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Cai, Yue; LaGatta, Alexandra; Goldstein, Steven L; Langmuir, Charles H; Gómez-Tuena, Arturo; Martín-del Pozzo, Ana Lillian; Carrasco-Núñez, Gerardo (2016): (Supplement EA1) Elements, Neodymium and Hafnium analysis on lavas from Nevado de Toluca [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.857521, In supplement to: Cai, Y et al. (2014): Hafnium isotope evidence for slab melt contributions in the Central Mexican Volcanic Belt and implications for slab melting in hot and cold slab arcs. Chemical Geology, 377, 45-55, https://doi.org/10.1016/j.chemgeo.2014.04.002

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Further details:
Lozano, R; Bernal, Juan Pablo (2005): Characterization of a new set of eight geochemical reference materials for XRF major and trace element analysis. Revista Mexicana de Ciencias Geologicas, Universidad Nacional Autonoma de Mexico, 22(3), 329-344
Mori, Laura; Gómez-Tuena, Arturo; Cai, Yue; Goldstein, Steven L (2007): Effects of prolonged flat subduction on the Miocene magmatic record of the central Trans-Mexican Volcanic Belt. Chemical Geology, 244(3-4), 452-473, https://doi.org/10.1016/j.chemgeo.2007.07.002
Tanaka, Tsuyoshi; Togashi, Shigeko; Kamioka, Hikari; Amakawa, Hiroshi; Kagami, Hiroo; Hamamoto, Takuji; Yuhara, Masaki; Orihashi, Yuji; Yoneda, Shigekazu; Shimizu, Hiroshi; Kunimaru, Takanori; Takahashi, Kazuya; Yanagi, Takeru; Nakano, Takanori; Fujimaki, Hirokazu; Shinjo, Ryuichi; Asahara, Yoshihiro; Tanimizu, Masaharu; Dragusanu, Cristian (2000): JNdi-1: a neodymium isotopic reference in consistency with LaJolla neodymium. Chemical Geology, 168(3-4), 279-281, https://doi.org/10.1016/S0009-2541(00)00198-4
Vervoort, Jeff D; Blichert-Toft, Janne (1999): Evolution of the depleted mantle: Hf isotope evidence from juvenile rocks through time. Geochimica et Cosmochimica Acta, 63(3-4), 533-556, https://doi.org/10.1016/S0016-7037(98)00274-9
Weis, Dominique A M; Kieffer, Bruno; Hanano, Diane; Nobre Silva, Ines; Barling, Jane; Pretorius, Wilma; Maerschalk, Claude; Mattielli, Nadine (2007): Hf isotope compositions of U.S. Geological Survey reference materials. Geochemistry, Geophysics, Geosystems, 8(6), n/a-n/a, https://doi.org/10.1029/2006GC001473
Coverage:
Median Latitude: 19.096538 * Median Longitude: -99.733458 * South-bound Latitude: 19.015000 * West-bound Longitude: -99.827340 * North-bound Latitude: 19.140000 * East-bound Longitude: -99.656580
Event(s):
AN81 * Latitude: 19.093000 * Longitude: -99.800580 * Location: Nevado de Toluca
AN160 * Latitude: 19.120000 * Longitude: -99.795760 * Location: Nevado de Toluca
AN179 * Latitude: 19.140000 * Longitude: -99.819570 * Location: Nevado de Toluca
Comment:
Major elements were determined by X-ray fluorescence spectroscopy (XRF) using a Siemens SRS-3000 instrument in the Laboratorio Universitario de Geoquímica Isotópica (LUGIS), UNAM, using procedures of Lozano and Bernal (2005).
Trace element concentrations were determined using Thermo Scientific Electron X-series ICP-MS (Inductively Coupled Plasma Mass Spectrometer) at the Centro de Geociencias (CGEO), UNAM-Querétaro, following sample preparation and measurement procedures described by Mori et al., (2007; doi:10.1016/j.chemgeo.2007.07.002).
