<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-04-13">
<md:citation id="dataset996469">
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<md:lastName>Schubert</md:lastName>
<md:firstName>Christina Martina</md:firstName>
<md:eMail>christina.cs.schubert@fau.de</md:eMail>
<md:affiliation id="dataset.author111462.inst20360">
<md:name>Friedrich-Alexander-Universität Erlangen-Nürnberg, GeoZentrum Nordbayern</md:name>
<md:ROR>https://ror.org/00f7hpc57</md:ROR>
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<md:author id="dataset.author37087">
<md:lastName>van Geldern</md:lastName>
<md:firstName>Robert</md:firstName>
<md:eMail>robert.van.geldern@fau.de</md:eMail>
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<md:orcid>0000-0003-2786-2893</md:orcid>
<md:affiliation id="dataset.author37087.inst20360">
<md:name>Friedrich-Alexander-Universität Erlangen-Nürnberg, GeoZentrum Nordbayern</md:name>
<md:ROR>https://ror.org/00f7hpc57</md:ROR>
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</md:author>
<md:author id="dataset.author43415">
<md:lastName>Barth</md:lastName>
<md:firstName>Johannes A C</md:firstName>
<md:eMail>johannes.barth@fau.de</md:eMail>
<md:orcid>0000-0002-3494-4507</md:orcid>
<md:affiliation id="dataset.author43415.inst20360">
<md:name>Friedrich-Alexander-Universität Erlangen-Nürnberg, GeoZentrum Nordbayern</md:name>
<md:ROR>https://ror.org/00f7hpc57</md:ROR>
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</md:author>
<md:author id="dataset.author111461">
<md:lastName>Visser</md:lastName>
<md:firstName>Anna-Neva</md:firstName>
<md:eMail>anna-neva.visser@fau.de</md:eMail>
<md:affiliation id="dataset.author111461.inst20360">
<md:name>Friedrich-Alexander-Universität Erlangen-Nürnberg, GeoZentrum Nordbayern</md:name>
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<md:year>2026</md:year>
<md:title>Hydrology, hydrochemistry, carbon dynamics, and calculated pCO2 and CO2 fluxes from the Wiesent, a karst headwater stream in Germany, 2023-2024</md:title>
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<md:URI>https://doi.pangaea.de/10.1594/PANGAEA.996469</md:URI>
<md:dateTime>2026-08-12T10:00:20</md:dateTime>
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<md:abstract>These datasets contains hydrological, hydrochemical, and biogeochemical measurements collected along a 3.25 km spring-to-stream transect in the Wiesent karst headwater in northern Bavaria, Germany, between March 2023 and May 2024. Monthly observations at 13 sites include field parameters (discharge, pH, electrical conductivity, redox potential, and water temperature), major ions and trace metals, dissolved and particulate carbon pools (DIC, DOC, POC), stable carbon and oxygen isotopes (δ13CDIC/DOC/POC [‰ VPDB], δ18ODO [‰ VSMOW]), and calculated partial pressure of CO2 (pCO2), CO2 fluxes, and gas-transfer velocities. In addition, a 24 h diel survey conducted in August 2023 provides the same field, carbon-system, stable isotope, pCO2, FCO2 and gas-transfer parameters at three representative sites along the transect at 4 h intervals. The dataset provides a basis for studies of karst hydrochemistry, carbon and oxygen cycling, carbonate buffering, spring-water and surface-water interactions, and CO2 evasion under varying hydroclimatic conditions.</md:abstract>
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<md:author id="ref140758.author111462">
<md:lastName>Schubert</md:lastName>
<md:firstName>Christina Martina</md:firstName>
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<md:author id="ref140758.author37087">
<md:lastName>van Geldern</md:lastName>
<md:firstName>Robert</md:firstName>
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<md:author id="ref140758.author43415">
