<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-08-17">
<md:citation id="dataset997939">
<md:author id="dataset.author97608">
<md:lastName>Santos</md:lastName>
<md:firstName>Ricardo N</md:firstName>
<md:eMail>r.n.santos@unibas.ch</md:eMail>
<md:orcid>0000-0002-8252-3619</md:orcid>
<md:affiliation id="dataset.author97608.inst21115">
<md:name>University of Basel</md:name>
<md:URI>https://www.unibas.ch/de</md:URI>
<md:ROR>https://ror.org/02s6k3f65</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author60766">
<md:lastName>Nelson</md:lastName>
<md:firstName>Daniel B</md:firstName>
<md:eMail>daniel.nelson@unibas.ch</md:eMail>
<md:orcid>0000-0002-2716-7770</md:orcid>
<md:affiliation id="dataset.author60766.inst21115">
<md:name>University of Basel</md:name>
<md:URI>https://www.unibas.ch/de</md:URI>
<md:ROR>https://ror.org/02s6k3f65</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author113645">
<md:lastName>Klatt</md:lastName>
<md:firstName>Antonia</md:firstName>
<md:eMail>antonia.klatt@unibas.ch</md:eMail>
<md:affiliation id="dataset.author113645.inst21115">
<md:name>University of Basel</md:name>
<md:URI>https://www.unibas.ch/de</md:URI>
<md:ROR>https://ror.org/02s6k3f65</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author542">
<md:lastName>Schubert</md:lastName>
<md:firstName>Carsten J</md:firstName>
<md:eMail>carsten.schubert@eawag.ch</md:eMail>
<md:orcid>0000-0003-1668-5967</md:orcid>
<md:affiliation id="dataset.author542.inst22468">
<md:name>Swiss Federal Institute of Aquatic Science and Technology</md:name>
<md:optionalName>EAWAG</md:optionalName>
<md:ROR>https://ror.org/00pc48d59</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author38857">
<md:lastName>Dubois</md:lastName>
<md:firstName>Nathalie</md:firstName>
<md:orcid>0000-0003-2349-0826</md:orcid>
<md:affiliation id="dataset.author38857.inst22468">
<md:name>Swiss Federal Institute of Aquatic Science and Technology</md:name>
<md:optionalName>EAWAG</md:optionalName>
<md:ROR>https://ror.org/00pc48d59</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author59888">
<md:lastName>De Jonge</md:lastName>
<md:firstName>Cindy</md:firstName>
<md:eMail>dejonge.cindy@gmail.com</md:eMail>
<md:orcid>0000-0002-1127-8433</md:orcid>
<md:affiliation id="dataset.author59888.inst22094">
<md:name>ETH Zurich</md:name>
<md:URI>https://ethz.ch</md:URI>
<md:ROR>https://ror.org/05a28rw58</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author114251">
<md:lastName>Ladd</md:lastName>
<md:firstName>S Nemiah</md:firstName>
<md:eMail>n.ladd@unibas.ch</md:eMail>
<md:orcid>0000-0002-0132-5785</md:orcid>
<md:affiliation id="dataset.author114251.inst21115">
<md:name>University of Basel</md:name>
<md:URI>https://www.unibas.ch/de</md:URI>
<md:ROR>https://ror.org/02s6k3f65</md:ROR>
</md:affiliation>
</md:author>
<md:year>2026</md:year>
<md:title>Vegetation-corrected plant-wax reconstruction of precipitation δ²H at Rotsee, Switzerland, over the past 12.9 ka</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.pangaea.de/10.1594/PANGAEA.997939</md:URI>
<md:dateTime>2026-10-20T06:48:24</md:dateTime>
</md:citation>
<md:abstract>This dataset contains a vegetation-corrected reconstruction of the hydrogen isotope composition of precipitation (δ2Hprc) from sediment core ROT21, collected from Rotsee in central Switzerland in October 2021. The record covers 0.0567–12.8696 ka BP and comprises 63 observations reported with sediment depth and calibrated age. Reconstructed δ2Hprc values were calculated from measured n-C29 alkane δ2H values. Changes in the relative contributions of grasses and woody plants were accounted for using the relative abundances of long-chain n-alkanes and vegetation-specific apparent hydrogen isotope fractionation factors derived from a compilation of modern European plant-wax measurements. Uncertainty was propagated using 10,000 Monte Carlo simulations per sample; the dataset reports the