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Data Publisher for Earth & Environmental Science

Cai, Yue; LaGatta, Alexandra; Goldstein, Steven L; Langmuir, Charles H; Gómez-Tuena, Arturo; Martín-del Pozzo, Ana Lillian; Carrasco-Núñez, Gerardo (2016): (Supplement EA1) Elements, Neodymium and Hafnium analysis on lavas from Nevado de Toluca [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.857521, In supplement to: Cai, Y et al. (2014): Hafnium isotope evidence for slab melt contributions in the Central Mexican Volcanic Belt and implications for slab melting in hot and cold slab arcs. Chemical Geology, 377, 45-55, https://doi.org/10.1016/j.chemgeo.2014.04.002

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Further details:
Lozano, R; Bernal, Juan Pablo (2005): Characterization of a new set of eight geochemical reference materials for XRF major and trace element analysis. Revista Mexicana de Ciencias Geologicas, Universidad Nacional Autonoma de Mexico, 22(3), 329-344
Mori, Laura; Gómez-Tuena, Arturo; Cai, Yue; Goldstein, Steven L (2007): Effects of prolonged flat subduction on the Miocene magmatic record of the central Trans-Mexican Volcanic Belt. Chemical Geology, 244(3-4), 452-473, https://doi.org/10.1016/j.chemgeo.2007.07.002
Tanaka, Tsuyoshi; Togashi, Shigeko; Kamioka, Hikari; Amakawa, Hiroshi; Kagami, Hiroo; Hamamoto, Takuji; Yuhara, Masaki; Orihashi, Yuji; Yoneda, Shigekazu; Shimizu, Hiroshi; Kunimaru, Takanori; Takahashi, Kazuya; Yanagi, Takeru; Nakano, Takanori; Fujimaki, Hirokazu; Shinjo, Ryuichi; Asahara, Yoshihiro; Tanimizu, Masaharu; Dragusanu, Cristian (2000): JNdi-1: a neodymium isotopic reference in consistency with LaJolla neodymium. Chemical Geology, 168(3-4), 279-281, https://doi.org/10.1016/S0009-2541(00)00198-4
Vervoort, Jeff D; Blichert-Toft, Janne (1999): Evolution of the depleted mantle: Hf isotope evidence from juvenile rocks through time. Geochimica et Cosmochimica Acta, 63(3-4), 533-556, https://doi.org/10.1016/S0016-7037(98)00274-9
Weis, Dominique A M; Kieffer, Bruno; Hanano, Diane; Nobre Silva, Ines; Barling, Jane; Pretorius, Wilma; Maerschalk, Claude; Mattielli, Nadine (2007): Hf isotope compositions of U.S. Geological Survey reference materials. Geochemistry, Geophysics, Geosystems, 8(6), n/a-n/a, https://doi.org/10.1029/2006GC001473
Coverage:
Median Latitude: 19.096538 * Median Longitude: -99.733458 * South-bound Latitude: 19.015000 * West-bound Longitude: -99.827340 * North-bound Latitude: 19.140000 * East-bound Longitude: -99.656580
Event(s):
AN81  * Latitude: 19.093000 * Longitude: -99.800580 * Location: Nevado de Toluca
AN160  * Latitude: 19.120000 * Longitude: -99.795760 * Location: Nevado de Toluca
AN179  * Latitude: 19.140000 * Longitude: -99.819570 * Location: Nevado de Toluca
Comment:
Major elements were determined by X-ray fluorescence spectroscopy (XRF) using a Siemens SRS-3000 instrument in the Laboratorio Universitario de Geoquímica Isotópica (LUGIS), UNAM, using procedures of Lozano and Bernal (2005).
Trace element concentrations were determined using Thermo Scientific Electron X-series ICP-MS (Inductively Coupled Plasma Mass Spectrometer) at the Centro de Geociencias (CGEO), UNAM-Querétaro, following sample preparation and measurement procedures described by Mori et al., (2007; doi:10.1016/j.chemgeo.2007.07.002).
Nd isotopes were measured at LDEO using VG-Sector 54 TIMS. Purified Nd was loaded on Re filaments and Nd isotopes were measured by dynamic multicollection as NdO+. 143Nd/144Nd ratios are normalized to 146Nd/144Nd = 0.7219. Unknowns are normalized to La Jolla value of 143Nd/144Nd = 0.511860 ± 19 (2 sigma external SD during the entire study period, n = 177). International standard JNdi-1 yielded 143Nd/144Nd = 0.512110 ± 19 (n = 5), which is comparable to the published value of 0.512117 ± 7 (Tanaka et al., 2000, doi:10.1016/S0009-2541(00)00198-4).
