Citation:

PANGAEA.929500

Name: Prioritised pharmaceuticals in German estuaries and coastal waters in 2015/2016
Published: 2021-03-22
License: https://creativecommons.org/licenses/by/4.0/

Always quote citation above when using data! You can download the citation in several formats below.

Published: 2021-03-22 • DOI registered: 2021-05-20

RIS Citation BibTeX Citation Text Citation ShareShow Map Google Earth

Abstract:

In this study a target analysis approach with method detection limits down to 0.01 ng L−1 was developed in order to determine ultra-trace pharmaceuticals in seawater of the German coast and their estuaries. The selection of target analytes based on a prioritisation commissioned by the German Environmental Agency considering occurrence in German surface waters, production volumes and ecotoxicological data. Using ultra-high pressure liquid chromatography coupled to a triple quadrupole mass spectrometer equipped with an electrospray ionisation source 21 prioritised pharmaceuticals out of seven therapeutical classes (antibiotics, iodinated X-ray contrast media (ICM), analgesics, lipid reducers, antiepileptics, anticonvulsants, beta-blockers) have been detected in the low to medium ng L−1-range. The most frequently measured substance groups in the German Baltic Sea and German Bight are the ICM, represented by the non-ionic ICM iomeprol (German Bightmax: 207 ng L−1; Baltic Seamax: 34.5 ng L−1) and the ionic ICM amidotrizoic acid (German Bight: 86.9 ng L−1), respectively. The same pattern of substance distribution could be detected in the German Bight, the German Baltic Sea and their inflows with lower concentrations in the offshore region that are partly a result of dilution with marine water. Pharmaceuticals entering the estuaries and coastal regions are an environmental issue since data on the ecotoxicological effects on aquatic marine organisms is limited. Especially the antibiotics clarithromycin and sulfamethoxazole could be ecotoxicologically/environmentally critical.

Related to:

Kötke, Danijela; Gandrass, Juergen; Xie, Zhiyong; Ebinghaus, Ralf (2019): Prioritised pharmaceuticals in German estuaries and coastal waters: Occurrence and environmental risk assessment. Environmental Pollution, 255, 113161, https://doi.org/10.1016/j.envpol.2019.113161

Project(s):

Helmholtz-Zentrum Geesthacht, Institute of Coastal Research (HZG)

Coverage:

Median Latitude: 54.066199 * Median Longitude: 11.016778 * South-bound Latitude: 53.036000 * West-bound Longitude: 8.078000 * North-bound Latitude: 54.823000 * East-bound Longitude: 14.535000

Date/Time Start: 2015-05-29T12:00:00 * Date/Time End: 2016-03-16T16:40:00

Minimum DEPTH, water: 0 m * Maximum DEPTH, water: 0 m

Event(s):

LP20150529_Stat_E1 * Latitude: 53.843000 * Longitude: 8.941000 * Date/Time: 2015-06-02T11:40:00 * Location: German Bight, North Sea * Campaign: * Basis: * Method/Device: Water sample (WS)

LP20150529_Stat_E2 * Latitude: 53.874000 * Longitude: 9.238000 * Date/Time: 2015-06-02T12:35:00 * Location: German Bight, North Sea * Campaign: * Basis: * Method/Device: Water sample (WS)

LP20150529_Stat_E3 * Latitude: 53.745000 * Longitude: 9.407000 * Date/Time: 2015-06-02T13:30:00 * Location: German Bight, North Sea * Campaign: * Basis: * Method/Device: Water sample (WS)

Comment:

Date/Time = local time

Temperature, water; Salinity and pH method:For campaigns SB1603 and SB1508: oxygen, conductivity, temperature, pH; Multimeter 3430 WTW. For campaign LP20150529: Measurement by on-line-in-situ FerryBox-System.