central reconstructed values and the lower and upper limits of the 68% confidence interval in per mil relative to Vienna Standard Mean Ocean Water (VSMOW). The reconstruction was produced to separate variation in precipitation isotope composition from changes in sedimentary plant-wax δ2H caused by shifts in vegetation. The vegetation correction and uncertainty propagation were implemented using the R scripts by Santos (2026) archived at Zenodo (https://doi.org/10.5281/zenodo.18694984); the development repository is available at https://github.com/RicardoANSantos/Rotsee_d2Hprc. The underlying measured plant-wax data are archived in PANGAEA under doi:10.1594/PANGAEA.987812, and the complete methodology is described by Santos et al. (2026).</md:abstract>
<md:reference dataciteRelType="References" group="210" id="ref142029" relationType="Related to" relationTypeId="12">
<md:author id="ref142029.author97608">
<md:lastName>Santos</md:lastName>
<md:firstName>Ricardo N</md:firstName>
<md:eMail>r.n.santos@unibas.ch</md:eMail>
<md:orcid>0000-0002-8252-3619</md:orcid>
</md:author>
<md:author id="ref142029.author60766">
<md:lastName>Nelson</md:lastName>
<md:firstName>Daniel B</md:firstName>
<md:eMail>daniel.nelson@unibas.ch</md:eMail>
<md:orcid>0000-0002-2716-7770</md:orcid>
</md:author>
<md:author id="ref142029.author113645">
<md:lastName>Klatt</md:lastName>
<md:firstName>Antonia</md:firstName>
<md:eMail>antonia.klatt@unibas.ch</md:eMail>
</md:author>
<md:author id="ref142029.author542">
<md:lastName>Schubert</md:lastName>
<md:firstName>Carsten J</md:firstName>
<md:eMail>carsten.schubert@eawag.ch</md:eMail>
<md:orcid>0000-0003-1668-5967</md:orcid>
</md:author>
<md:author id="ref142029.author38857">
<md:lastName>Dubois</md:lastName>
<md:firstName>Nathalie</md:firstName>
<md:orcid>0000-0003-2349-0826</md:orcid>
</md:author>
<md:author id="ref142029.author59888">
<md:lastName>De Jonge</md:lastName>
<md:firstName>Cindy</md:firstName>
<md:eMail>dejonge.cindy@gmail.com</md:eMail>
<md:orcid>0000-0002-1127-8433</md:orcid>
</md:author>
<md:author id="ref142029.author88832">
<md:lastName>Ladd</md:lastName>
<md:firstName>S N</md:firstName>
<md:orcid>0000-0002-0132-5785</md:orcid>
</md:author>
<md:year>2026</md:year>
<md:title>Central European Hydroclimate Since the Younger Dryas Inferred From Vegetation‐Corrected Sedimentary Plant Wax δ 2 H Values</md:title>
<md:type id="ref142029.reftype1">journal article</md:type>
<md:source id="ref142029.journal16885" type="journal">Paleoceanography and Paleoclimatology</md:source>
<md:volume>41(3)</md:volume>
<md:URI>https://doi.org/10.1029/2025PA005401</md:URI>
<md:pages>e2025PA005401</md:pages>
</md:reference>
<md:reference dataciteRelType="IsDocumentedBy" group="640" id="refds987812" relationType="Further details" relationTypeId="17">
<md:author id="refds987812.author97608">
<md:lastName>Santos</md:lastName>
<md:firstName>Ricardo N</md:firstName>
<md:eMail>r.n.santos@unibas.ch</md:eMail>
<md:orcid>0000-0002-8252-3619</md:orcid>
</md:author>
<md:author id="refds987812.author60766">
<md:lastName>Nelson</md:lastName>
<md:firstName>Daniel B</md:firstName>
<md:eMail>daniel.nelson@unibas.ch</md:eMail>
<md:orcid>0000-0002-2716-7770</md:orcid>
</md:author>
<md:author id="refds987812.author113645">
<md:lastName>Klatt</md:lastName>
<md:firstName>Antonia</md:firstName>
<md:eMail>antonia.klatt@unibas.ch</md:eMail>
</md:author>
<md:author id="refds987812.author542">
<md:lastName>Schubert</md:lastName>
<md:firstName>Carsten J</md:firstName>
<md:eMail>carsten.schubert@eawag.ch</md:eMail>
<md:orcid>0000-0003-1668-5967</md:orcid>
</md:author>
<md:author id="refds987812.author38857">
<md:lastName>Dubois</md:lastName>
<md:firstName>Nathalie</md:firstName>
<md:orcid>0000-0003-2349-0826</md:orcid>
</md:author>
<md:author id="refds987812.author59888">
<md:lastName>De Jonge</md:lastName>
<md:firstName>Cindy</md:firstName>
<md:eMail>dejonge.cindy@gmail.com</md:eMail>