Hf isotope ratios were measured at LDEO using multi-collector ICPMS. 176Hf/177Hf are normalized to 179Hf/177Hf = 0.7325. Instrumental drift was monitored by repeated measurements of a Johnson-Matthey Hf elemental standard with the same 176Hf/177Hf ratio as the JMC-475 standard. Unknowns are normalized to the JMC-475 value of 176Hf/177Hf = 0.282160 (Vervoort and Blichert-Toft, 1999; doi:10.1016/S0009-2541(00)00198-4). 2 sigma external SD during measurement sessions are below 0.000012 (n = 10). The average measured 176Hf/177Hf values for BHVO-1 is 0.283107 ± 20 (n = 14) and for BCR-1 is 0.282876 ± 13 (n = 5), which agree with the recommended values from Weis et al. (2007, doi:10.1029/2006GC001473), which reported BHVO-1 of 0.283106 ± 12 (n = 7); BCR-1 of 0.282875 ± 8 (n = 5).
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
Event labelEventCai, Yue
Latitude of eventLatitudeCai, Yue
Longitude of eventLongitudeCai, Yue
International Generic Sample NumberIGSNCai, YueIGSN number
Sample commentSample commentCai, Yue
MagnesiumMg# of ionsCai, Yue
Silicon dioxideSiO2%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
Titanium dioxideTiO2%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
Aluminium oxideAl2O3%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
10 Iron oxide, FeOFeO%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
11 Manganese oxideMnO%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
12 Magnesium oxideMgO%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
13 Calcium oxideCaO%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
14 Sodium oxideNa2O%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
15 Potassium oxideK2O%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
16 Phosphorus pentoxideP2O5%Cai, YueX-ray fluorescence spectroscopy (Siemens SRS-3000)
17 BariumBamg/kgCai, YueICP-MS (Thermo Scientific, X-series)
18 RubidiumRbmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
19 CaesiumCsmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
20 ThoriumThmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
21 UraniumUmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
22 NiobiumNbmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
23 TantalumTamg/kgCai, YueICP-MS (Thermo Scientific, X-series)
24 LeadPbmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
25 StrontiumSrmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
26 LanthanumLamg/kgCai, YueICP-MS (Thermo Scientific, X-series)
27 CeriumCemg/kgCai, YueICP-MS (Thermo Scientific, X-series)
28 PraseodymiumPrmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
29 NeodymiumNdmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
30 ZirconiumZrmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
31 HafniumHfmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
32 SamariumSmmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
33 EuropiumEumg/kgCai, YueICP-MS (Thermo Scientific, X-series)
34 GadoliniumGdmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
35 DysprosiumDymg/kgCai, YueICP-MS (Thermo Scientific, X-series)
36 TerbiumTbmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
37 YttriumYmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
38 YtterbiumYbmg/kgCai, YueICP-MS (Thermo Scientific, X-series)
39 LutetiumLumg/kgCai, YueICP-MS (Thermo Scientific, X-series)
40 Neodymium-143/Neodymium-144 ratio143Nd/144NdCai, YueThermal Ionization Mass Spectrometry (TIMS)
41 Neodymium-143/Neodymium-144 ratio143Nd/144NdCai, YueThermal Ionization Mass Spectrometry (TIMS)Duplicate
42 Neodymium-143/Neodymium-144 ratio, error143Nd/144Nd e±Cai, YueThermal Ionization Mass Spectrometry (TIMS)
43 Neodymium-143/Neodymium-144 ratio, error143Nd/144Nd e±Cai, YueThermal Ionization Mass Spectrometry (TIMS)Duplicate
44 ε-Neodymiumε-NdCai, YueThermal Ionization Mass Spectrometry (TIMS)
45 ε-Neodymiumε-NdCai, YueThermal Ionization Mass Spectrometry (TIMS)Duplicate
46 Hafnium-176/Hafnium-177176Hf/177HfCai, YueMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)
47 ErrorErrorCai, YueMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)Internal measurement error (2SE)
48 ReproducibilityRepro± %Cai, YueMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)External reproducibility (2SD)
49 ε-Hafniumε-HfCai, YueMulti-collector inductively coupled plasma mass spectrometer (MC-ICP-MS)
Size:
568 data points

