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Passier, Hilde F; Bosch, Hendrik-Jan; Nijenhuis, Ivar A; Lourens, Lucas Joost; Böttcher, Michael Ernst; Leenders, Anke; Sinninghe Damsté, Jaap S; de Lange, Gert J; de Leeuw, Jan W (1997): (Table 1) Geochemistry of Sapropels of the Mediterranean Sea [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.769873, Supplement to: Passier, HF et al. (1999): Sulphidic Mediterranean surface waters during Pliocene sapropel formation. Nature, 397(6715), 146-149, https://doi.org/10.1038/16441

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Abstract:
Sapropels -organic-matter rich layers- are common in Neogene sediments of the eastern Mediterranean Sea. The formation of these layers has been attributed to climate-related increases in organic-matter production (Calvert et al., 1992, doi:10.1038/359223a0; Rossignol-Strick et al., 1982, doi:10.1038/295105a0; Rohling, 1994, doi:10.1016/0025-3227(94)90202-X) and increased organic-matter preservation due to oxygen depletion in more stagnant bottom waters (Rossignol-Strick et al., 1982, doi:10.1038/295105a0; Rohling, 1994, doi:10.1016/0025-3227(94)90202-X). Here we report that eastern Mediterranean Pliocene sapropels (Emeis et al., 1996, doi:10.2973/odp.proc.ir.160.102.1996) contain molecular fossils of a compound (isorenieratene) known to be synthesized by photosynthetic green sulphur bacteria, suggesting that sulphidic (euxinic) -and therefore anoxic- conditions prevailed in the photic zone of the water column. These sapropels also have a high trace-metal content, which is probably due to the efficient scavenging of these metals by precipitating sulphides in a euxinic water column. The abundance and sulphur-isotope composition of pyrite are consistent with iron sulphide formation in the water column. We conclude that basin-wide water-column euxinia occurred over substantial periods during Pliocene sapropel formation in the eastern Mediterranean Sea, and that the ultimate degradation of the increased organic-matter production was strongly influential in generating and sustaining the euxinic conditions.
Project(s):
Coverage:
Median Latitude: 34.846000 * Median Longitude: 25.162020 * South-bound Latitude: 33.796400 * West-bound Longitude: 17.750000 * North-bound Latitude: 36.260800 * East-bound Longitude: 32.725600
Date/Time Start: 1995-03-20T02:00:00 * Date/Time End: 1995-04-16T17:55:00
Minimum DEPTH, sediment/rock: 42.6 m * Maximum DEPTH, sediment/rock: 82.9 m
Event(s):
160-964D * Latitude: 36.260600 * Longitude: 17.750000 * Date/Time Start: 1995-03-20T02:00:00 * Date/Time End: 1995-03-20T16:45:00 * Elevation: -3660.0 m * Penetration: 108.6 m * Recovery: 112.2 m * Location: Eastern Basin * Campaign: Leg160 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 12 cores; 108.6 m cored; 0 m drilled; 103.3 % recovery
160-964E * Latitude: 36.260800 * Longitude: 17.750000 * Date/Time Start: 1995-03-20T16:45:00 * Date/Time End: 1995-03-21T00:45:00 * Elevation: -3661.0 m * Penetration: 85.5 m * Recovery: 54.32 m * Location: Eastern Basin * Campaign: Leg160 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 6 cores; 53 m cored; 0 m drilled; 102.5 % recovery
160-966C * Latitude: 33.796400 * Longitude: 32.701400 * Date/Time Start: 1995-03-28T13:12:00 * Date/Time End: 1995-03-29T03:20:00 * Elevation: -926.0 m * Penetration: 127 m * Recovery: 101.6 m * Location: Eastern Basin * Campaign: Leg160 * Basis: Joides Resolution * Method/Device: Drilling/drill rig (DRILL) * Comment: 17 cores; 127 m cored; 0 m drilled; 80 % recovery
Comment:
Sediment depth is given in mbsf. Enrichment factors are given with respect to average non-sapropel sediments around the sapropels.
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEvent
2CodeCodePassier, Hilde Fsapropel
3Sample code/labelSample labelPassier, Hilde FDSDP/ODP/IODP sample designation
4AGEAgeka BPGeocode
5DEPTH, sediment/rockDepth sedmGeocode
6CadmiumCdmg/kgPassier, Hilde F
7Enrichment factorEFPassier, Hilde FCd
8MolybdenumMomg/kgPassier, Hilde F
9Enrichment factorEFPassier, Hilde FMo
10NickelNimg/kgPassier, Hilde F
11Enrichment factorEFPassier, Hilde FNi
12SeleniumSemg/kgPassier, Hilde F
13Enrichment factorEFPassier, Hilde FSe
14VanadiumVmg/kgPassier, Hilde F
15Enrichment factorEFPassier, Hilde FV
16Carbon, organic, totalTOC%Passier, Hilde F
17Enrichment factorEFPassier, Hilde FTOC
18Accumulation rate, total organic carbonAcc rate TOCg/cm2/kaPassier, Hilde F
19BariumBamg/kgPassier, Hilde F
20Enrichment factorEFPassier, Hilde FBa
21Sulfur of pyriteS Py%Passier, Hilde F
22δ34S, pyriteδ34S Py‰ CDTPassier, Hilde F
23Isorenieratene derivativeIso derivPassier, Hilde F++ = abundant, + = trace, - = not detected
Size:
145 data points

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