Parameter(s):

#	Name	Short Name	Unit	Principal Investigator	Method/Device	Comment
1	Event label	Event		Kötke, Danijela
2	Campaign of event	Campaign		Kötke, Danijela
3	Latitude of event	Latitude		Kötke, Danijela
4	Longitude of event	Longitude		Kötke, Danijela
5	Date/Time of event	Date/Time		Kötke, Danijela
6	DEPTH, water	Depth water	m	Kötke, Danijela		Geocode
7	Temperature, water	Temp	°C	Kötke, Danijela	See description in dataset comment	measured in water column
8	Salinity	Sal		Kötke, Danijela	See description in dataset comment	measured in water column
9	pH	pH		Kötke, Danijela	See description in dataset comment	measured in water column
10	Nadolol	Nadolol	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: <0.01ng/l, limit of detection for LP20150529: <0.01ng/l, limit of quantification for SB1603 and SB1508: 0.01ng/l, limit of quantification for LP20150529: 0.03ng/l
11	Paracetamol	Paracetamol	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.01ng/l, limit of detection for LP20150529: 0.14ng/l, limit of quantification for SB1603 and SB1508: 0.03ng/l, limit of quantification for LP20150529: 0.46ng/l
12	Carbamazepine	Carbamazepine	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.11ng/l, limit of detection for LP20150529: 0.33ng/l, limit of quantification for SB1603 and SB1508: 0.38ng/l, limit of quantification for LP20150529: 1.12ng/l
13	Diclofenac	Diclofenac	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.03ng/l, limit of detection for LP20150529: 0.18ng/l, limit of quantification for SB1603 and SB1508: 0.1ng/l, limit of quantification for LP20150529: 0.61ng/l
14	Iohexol	Iohexol	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.17ng/l, limit of detection for LP20150529: 0.34ng/l, limit of quantification for SB1603 and SB1508: 0.26ng/l, limit of quantification for LP20150529: 0.53ng/l
15	Iopromide	Iopromide	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.17ng/l, limit of detection for LP20150529: 0.3ng/l, limit of quantification for SB1603 and SB1508: 0.27ng/l, limit of quantification for LP20150529: 0.85ng/l
16	Lincomycin	Lincomycin	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: <0.01ng/l, limit of detection for LP20150529: 0.01ng/l, limit of quantification for SB1603 and SB1508: 0.01ng/l, limit of quantification for LP20150529: 0.01ng/l
17	Propranolol	Propranolol	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.02ng/l, limit of detection for LP20150529: 0.03ng/l, limit of quantification for SB1603 and SB1508: 0.07ng/l, limit of quantification for LP20150529: 0.09ng/l
18	Sulfadimethoxine	Sulfadimethoxine	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.01ng/l, limit of detection for LP20150529: 0.01ng/l, limit of quantification for SB1603 and SB1508: 0.02ng/l, limit of quantification for LP20150529: 0.04ng/l
19	Sulfamethoxazole	Sulfamethoxazole	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.01ng/l, limit of detection for LP20150529: 0.02ng/l, limit of quantification for SB1603 and SB1508: 0.02ng/l, limit of quantification for LP20150529: 0.07ng/l
20	Bezafibrate	Bezafibrate	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.03ng/l, limit of detection for LP20150529: 0.06ng/l, limit of quantification for SB1603 and SB1508: 0.18ng/l, limit of quantification for LP20150529: 0.36ng/l
21	Clarithromycin	Clarithromycin	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.01ng/l, limit of detection for LP20150529: 0.01ng/l, limit of quantification for SB1603 and SB1508: 0.02ng/l, limit of quantification for LP20150529: 0.03ng/l
22	Erythromycin	Erythromycin	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: <0.01ng/l, limit of detection for LP20150529: <0.01ng/l, limit of quantification for SB1603 and SB1508: 0.01ng/l, limit of quantification for LP20150529: 0.01ng/l
23	Iomeprol	Iomeprol	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.16ng/l, limit of detection for LP20150529: 0.99ng/l, limit of quantification for SB1603 and SB1508: 0.4ng/l, limit of quantification for LP20150529: 3.29ng/l
24	Iopamidol	Iopamidol	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.15ng/l, limit of detection for LP20150529: 0.34ng/l, limit of quantification for SB1603 and SB1508: 0.34ng/l, limit of quantification for LP20150529: 0.53ng/l
25	Primidone	Primidone	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.04ng/l, limit of detection for LP20150529: 0.1ng/l, limit of quantification for SB1603 and SB1508: 0.13ng/l, limit of quantification for LP20150529: 0.34ng/l
26	Roxithromycin	Roxithromycin	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.01ng/l, limit of detection for LP20150529: 0.02ng/l, limit of quantification for SB1603 and SB1508: 0.04ng/l, limit of quantification for LP20150529: 0.06ng/l
27	Sulfamethazine	Sulfamethazine	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.07ng/l, limit of detection for LP20150529: 0.33ng/l, limit of quantification for SB1603 and SB1508: 0.22ng/l, limit of quantification for LP20150529: 1.09ng/l
28	Tiamulin	Tiamulin	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for SB1603 and SB1508: 0.01ng/l, limit of detection for LP20150529: <0.01ng/l, limit of quantification for SB1603 and SB1508: 0.02ng/l, limit of quantification for LP20150529: 0.02ng/l
29	Amidotrizoic acid	Amidotrizoic acid	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for LP20150529: 0.05ng/l, limit of quantification for LP20150529: 0.35ng/l
30	Ioxitalamic acid	Ioxitalamic acid	ng/l	Kötke, Danijela	Solid-phase extraction (SPE) and cleanup, coupled liquid chromatography tandem mass spectrometry (LC-MS/MS)	measured in water column, limit of detection for LP20150529: 0.06ng/l, limit of quantification for LP20150529: 0.36ng/l