<md:orcid>0000-0002-1127-8433</md:orcid>
</md:author>
<md:author id="refds987812.author88832">
<md:lastName>Ladd</md:lastName>
<md:firstName>S N</md:firstName>
<md:orcid>0000-0002-0132-5785</md:orcid>
</md:author>
<md:year>2026</md:year>
<md:title>Plant wax composition of sediment core ROT21 from the Rotsee, Switzerland</md:title>
<md:type id="refds987812.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.org/10.1594/PANGAEA.987812</md:URI>
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<md:extent>
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<md:westBoundLongitude>9.3133333</md:westBoundLongitude>
<md:eastBoundLongitude>9.3133333</md:eastBoundLongitude>
<md:southBoundLatitude>48.0694444</md:southBoundLatitude>
<md:northBoundLatitude>48.0694444</md:northBoundLatitude>
<md:meanLongitude>9.3133333</md:meanLongitude>
<md:meanLatitude>48.0694444</md:meanLatitude>
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<md:temporal>
<md:minDateTime>2021-10-03T00:00:00</md:minDateTime>
<md:maxDateTime>2021-10-05T00:00:00</md:maxDateTime>
</md:temporal>
<md:elevation geocodeId="geocode1" name="DEPTH, sediment/rock" unit="m">
<md:min>0.193</md:min>
<md:max>10.09966667</md:max>
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<md:award id="award4508">
<md:funder id="award4508.funder21115" semanticURI="https://ror.org/02s6k3f65">
<md:name>University of Basel</md:name>
<md:URI>https://www.unibas.ch/de</md:URI>
<md:ROR>https://ror.org/02s6k3f65</md:ROR>
</md:funder>
<md:number>PCEFP2 194211</md:number>
<md:title>ADAPT: Algal Dynamics And Productivity through</md:title>
<md:URI>https://duw.unibas.ch/en/forschungsgruppen/organic-geochemistry/adapt/</md:URI>
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<md:event displayTypeName="Event" id="event3311407" typeName="Generic Event">
<md:label>ROT21</md:label>
<md:latitude>48.0694444</md:latitude>
<md:longitude>9.3133333</md:longitude>
<md:location id="event3311407.loc1.term76814">
<md:name> Rotsee, Switzerland</md:name>
</md:location>
<md:elevation>419.0</md:elevation>
<md:dateTime>2021-10-03T00:00:00</md:dateTime>
<md:latitude2>48.0694444</md:latitude2>
<md:longitude2>9.3133333</md:longitude2>
<md:elevation2>419.0</md:elevation2>
<md:dateTime2>2021-10-05T00:00:00</md:dateTime2>
<md:method id="event3311407.method11111">
<md:name>Gravity corer, UWITEC</md:name>
<md:optionalName>GCUWI</md:optionalName>
</md:method>
<md:attribute attid="37748" name="Lake water depth">5.5</md:attribute>
<md:comment>2021-10-03/05</md:comment>
</md:event>
<md:size unit="data points">189</md:size>
<md:license id="license21">
<md:label>CC-BY-4.0</md:label>
<md:name>Creative Commons Attribution 4.0 International</md:name>
<md:URI>https://creativecommons.org/licenses/by/4.0/</md:URI>
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<md:matrixColumn behaviour="1" col="0" format="0.0000" id="col0.ds16035392" source="geocode" type="numeric">
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<md:name>DEPTH, sediment/rock</md:name>
<md:shortName>Depth sed</md:shortName>
<md:unit>m</md:unit>
<md:term endOffset="5" fragment="1" id="col0.ds16035392.geocode1.term1073131" semanticURI="urn:obo:pato:term:0001595" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>depth</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0001595</md:URI>
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<md:term endOffset="15" fragment="2" id="col0.ds16035392.geocode1.term38263" startOffset="7" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sediment</md:name>
<md:URI>http://purl.obolibrary.org/obo/ENVO_00002007</md:URI>
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<md:term endOffset="20" fragment="3" id="col0.ds16035392.geocode1.term41056" startOffset="16" terminologyId="18" terminologyLabel="PAN-MicroBio">
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<md:term id="col0.ds16035392.geocode1.term43863" semanticURI="http://qudt.org/1.1/vocab/quantity#Length" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Length</md:name>
