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Hussain, Hafiz Shahid; Abbott, April N; Löhr, Stefan C; Hanif, Muhammad; Sean, Murray T; Mohibullah, Mohibullah; Ghani, Mukhtiar: Stable isotope analysis of each sample of carbonates from the Zranda section during the Palaeocene-Eocene Thermal Maximum [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.969023 (dataset in review)

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Abstract:
The Palaeocene-Eocene Thermal Maximum (PETM) is recognized as a significant climatic event in the Cenozoic era, marked by negative carbon excursions, rapid warming, and ocean acidification. However, stable isotope analysis of carbonates poses challenges due to diagenesis. This repository presents a comprehensive study of diagenetic features within the Zranda section, which represents shallow carbonates of the eastern Tethys. Through meticulous examination, this dataset facilitates the identification of minimally affected samples, enhancing their suitability for stable carbon isotope analysis.
Each sample was drilled with a dental drill to obtain 4 mg of powder for bulk carbonate stable isotope analysis. The best-preserved sections were targeted, avoiding visually altered areas due to diagenetic processes. Carbon and oxygen isotopes were measured using an IBEX system connected to a Thermo Fisher-MAT 253 Plus stable isotope mass spectrometer at Macquarie University's GeoAnalytical facility. The powder underwent reaction with 105% phosphoric acid at 90°C in a stirred acid bath. CO2 gas evolved from the reaction was isolated and filtered through cold traps and a sulfur-trap before being concentrated into a micro-vessel for analysis. Accuracy was monitored using an in-house Carrara marble standard and clumped isotope carbonate standards (ETH 1, ETH 2, ETH 3, and ETH 4). Isotopic values were calculated using Easotope software.
Keyword(s):
Carbonate; carbon isotope analysis; Diagenesis
Supplement to:
Hussain, Hafiz Shahid; Abbott, April N; Löhr, Stefan C; Hanif, Muhammad; Sean, Murray T; Mohibullah, Mohibullah; Ghani, Mukhtiar (submitted): Expression of the Palaeocene-Eocene Thermal Maximum in shallow-water carbonates of central eastern Tethys (Lower Indus Basin, Pakistan. Paleoceanography and Paleoclimatology
References:
Chilingar, George V; Bissell, Harold J; Wolf, Karl H (1967): Chapter 5 Diagenesis of Carbonate Rocks. In: Diagenesis in Sediments, Developments in Sedimentology, 8, Elsevier, 179-322, https://doi.org/10.1016/S0070-4571(08)70844-6
Madden, Robert H C; Wilson, Moyra E J; Mihaljević, Morana; Pandolfi, John M; Welsh, Kevin (2017): Unravelling the depositional origins and diagenetic alteration of carbonate breccias. Sedimentary Geology, 357, 33-52, https://doi.org/10.1016/j.sedgeo.2017.05.002
Coverage:
Median Latitude: 30.471993 * Median Longitude: 67.617527 * South-bound Latitude: 30.471635 * West-bound Longitude: 67.617267 * North-bound Latitude: 30.472384 * East-bound Longitude: 67.617800
Date/Time Start: 2019-10-16T00:00:00 * Date/Time End: 2020-10-16T00:00:00
Minimum Elevation: 2239.9 m * Maximum Elevation: 2263.3 m
Event(s):
PETM_Z_1_ZD_2 * Latitude: 30.471635 * Longitude: 67.617267 * Date/Time: 2019-10-16T00:00:00 * Elevation: 2239.9 m * Location: Pakistan * Method/Device: Outcrop sample (OUTCROP)
PETM_Z_1_ZD_3 * Latitude: 30.471635 * Longitude: 67.617286 * Date/Time: 2019-10-16T00:00:00 * Elevation: 2240.3 m * Location: Pakistan * Method/Device: Outcrop sample (OUTCROP)
PETM_Z_1_ZD_4 * Latitude: 30.471657 * Longitude: 67.617279 * Date/Time: 2019-10-16T00:00:00 * Elevation: 2240.2 m * Location: Pakistan * Method/Device: Outcrop sample (OUTCROP)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventHussain, Hafiz Shahid
2Latitude of eventLatitudeHussain, Hafiz Shahid
3Longitude of eventLongitudeHussain, Hafiz Shahid
4Date/Time of eventDate/TimeHussain, Hafiz Shahid
5Elevation of eventElevationmHussain, Hafiz Shahid
6SiteSiteHussain, Hafiz Shahid
7Sample code/labelSample labelHussain, Hafiz Shahid
8DistanceDistancemHussain, Hafiz ShahidDistance from the top of section
9δ13Cδ13CHussain, Hafiz ShahidMass spectrometer, Finnigan, MAT 253VPDB
10δ18Oδ18OHussain, Hafiz ShahidMass spectrometer, Finnigan, MAT 253VPDB
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
170 data points

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