License:

Creative Commons Attribution 4.0 International (CC-BY-4.0)

Size:

1176 data points

Data

Download dataset as tab-delimited text — use the following character encoding:

1 Event	2 Campaign	3 Latitude	4 Longitude	5 Date/Time	7 Temp [°C]	8 Sal	9 pH	10 Nadolol [ng/l]	11 Paracetamol [ng/l]	12 Carbamazepine [ng/l]	13 Diclofenac [ng/l]	14 Iohexol [ng/l]	15 Iopromide [ng/l]	16 Lincomycin [ng/l]	17 Propranolol [ng/l]	18 Sulfadimethoxine [ng/l]	19 Sulfamethoxazole [ng/l]	20 Bezafibrate [ng/l]	21 Clarithromycin [ng/l]	22 Erythromycin [ng/l]	23 Iomeprol [ng/l]	24 Iopamidol [ng/l]	25 Primidone [ng/l]	26 Roxithromycin [ng/l]	27 Sulfamethazine [ng/l]	28 Tiamulin [ng/l]	29 Amidotrizoic acid [ng/l]	30 Ioxitalamic acid [ng/l]
SB1603_Stat_BS5	SB1603	54.3184	13.0953	2016-03-15T09:45:00	4.3	7.6	8.5	<0.01	<0.01	8.96	0.70	2.04	3.34	0.02	0.07	0.06	2.96	0.53	0.42	0.14	34.50	3.11	6.71	0.48	<0.22	<0.02
SB1603_Stat_BS4	SB1603	54.4036	13.6179	2016-03-15T11:00:00	4.7	8.0	8.7	<0.01	<0.01	8.26	0.25	1.92	3.33	0.03	0.11	0.10	3.29	0.19	0.19	0.04	5.85	0.89	4.74	0.29	<0.22	0.07
SB1603_Stat_BS6	SB1603	54.4552	12.5706	2016-03-15T12:15:00	6.7	9.2	8.1	<0.01	<0.01	3.73	0.11	1.08	1.12	<0.01	0.13	0.10	1.93	<0.03	0.15	0.04	6.63	1.03	4.21	0.28	<0.22	0.21
SB1603_Stat_BS7	SB1603	54.3527	12.3831	2016-03-15T13:30:00	7.1	10.1	8.2	<0.01	<0.01	2.89	<0.10	0.67	0.87	<0.01	0.09	0.10	1.55	<0.03	0.08	0.04	3.35	0.66	4.56	0.19	<0.22	0.08
SB1603_Stat_BS8	SB1603	54.1805	12.0906	2016-03-15T14:50:00	6.1	10.2	8.2	<0.01	<0.01	3.42	0.51	1.99	1.14	<0.01	<0.07	0.10	1.64	<0.18	0.14	0.07	8.72	2.85	3.47	0.20	<0.07	<0.01
SB1603_Stat_BS9	SB1603	54.1559	11.7628	2016-03-15T16:30:00	5.9	9.4	8.3	<0.01	<0.01	2.88	<0.10	0.69	1.14	<0.01	0.09	0.11	1.68	<0.03	0.08	0.03	2.41	0.51	3.64	0.20	<0.22	0.10
SB1603_Stat_BS11	SB1603	53.9482	11.3478	2016-03-15T18:00:00	6.2	13.0	8.5	<0.01	<0.01	2.58	<0.10	1.63	0.62	<0.01	<0.02	0.09	1.62	<0.03	0.07	0.02	6.59	1.46	3.05	0.07	<0.22	<0.01
SB1603_Stat_BS14	SB1603	54.0014	10.7836	2016-03-16T09:05:00	4.7	11.5	8.5	<0.01	<0.01	2.95	0.19	1.27	0.93	<0.01	<0.02	0.09	1.53	<0.03	0.09	0.04	4.99	1.52	4.36	0.09	<0.22	<0.01
