei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
19Carboxyl-rich alicyclic moleculesCRAM%Wei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
20Compounds, unsatuared aliphatic and peptide-likeUA+Peptide%Wei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
21Compounds, saturatedComp saturated%Wei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
22Degradation indexDIWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
23Terrigenous indexTerrigenous IWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
24ProportionProp%Wei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)of NEG-IDEG (%, n=5)
25ProportionProp%Wei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)of POS-IDEG (%, n=5)
26ProportionProp%Wei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)of terrigenous compounds (%, n=40)
27ProportionProp%Wei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)marine compounds (%, n=40)
28Highly aromatic compounds per dissolved organic carbonHAC/DOCμmol/lWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)in SPE-DOC
29Highly unsaturated compounds per dissolved organic carbonHUC/DOCμmol/lWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)in SPE-DOC
30Carboxyl-rich alicyclic molecules per dissolved organic carbonCRAM/DOCμmol/lWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)in SPE-DOC
31Unsatuared aliphatic and peptide-like compounds per dissolved organic carbonUA+Peptide/DOCμmol/lWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)in SPE-DOC
32Saturated compounds per dissolved organic carbonSC/DOCμmol/lWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)in SPE-DOC
33Compounds with negative degradation index per dissolved organic carbonNEG-IDEG/DOCμmol/lWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)in SPE-DOC
34Compounds with positive degradation index per dissolved organic carbonPOS-IDEG/DOCμmol/lWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)in SPE-DOC
35Terrigenous compounds per dissolved organic carbonTerr/DOCμmol/lWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)in SPE-DOC
36Marine compounds per dissolved organic carbonMarine/DOCμmol/lWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)in SPE-DOC
37Highly aromatic compounds, carboxyl-rich alicyclic molecules normalizedHAC/CRAMWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
38Unsatuared aliphatic and peptide-like compounds, carboxyl-rich alicyclic molecules normalizedUA+Peptide/CRAMWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
39Saturated compounds, carboxyl-rich alicyclic molecules normalizedSC/CRAMWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
40Compounds with negative degradation index, carboxyl-rich alicyclic molecules normalizedNEG-IDEG/CRAMWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
41Compounds with positive degradation index, carboxyl-rich alicyclic molecules normalizedPOS-IDEG/CRAMWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
42Terrigenous compounds, carboxyl-rich alicyclic molecules normalizedTerr/CRAMWei, BingbingFourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
43Marine compounds, carboxyl-rich alicyclic molecules normalizedMarine/CRAMWei, Bingbing
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
333 data points

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