<md:optionalName>L</md:optionalName>
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<md:PI id="col0.ds16035392.pi97608">
<md:lastName>Santos</md:lastName>
<md:firstName>Ricardo N</md:firstName>
<md:eMail>r.n.santos@unibas.ch</md:eMail>
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<md:caption>Depth sed [m]</md:caption>
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<md:name>AGE</md:name>
<md:shortName>Age</md:shortName>
<md:unit>ka BP</md:unit>
<md:URI>http://en.wikipedia.org/wiki/Kyr</md:URI>
<md:term endOffset="3" fragment="1" id="col1.ds16035393.geocode2205.term1073135" semanticURI="urn:obo:pato:term:0000011" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>age</md:name>
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<md:term id="col1.ds16035393.geocode2205.term43975" semanticURI="http://qudt.org/1.1/vocab/quantity#Time" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Time</md:name>
<md:optionalName>T</md:optionalName>
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<md:method id="col1.ds16035393.method462">
<md:name>Age, calibrated</md:name>
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<md:PI id="col1.ds16035393.pi97608">
<md:lastName>Santos</md:lastName>
<md:firstName>Ricardo N</md:firstName>
<md:eMail>r.n.santos@unibas.ch</md:eMail>
<md:orcid>0000-0002-8252-3619</md:orcid>
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<md:comment>before present refers to 1950 CE</md:comment>
<md:caption>Age [ka BP]</md:caption>
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<md:matrixColumn col="2" format="0.00000000" id="col2.ds16035394" source="data" type="numeric">
<md:parameter id="col2.ds16035394.param579061">
<md:name>δ Deuterium, precipitation, reconstructed, median</md:name>
<md:shortName>δD precip reconst median</md:shortName>
<md:unit>‰ SMOW</md:unit>
<md:term endOffset="41" fragment="1" id="col2.ds16035394.param579061.term44348" startOffset="28" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>reconstructed</md:name>
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</md:parameter>
<md:method id="col2.ds16035394.method19767">
<md:name>n-Alkane relative-abundance-based vegetation correction; see reference(s)</md:name>
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<md:PI id="col2.ds16035394.pi97608">
<md:lastName>Santos</md:lastName>
<md:firstName>Ricardo N</md:firstName>
<md:eMail>r.n.santos@unibas.ch</md:eMail>
<md:orcid>0000-0002-8252-3619</md:orcid>
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<md:comment>relative to VSMOW</md:comment>
<md:caption>δD precip reconst median [‰ SMOW]</md:caption>
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<md:unit>‰ SMOW</md:unit>
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<md:lastName>Santos</md:lastName>
<md:firstName>Ricardo N</md:firstName>
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<md:orcid>0000-0002-8252-3619</md:orcid>
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<md:comment>relative to VSMOW</md:comment>
<md:caption>δD precip reconst 68% CI low [‰ SMOW]</md:caption>
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<md:name>n-Alkane relative-abundance-based vegetation correction; see reference(s)</md:name>
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<md:lastName>Santos</md:lastName>
<md:firstName>Ricardo N</md:firstName>
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<md:orcid>0000-0002-8252-3619</md:orcid>
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<md:comment>relative to VSMOW</md:comment>
<md:caption>δD precip reconst 68% CI up [‰ SMOW]</md:caption>
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<md:curationLevel id="curlevel30">
<md:label>CurationLevelC</md:label>
<md:name>Enhanced curation</md:name>
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