SB1603_Stat_BS15	SB1603	54.1412	10.9647	2016-03-16T10:00:00	5.1	10.8	8.3	<0.01	<0.01	2.82	0.18	0.83	1.05	<0.01	<0.02	0.09	1.78	<0.03	0.11	0.03	2.55	0.63	3.15	0.15	<0.22	<0.02
SB1603_Stat_BS16	SB1603	54.3559	11.0916	2016-03-16T11:30:00	5.9	9.0	8.3	<0.01	<0.01	2.57	<0.10	0.65	0.88	<0.01	<0.02	0.11	1.67	<0.03	0.04	0.04	1.78	0.55	3.74	0.04	<0.22	<0.01
SB1603_Stat_BS17	SB1603	54.3250	10.6670	2016-03-16T12:10:00	6.3	14.7	8.3	<0.01	<0.01	2.53	<0.10	0.97	0.78	<0.01	<0.02	0.08	1.36	<0.03	0.06	0.03	4.45	1.39	2.74	0.06	<0.22	<0.02
SB1603_Stat_BS18	SB1603	54.4158	10.4154	2016-03-16T12:55:00	6.4	18.3	8.3	<0.01	0.42	2.08	0.17	0.76	0.48	<0.01	<0.02	0.06	1.18	<0.03	0.08	0.04	5.34	2.04	2.37	0.11	<0.22	<0.02
SB1603_Stat_BS19	SB1603	54.4272	10.1716	2016-03-16T14:00:00	8.1	18.2	8.3	<0.01	0.57	2.73	0.84	1.20	0.52	0.02	<0.07	0.04	1.85	0.24	0.34	0.14	13.10	12.00	3.26	0.35	<0.22	<0.01
SB1603_Stat_BS20	SB1603	54.4620	9.8434	2016-03-16T15:10:00	8.8	16.1	8.2	<0.01	<0.01	1.98	0.47	0.86	0.42	<0.01	<0.02	0.06	1.36	<0.03	0.11	0.05	5.90	2.23	2.29	0.10	<0.22	<0.01
SB1603_Stat_BS21	SB1603	54.6596	9.9345	2016-03-16T15:55:00	7.0	10.2	8.5	<0.01	<0.01	9.20	3.47	2.70	0.64	0.28	0.09	0.07	4.18	0.99	1.22	0.15	66.50	14.60	7.08	0.47	0.87	0.05
SB1603_Stat_BS22	SB1603	54.8229	9.6543	2016-03-16T16:40:00	6.2	13.9	8.3	<0.01	<0.01	2.45	0.35	1.06	0.56	0.03	<0.02	0.08	1.59	0.64	0.16	0.12	4.82	6.59	3.22	0.21	<0.22	<0.01
LP20150529_Stat_E1	LP20150529	53.8430	8.9410	2015-06-02T11:40:00	14.3	7.5	8.1	<0.01	<0.14	69.70	6.03	12.30	68.50	0.17	0.25	0.32	39.20	0.40	0.23	0.37	215.00	19.40	6.87	0.16	2.30	0.03	116.00	1.53
LP20150529_Stat_E2	LP20150529	53.8740	9.2380	2015-06-02T12:35:00	14.8	2.7	8.0	<0.01	<0.14	57.60	4.78	10.30	53.90	0.22	0.25	0.25	31.50	0.37	0.75	0.52	177.00	17.50	22.70	0.06	1.31	0.07	91.90	1.10
LP20150529_Stat_E3	LP20150529	53.7450	9.4070	2015-06-02T13:30:00	15.1	0.8	7.9	<0.01	<0.14	82.60	10.80	17.40	87.80	0.29	0.24	0.24	42.50	0.55	0.13	0.21	302.00	25.70	26.90	<0.02	1.44	0.03	170.00	3.09
