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Osterholz, Helena; Turner, Stephnie; Alakangas, Linda; Tullborg, Eva-Lena; Kalinowski, Birgitta; Dittmar, Thorsten; Dopson, Mark (2021): Water chemistry of unfiltered groundwater samples from the Fennoscandian Shield deep terrestrial biosphere in 2018 and 2019 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.939654

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Abstract:
Copious amounts of organic carbon are stored for long periods of time in deep continental groundwaters. Little is known about its composition and cycling, mainly due to the difficulties in obtaining sample material. Cool fracture waters of different origins can be obtained under clean conditions at Äspö Hard Rock Laboratory (Äspö HRL, Sweden), operated by the Swedish Nuclear Fuel and Waste Management Company (SKB). We sampled groundwater from different depth (171 to 507 meter below sea level) in the bedrock fractures in November 2018 and March-April 2019. We assessed water chemistry and dissolved organic matter composition via stable carbon isotopic and molecular-formula level analysis in recent Baltic Sea-influenced to old saline fracture waters in the granitic Fennoscandian shield.
Physicochemical parameters, major ions, water isotopic compositions (δ18O and δD), total nitrogen as well as dissolved organic matter concentration and stable isotopic composition were obtained for unfiltered groundwater samples from different boreholes.
Keyword(s):
aquifer; FT-ICR-MS; groundwater
Related to:
Osterholz, Helena; Turner, Stephanie; Alakangas, Linda J; Tullborg, Eva-Lena; Dittmar, Thorsten; Kalinowski, Birgitta E; Dopson, Mark (2022): Terrigenous dissolved organic matter persists in the energy-limited deep groundwaters of the Fennoscandian Shield. Nature Communications, 13(1), 4837, https://doi.org/10.1038/s41467-022-32457-z
Coverage:
Median Latitude: 57.398037 * Median Longitude: 16.685330 * South-bound Latitude: 56.918333 * West-bound Longitude: 16.651667 * North-bound Latitude: 57.433440 * East-bound Longitude: 17.051667
Date/Time Start: 2018-11-16T00:00:00 * Date/Time End: 2019-10-04T00:00:00
Minimum Elevation: -507.0 m * Maximum Elevation: 0.0 m
Event(s):
BalticSea_Äspö * Latitude: 57.417500 * Longitude: 16.651667 * Date/Time: 2019-09-04T00:00:00 * Elevation: 0.0 m * Location: Sweden * Comment: Water type: BalticSea
BalticSea_Kalmar * Latitude: 56.918333 * Longitude: 17.051667 * Date/Time: 2019-04-16T00:00:00 * Elevation: 0.0 m * Location: Sweden * Comment: Water type: BalticSea
HA2780A_1 * Latitude: 57.433440 * Longitude: 16.659740 * Date/Time: 2019-03-18T00:00:00 * Elevation: -381.0 m * Location: Sweden * Comment: Water type: Saline
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventOsterholz, Helena
2Latitude of eventLatitudeOsterholz, Helena
3Longitude of eventLongitudeOsterholz, Helena
4Elevation of eventElevationmOsterholz, Helena
5DATE/TIMEDate/TimeOsterholz, HelenaGeocode
6TypeTypeOsterholz, HelenaWater type
7ConductivityCondmS/cmOsterholz, Helena
8Carbon, organic, dissolvedDOCµmol/lOsterholz, HelenaAverage of technical replicates
9Carbon, organic, dissolved, standard deviationDOC std dev±Osterholz, Helena
10Nitrogen, total dissolvedTDNµmol/lOsterholz, HelenaAverage of technical replicates
11Nitrogen, total dissolved, standard deviationTDN std dev±Osterholz, Helena
12Extraction efficiencyEE%Osterholz, Helena
13SodiumNamg/lOsterholz, Helena
14PotassiumKmg/lOsterholz, Helena
15CalciumCamg/lOsterholz, Helena
16MagnesiumMgmg/lOsterholz, Helena
17ChlorineClmg/lOsterholz, Helena
18Sulfur in sulfateS in SO4*2-mg/lOsterholz, Helena
19Sulfide in hydrogen sulfideS2--H2Smg/lOsterholz, Helena
20IronFemg/lOsterholz, Helena
21Iron, totalFe totmg/lOsterholz, Helena
22Iron 2+Fe2+mg/lOsterholz, Helena
23ManganeseMnmg/lOsterholz, Helena
24pHpHOsterholz, Helena
25Temperature, waterTemp°COsterholz, Helena
26Nitrogen in nitriteN-[NO2]-mg/lOsterholz, Helena
27Nitrogen in nitrateN-[NO3]-mg/lOsterholz, Helena
28Nitrogen in ammoniumN-[NH4]+mg/lOsterholz, Helena
29Phosphorus in phosphateP-[PO4]3-mg/lOsterholz, Helena
30Carbon-14, modern, dissolved inorganic carbonpMC DIC%Osterholz, Helena
31Carbon-14, modern, dissolved organic carbonpMC DOC%Osterholz, Helena
32δ13C, dissolved inorganic carbonδ13C DIC‰ PDBOsterholz, Helena
33δ13C, dissolved organic carbonδ13C DOC‰ PDBOsterholz, Helena
34δ Deuterium, waterδD H2O‰ SMOWOsterholz, Helena
35δ18O, waterδ18O H2O‰ SMOWOsterholz, Helena
Size:
1050 data points

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