Nd isotopes were measured at LDEO using VG-Sector 54 TIMS. Purified Nd was loaded on Re filaments and Nd isotopes were measured by dynamic multicollection as NdO+. 143Nd/144Nd ratios are normalized to 146Nd/144Nd = 0.7219. Unknowns are normalized to La Jolla value of 143Nd/144Nd = 0.511860 ± 19 (2 sigma external SD during the entire study period, n = 177). International standard JNdi-1 yielded 143Nd/144Nd = 0.512110 ± 19 (n = 5), which is comparable to the published value of 0.512117 ± 7 (Tanaka et al., 2000, doi:10.1016/S0009-2541(00)00198-4).
Hf isotope ratios were measured at LDEO using multi-collector ICPMS. 176Hf/177Hf are normalized to 179Hf/177Hf = 0.7325. Instrumental drift was monitored by repeated measurements of a Johnson-Matthey Hf elemental standard with the same 176Hf/177Hf ratio as the JMC-475 standard. Unknowns are normalized to the JMC-475 value of 176Hf/177Hf = 0.282160 (Vervoort and Blichert-Toft, 1999; doi:10.1016/S0009-2541(00)00198-4). 2 sigma external SD during measurement sessions are below 0.000012 (n = 10). The average measured 176Hf/177Hf values for BHVO-1 is 0.283107 ± 20 (n = 14) and for BCR-1 is 0.282876 ± 13 (n = 5), which agree with the recommended values from Weis et al. (2007, doi:10.1029/2006GC001473), which reported BHVO-1 of 0.283106 ± 12 (n = 7); BCR-1 of 0.282875 ± 8 (n = 5).
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventCai, Yue
2Latitude of eventLatitudeCai, Yue
3Longitude of eventLongitudeCai, Yue
4International Generic Sample NumberIGSNCai, YueIGSN number
5Sample commentSample commentCai, Yue
6MagnesiumMg# of ionsCai, Yue
7Silicon dioxideSiO2%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
8Titanium dioxideTiO2%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
9Aluminium oxideAl2O3%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
10Iron oxide, FeOFeO%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
11Manganese oxideMnO%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
12Magnesium oxideMgO%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
13Calcium oxideCaO%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
14Sodium oxideNa2O%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
15Potassium oxideK2O%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
16Phosphorus pentoxideP2O5%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
17BariumBamg/kgCai, YueICP-MS (Thermo Scientific, X-series)
18RubidiumRbmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
19CaesiumCsmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
20ThoriumThmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
21UraniumUmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
22NiobiumNbmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
23TantalumTamg/kgCai, YueICP-MS (Thermo Scientific, X-series)
24LeadPbmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
25StrontiumSrmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
26LanthanumLamg/kgCai, YueICP-MS (Thermo Scientific, X-series)
27CeriumCemg/kgCai, YueICP-MS (Thermo Scientific, X-series)
28PraseodymiumPrmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
29NeodymiumNdmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
30ZirconiumZrmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
31HafniumHfmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
32SamariumSmmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
33EuropiumEumg/kgCai, YueICP-MS (Thermo Scientific, X-series)
34GadoliniumGdmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
35DysprosiumDymg/kgCai, YueICP-MS (Thermo Scientific, X-series)
36TerbiumTbmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
37YttriumYmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
38YtterbiumYbmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
39LutetiumLumg/kgCai, YueICP-MS (Thermo Scientific, X-series)
40Neodymium-143/Neodymium-144 ratio143Nd/144NdCai, YueThermal Ionization Mass Spectrometry (TIMS)
41Neodymium-143/Neodymium-144 ratio143Nd/144NdCai, YueThermal Ionization Mass Spectrometry (TIMS)Duplicate
42Neodymium-143/Neodymium-144 ratio, error143Nd/144Nd e±Cai, YueThermal Ionization Mass Spectrometry (TIMS)
43Neodymium-143/Neodymium-144 ratio, error143Nd/144Nd e±Cai, YueThermal Ionization Mass Spectrometry (TIMS)Duplicate
44ε-Neodymiumε-NdCai, YueThermal Ionization Mass Spectrometry (TIMS)
45ε-Neodymiumε-NdCai, YueThermal Ionization Mass Spectrometry (TIMS)Duplicate
46Hafnium-176/Hafnium-177176Hf/177HfCai, YueMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)
47ErrorErrorCai, YueMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)Internal measurement error (2SE)
48ReproducibilityRepro± %Cai, YueMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)External reproducibility (2SD)
49ε-Hafniumε-HfCai, YueMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)
Size:
568 data points

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