LP20150529_Stat_E4	LP20150529	53.6050	9.5760	2015-06-02T14:32:00	15.8	0.6	7.7	<0.01	<0.14	89.10	18.60	20.80	104.00	0.27	0.38	0.19	39.30	1.06	0.20	0.34	378.00	29.10	30.10	<0.02	1.38	0.04	165.00	3.30
LP20150529_Stat_E5	LP20150529	53.5500	9.8190	2015-06-02T15:31:00	16.4	0.5	7.6	<0.01	<0.14	105.50	24.40	10.40	124.00	0.26	0.47	0.14	31.80	2.33	0.57	1.01	242.00	12.80	49.10	0.09	1.74	0.07	61.50	0.91
LP20150529_Stat_GB1	LP20150529	53.9010	8.6860	2015-05-29T12:00:00	13.8	22.5	8.3	<0.03	<0.14	20.10	0.87	9.28	22.30	0.13	0.15	0.13	12.10	0.52	0.57	0.31	99.30	11.90	8.16	0.17	<1.09	0.10	33.80	0.65
LP20150529_Stat_GB2	LP20150529	53.9640	8.5220	2015-05-29T12:45:00	14.0	26.3	8.3	<0.03	<0.14	13.30	<0.61	6.35	15.80	0.10	<0.09	0.09	7.60	0.43	0.40	0.21	62.00	8.95	4.02	0.13	<0.33	0.05
LP20150529_Stat_GB3	LP20150529	53.9030	8.0780	2015-05-29T14:48:00	13.3	30.0	8.3	<0.03	<0.14	4.78	<0.61	0.98	7.27	0.07	<0.09	0.04	1.78	<0.36	0.41	0.13	7.66	0.85	1.90	0.09	<1.09	0.02	1.71	<0.36
LP20150529_Stat_GB4	LP20150529	53.7540	8.1890	2015-05-29T16:20:00	14.1	26.8	8.2		<0.14	12.40					0.11												31.80	1.20
LP20150529_Stat_GB5	LP20150529	53.6630	8.3800	2015-05-29T17:25:00	14.5	18.5	8.1	<0.03	<0.14	29.70	4.82	25.50	34.10	0.16	0.22	0.13	13.00	2.06	1.66	0.94	207.00	31.60	9.73	0.38	<1.09	0.05	86.90	2.35
LP20150529_Stat_W1	LP20150529	53.4590	8.4930	2015-05-30T15:20:00	15.2	6.8	7.9	<0.01	<0.14	65.70	14.10	28.90	65.20	0.29	0.38	0.31	24.80	3.44	1.71	1.59	325.00	41.40	18.60	0.37	<1.09	0.06	177.00	3.23
LP20150529_Stat_W2	LP20150529	53.3690	8.5010	2015-05-30T14:50:00	15.6	2.2	7.9	<0.01	<0.14	87.60	23.40	39.00	90.20	0.44	0.50	0.47	32.30	4.71	1.47	2.00	484.00	59.50	28.80	0.45	<1.09	0.05	221.00	3.79
LP20150529_Stat_W3	LP20150529	53.2790	8.4880	2015-05-30T14:13:00	16.1	0.8	8.0	<0.01	<0.14	88.90	23.50	39.20	87.40	0.47	0.58	0.49	32.70	5.03	2.84	2.87	488.00	60.50	25.90	0.88	<0.33	0.05	207.00	3.51
LP20150529_Stat_W4	LP20150529	53.1880	8.5370	2015-05-30T13:17:00	16.6	0.8	8.0	<0.03	<0.14	92.60	27.10	38.10	96.90	0.41	0.70	0.34	35.10	6.02	8.07	3.90	463.00	59.80	29.00	2.86	<1.09	0.08	222.00	4.11
