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Neumann, Mareike; Decker, Charlotte; Hallmann, Christian: Cheilanthane ratios in Mesoproterozoic to Early Paleozoic rocks [dataset]. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.932811 (dataset in review)

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Abstract:
This data set contains values on the cheilanthane (tricyclic terpenoids) ratios of C22/C21 and C24/23 from Mesoproterozoic to Silurian rocks of global distribution. Lipid extractions were performed following standard protocols. The yield was contamination-controlled via exterior vs. interior comparison of individual peak concentrations. Values were obtained via integration of multiple-reaction-monitoring (MRM) measurements. In comparing our data of cheilanthane ratios to that reported for younger rocks and oils, we noticed consistently lower C24/C23 values in our samples, suggesting a bimodal character of cheilanthane distribution in time. We tentatively attribute this to the rise of a source of oxidatively decarboxylated cheilanthatriol derived from ferns. Fossil cheilanthanes likely represent a composite mixture of various biological sources, whose secular patterns may record more than the Paleozoic rise of terrestrial plants presented here.
Keyword(s):
Biomarkers; cheilanthane; Early Paleozoic; tricyclic terpenoids
Related to:
Neumann, Mareike; Decker, Charlotte; Hallmann, Christian (submitted): Bimodal secular tricyclic terpenoid patterns reflect Paleozoic terrestrialization. Organic Geochemistry
Coverage:
Median Latitude: -0.426725 * Median Longitude: 95.811156 * South-bound Latitude: -34.800000 * West-bound Longitude: 14.310000 * North-bound Latitude: 58.330000 * East-bound Longitude: 140.632300
Minimum SECTION, height: 64.480 m * Maximum SECTION, height: 1070.900 m
Event(s):
Boeryd * Latitude: 58.060000 * Longitude: 14.490000
Byilkaoora-1 * Latitude: -27.270000 * Longitude: 133.524700
Byilkaoora-2 * Latitude: -27.290000 * Longitude: 133.447400
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventNeumann, Mareike
2Cheilanthane, C22/C21 ratioC22/C21Neumann, Mareike
3Cheilanthane, C24/C23 ratioC24/C23Neumann, Mareike
4Laboratory code/labelLab labelNeumann, MareikeHallmannlab ID
5Geologic age nameGeol ageNeumann, Mareike
6Outcrop IDOutcrop IDNeumann, MareikeCore/Outcrop
7SECTION, heightSectionmNeumann, MareikeGeocode
8FormationFormationNeumann, Mareike
License:
Creative Commons Attribution 4.0 International (CC-BY-4.0) (License comes into effect after moratorium ends)
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
302 data points

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