Data

Download dataset as tab-delimited text — use the following character encoding:


Event

Latitude

Longitude

IGSN
(IGSN number)

Sample comment

Mg [# of ions]

SiO2 [%]
(X-ray fluorescence spectrosco...)

TiO2 [%]
(X-ray fluorescence spectrosco...)

Al2O3 [%]
(X-ray fluorescence spectrosco...)
10 
FeO [%]
(X-ray fluorescence spectrosco...)
11 
MnO [%]
(X-ray fluorescence spectrosco...)
12 
MgO [%]
(X-ray fluorescence spectrosco...)
13 
CaO [%]
(X-ray fluorescence spectrosco...)
14 
Na2O [%]
(X-ray fluorescence spectrosco...)
15 
K2O [%]
(X-ray fluorescence spectrosco...)
16 
P2O5 [%]
(X-ray fluorescence spectrosco...)
17 
Ba [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
18 
Rb [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
19 
Cs [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
20 
Th [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
21 
U [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
22 
Nb [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
23 
Ta [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
24 
Pb [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
25 
Sr [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
26 
La [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
27 
Ce [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
28 
Pr [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
29 
Nd [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
30 
Zr [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
31 
Hf [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
32 
Sm [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
33 
Eu [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
34 
Gd [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
35 
Dy [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
36 
Tb [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
37 
Y [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
38 
Yb [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
39 
Lu [mg/kg]
(ICP-MS (Thermo Scientific, X-...)
40 
143Nd/144Nd
(Thermal Ionization Mass Spect...)
41 
143Nd/144Nd
(Duplicate, Thermal Ionization...)
42 
143Nd/144Nd e [±]
(Thermal Ionization Mass Spect...)
43 
143Nd/144Nd e [±]
(Duplicate, Thermal Ionization...)
44 
ε-Nd
(Thermal Ionization Mass Spect...)
45 
ε-Nd
(Duplicate, Thermal Ionization...)
46 
176Hf/177Hf
(Multi-collector inductively c...)
47 
Error
(Internal measurement error (2...)
48 
Repro [± %]
(External reproducibility (2SD...)
49 
ε-Hf
(Multi-collector inductively c...)
AN160 19.1200-99.7958CAI000001Toluca53.764.80.6715.84.660.083.04.64.12.00.1951535.51.493.731.305.120.369.072416.638.64.9620.31514.694.261.233.612.720.51515.31.360.1920.5129060.0000075.20.2830460.0000070.0000089.7
AN179 19.1400-99.8196CAI000002Toluca weathered44.164.50.7716.74.880.092.14.34.32.20.1546151.71.284.711.805.550.408.746624.140.07.8032.71854.887.051.646.985.570.98535.62.700.4110.5128630.0000054.40.2830370.0000070.0000089.4
AN182 19.1400-99.8273CAI000003Toluca39.367.00.4916.53.770.061.43.84.42.50.1345550.52.624.781.604.390.348.973017.136.34.8919.31424.353.771.063.112.210.43513.11.100.1740.5128750.0000074.60.2830880.0000060.00000811.2
AN81 19.0930-99.8006CAI000004Toluca52.564.90.6416.14.450.082.74.54.02.10.4649737.81.723.621.284.970.358.865516.336.34.7819.51464.434.081.193.482.630.49814.91.310.1960.5129130.0000065.40.2830440.0000070.0000129.6
M32 19.0550-99.7263CAI000005Toluca weathered56.962.40.7517.15.020.093.74.84.21.80.1845742.91.974.111.635.030.368.254924.742.46.5926.51493.855.521.354.973.900.71624.71.920.2810.5128980.0000075.10.2830470.0000080.0000089.7
M34 19.0550-99.7819CAI000006Toluca50.165.20.6016.74.060.072.34.44.62.00.1642547.71.674.231.644.080.317.957414.430.14.2117.21383.503.681.073.252.570.47314.81.400.2050.5129450.0000066.00.2830580.0000080.00000810.1
M69 19.0150-99.7694CAI000007Toluca weathered55.862.30.7516.45.140.083.65.44.12.00.2152444.91.774.911.774.980.368.268035.649.641.41513.878.102.006.414.520.87226.12.100.3020.5128860.5128910.0000050.0000074.84.90.2830260.0000070.0000129.0
RAM101 19.0980-99.6616CAI000008Toluca weathered46.667.20.5916.64.020.062.03.04.02.40.1556154.81.455.081.885.270.399.845780.240.862.71434.7011.402.966.891.38038.22.500.3520.5128690.5128670.0000070.0000104.54.50.2830320.0000070.0000129.2
RAM215 19.1090-99.7065CAI000009Toluca weathered44.964.00.7116.85.060.082.34.34.52.10.1845645.41.354.371.595.070.378.852920.539.65.9123.71464.714.971.294.413.510.64220.51.780.2610.5129150.0000085.40.2830660.0000090.00000810.4
RAM22 19.1180-99.6602CAI00000AToluca41.964.30.7216.75.010.072.04.34.52.20.1946145.41.384.481.665.130.388.853718.639.55.5622.51604.454.881.284.353.540.64020.21.850.2570.5129320.5129360.0000050.0000075.75.80.2830650.0000080.00001210.3
RAM452 19.1210-99.6566CAI00000BToluca49.861.90.6118.35.230.092.95.04.41.60.1451115.50.955.221.524.720.3910.665017.536.54.9419.31264.174.011.153.492.880.52215.91.480.2270.5129270.5129330.0000060.0000075.65.80.2830620.0000060.00001210.3
RAM453 19.1060-99.6567CAI00000CToluca weathered35.566.30.7417.15.030.081.53.23.72.20.1446343.30.884.001.455.240.388.240826.132.17.6331.32176.046.861.956.194.780.88328.22.280.3150.5129400.0000065.90.2830670.0000080.00000810.4
RAM592 19.0850-99.6725CAI00000DToluca36.062.80.6417.26.720.092.14.63.91.80.1644237.92.233.061.194.750.358.355911.825.53.6515.31023.543.421.013.182.540.47315.41.380.1930.5129630.0000076.30.2830500.0000070.0000129.8