SB1508_Stat_O1	SB1508	53.0360	14.3120	2015-08-23T09:06:00	22.6	0.4	8.4	0.01	<0.01	162.00	2.29	10.10	94.50	0.54	0.08	0.06	20.30	<0.03	1.54	0.29	21.10	0.73	15.30	0.16	0.97	0.08
SB1508_Stat_O2	SB1508	53.3830	14.5350	2015-08-23T12:20:00	25.6	0.4	7.9	<0.01	<0.01	149.00	1.59	7.91	55.40	0.46	0.10	0.06	15.40	<0.03	1.69	0.32	23.70	0.98	19.80	0.23	0.45	0.11
SB1508_Stat_O3	SB1508	53.7360	14.1740	2015-08-23T14:55:00	24.4	1.9	8.7	<0.01	<0.01	74.20	<0.03	6.27	30.00	0.09	<0.02	<0.01	5.47	<0.03	1.05	0.17	21.10	<0.34	8.31	0.10	<0.22	0.03
SB1508_Stat_P1	SB1508	53.8600	13.6900	2015-08-23T18:35:00	22.4	0.3	7.9	<0.01	<0.01	82.00	1.02	0.29	21.00	0.07	0.20	<0.01	3.35	<0.03	0.96	0.58	251.00	2.97	24.70	3.64	<0.22	0.02
SB1508_Stat_BS1	SB1508	53.9760	14.1460	2015-09-01T19:00:00	20.9	7.6	8.2	<0.01	<0.01	6.94	<0.03	0.58	2.37	0.02	<0.02	0.08	1.52	<0.03	0.12	<0.01	1.83	<0.15	<0.04	<0.04	<0.07	<0.01
SB1508_Stat_BS2	SB1508	54.0600	14.0000	2015-09-01T17:45:00	21.2	7.6	8.3	<0.01	<0.01	6.49	0.29	0.47	1.97	0.02	<0.02	0.07	1.50	<0.03	0.12	0.09	1.47	<0.15	<0.04	<0.04	<0.07	<0.01
SB1508_Stat_BS3	SB1508	54.3480	13.7440	2015-09-02T11:40:00	19.2	7.8	8.3	<0.01	<0.01	6.51	<0.03	0.49	2.01	0.02	<0.02	0.08	1.49	<0.03	0.08	<0.01	1.97	<0.15	<0.04	<0.04	<0.07	<0.02
SB1508_Stat_BS4	SB1508	54.4040	13.6180	2015-09-02T10:40:00	18.6	7.9	8.3	<0.01	<0.01	6.91	<0.03	0.60	2.13	0.02	<0.02	0.06	1.57	<0.03	0.08	<0.01	2.51	<0.15	<0.04	<0.04	<0.07	<0.02
SB1508_Stat_BS5	SB1508	54.3180	13.0950	2015-09-02T08:55:00	18.2	8.2	8.2	<0.01	<0.01	10.60	0.50	0.36	1.47	0.01	<0.07	0.04	1.52	<0.03	0.20	0.09	9.82	<0.15	<0.04	0.07	<0.07	<0.01
SB1508_Stat_BS6	SB1508	54.4550	12.5710	2015-09-03T10:30:00	18.0	8.9	8.2	<0.01	<0.01	3.48	<0.03	0.29	1.06	0.01	<0.02	0.09	1.14	<0.03	0.05	<0.01	1.05	<0.15	<0.04	<0.01	<0.07	<0.01
SB1508_Stat_BS7	SB1508	54.3530	12.3830	2015-09-03T11:50:00	17.5	9.1	8.2	<0.01	<0.01	3.11	<0.03	0.32	0.99	0.01	<0.02	0.09	1.10	<0.03	0.04	<0.01	1.19	<0.15	<0.04	<0.01	<0.07	<0.01
SB1508_Stat_BS8	SB1508	54.1810	12.0910	2015-09-03T13:50:00	17.6	9.8	8.1	<0.01	<0.01	5.93	<0.03	0.64	1.65	0.01	<0.07	0.08	1.59	<0.03	0.07	<0.01	4.31	<0.34	<0.04	<0.04	<0.07	<0.01