<md:lastName>Barth</md:lastName>
<md:firstName>Johannes A C</md:firstName>
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<md:author id="ref140758.author111461">
<md:lastName>Visser</md:lastName>
<md:firstName>Anna-Neva</md:firstName>
<md:eMail>anna-neva.visser@fau.de</md:eMail>
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<md:prepubStatus>submitted</md:prepubStatus>
<md:title>Stable but transient – episodic sensitivity in a buffered German karst headwater stream</md:title>
<md:type id="ref140758.reftype1">journal article</md:type>
<md:source id="ref140758.journal6667" relatedTermIds="34073" type="journal">Hydrological Processes</md:source>
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<md:extent>
<md:geographic>
<md:westBoundLongitude>11.1536399999999</md:westBoundLongitude>
<md:eastBoundLongitude>11.19159</md:eastBoundLongitude>
<md:southBoundLatitude>49.9728399999999</md:southBoundLatitude>
<md:northBoundLatitude>49.97744</md:northBoundLatitude>
<md:meanLongitude>11.168661671794855</md:meanLongitude>
<md:meanLatitude>49.97605849230767</md:meanLatitude>
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<md:temporal>
<md:minDateTime>2023-03-09T00:00:00</md:minDateTime>
<md:maxDateTime>2024-05-13T00:00:00</md:maxDateTime>
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<md:number>BA 2207/27-1</md:number>
<md:title>KarLoss</md:title>
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<md:number>GE 2338/4-1</md:number>
<md:title>KarLoss</md:title>
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<md:size unit="datasets">5</md:size>
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<md:additionalSearchableContent>Sample ID | Sampling date | Date | Distance | Stream flow, width | Stream flow w | Stream flow, depth | Stream flow d | Discharge | Q | Impeller, Miniflügel M1, SEBA Hydrometrie | Temperature, water | Temp | Multi-parameter portable meter, Xylem Analytics, WTW MultiLine® 3630 IDS | pH | Conductivity | Cond | Oxidation reduction (RedOx) potential | Eh | Oxygen | O2 | Fluoride | F- | Ion chromatograph, Metrohm, 930 Compact IC Flex | Chloride | Cl- | Sulfate | [SO4]2- | Nitrate | [NO3]- | Sodium | Na | Inductively coupled plasma mass spectrometer (ICP-MS), Thermo Fisher Scientific Inc., iCAP Qc | Magnesium | Mg | Potassium | K | Silicon | Si | Calcium | Ca | Aluminium | Al | Manganese | Mn | Iron | Fe | Sampling date/time, experiment | Date/time sampling exp | Alkalinity, total | AT | Eco Titrando, Methrom AG | Carbon, inorganic, dissolved | DIC | Isotope ratio mass spectrometer (IRMS), Thermo Scientific, Delta plus XP | ‰ VPDB | δ13C, dissolved inorganic carbon | δ13C DIC | Carbon, organic, dissolved | DOC | Total Organic Carbon Analyzers, Xylem, OI Analytical Aurora 1030W TOC Analyzer [SKU: 322110] coupled to a DELTA V Plus Advantage isotope ratio mass spectrometer | δ13C, dissolved organic carbon | δ13C DOC | Carbon, organic, particulate | POC | Element analyser, Costech Analytical Technologies, ECS 4010  CHNS-O | δ13C, particulate organic carbon | δ13C POC | Carbon dioxide, partial pressure | pCO2 | Calculated from temperature, pH values and c(DIC) | Carbon dioxide efflux rate | CO2 efflux | Calculated from k600 and concentration gradient of dissolved CO2 in stream water and in the water at equilibrium with overlaying atmosphere | Transfer velocity, scaled | k600 | Calculated from stream hydraulic parameters | ‰ VSMOW | δ18O, dissolved oxygen | δ18O O2 | Isotope-Ratio Mass spectrometry (IRMS), ThermoFisher Scientific, Delta V Advantage with GasBench II carbonate preparation device</md:additionalSearchableContent>
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