SB1508_Stat_BS9	SB1508	54.1560	11.7630	2015-09-03T16:05:00	18.3	9.6	8.2	<0.01	<0.01	3.01	<0.03	0.28	1.17	0.01	<0.02	0.08	1.10	<0.03	0.03	<0.01	1.26	<0.15	<0.04	<0.01	<0.07	<0.01
SB1508_Stat_BS10	SB1508	53.9920	11.3740	2015-09-03T18:00:00	18.5	11.2	8.3	<0.01	<0.01	3.72	<0.03	0.33	0.47	0.02	<0.02	0.06	0.93	<0.03	0.05	0.02	2.37	<0.15	<0.04	<0.01	<0.07	<0.01
SB1508_Stat_BS11	SB1508	53.9480	11.3480	2015-09-03T20:00:00	18.4	11.5	8.2	<0.01	<0.01	4.34	<0.03	<0.26	0.52	0.02	<0.02	0.06	0.90	<0.03	0.11	<0.01	2.64	<0.15	<0.04	<0.04	<0.07	<0.01
SB1508_Stat_BS12	SB1508	53.9410	11.2520	2015-09-03T19:30:00	18.7	11.6	8.3	<0.01	<0.01	3.48	<0.03	<0.26	0.54	0.04	<0.02	0.06	0.99	<0.03	0.05	<0.01	2.21	<0.15	<0.04	<0.01	<0.07	<0.01
SB1508_Stat_BS13	SB1508	53.9700	10.8830	2015-09-04T11:45:00	16.9	11.6	8.2	<0.01	<0.01	6.24	<0.03	1.70	0.66	0.02	<0.02	0.07	1.95	<0.03	0.11	0.09	17.80	0.84	<0.04	<0.04	<0.07	<0.01
SB1508_Stat_BS15	SB1508	54.1410	10.9650	2015-09-04T13:30:00	17.2	11.0	8.3	<0.01	<0.01	3.31	<0.03	0.48	0.72	0.01	<0.02	0.08	1.09	<0.03	0.04	0.04	3.52	<0.15	<0.04	<0.04	<0.07	<0.01
SB1508_Stat_BS16	SB1508	54.3560	11.0920	2015-09-04T16:35:00	17.5	12.5	8.2	<0.01	<0.01	3.82	<0.03	0.32	0.73	0.01	<0.02	0.07	0.96	<0.03	0.04	0.03	1.70	<0.15	<0.04	<0.04	<0.07	<0.01
SB1508_Stat_BS19	SB1508	54.4270	10.1720	2015-09-05T11:35:00	17.3	14.9	8.1	<0.01	<0.01	3.51	<0.03	0.38	0.76	0.01	<0.02	0.05	1.22	<0.03	0.06	0.05	4.60	0.55	<0.04	<0.04	<0.07	<0.01
SB1508_Stat_BS20	SB1508	54.4620	9.8430	2015-09-10T10:30:00	16.9	14.3	8.2	<0.01	<0.01	3.51	<0.03	0.37	0.85	0.01	<0.02	0.06	1.13	<0.03	0.04	0.03	2.47	<0.15	<0.04	<0.01	<0.07	<0.01
SB1508_Stat_BS21	SB1508	54.6600	9.9350	2015-09-05T13:50:00	16.5	11.2	8.5	<0.01	<0.01	16.50	0.48	1.66	1.39	0.10	<0.02	<0.01	1.53	<0.03	0.20	0.09	123.00	0.66	<0.04	<0.04	<0.22	<0.01
SB1508_Stat_BS22	SB1508	54.8230	9.6540	2015-09-05T16:05:00	16.9	14.9	8.5	<0.01	<0.01	3.97	<0.10	0.55	0.55	0.01	<0.02	0.04	0.74	0.48	0.07	0.05	6.61	<0.15	<0.04	<0.04	<0.07	<0.01