/* DATA DESCRIPTION: Citation: Brüning, Romy; Bünning, Lillian Tabea Hannah; Scheer, Lars Christian; Strehse, Jennifer Susanne; Lindemeyer, Jacqueline; Gundlach, Maren; Schuster, Romina Marietta; Marx, Ute; Brenner, Matthias; Maser, Edmund (2026): Chemical analysis of explosive compounds in common dab collected during RV Heincke expedition HE635 from munition dumping areas west of Sylt (NNW03L) and south-west of Heligoland (North Sea) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.996429 Abstract: This dataset documents field investigations regarding the release of legacy World War I and II munition explosive compounds into marine biota, focusing on munition dumping areas west of the island of Sylt and south west of the island of Heligoland, North Sea. Flatfish Limanda limanda (common dab) was chosen as a sentinel species. Sampling was conducted during the HE635 cruise in March 2024 with the research vessel Heincke of the Alfred Wegener Institute (AWI). Fish were caught using bottom trawls deployed close to the borders of the dumping areas marked on the sea charts. Before dissection, captured fish were transferred to seawater tanks, and only live fish were taken for analysis. Each individual was measured, weighed, and after killing the fish livers were assessed macroscopically. In addition, biometric factors were measured to determine condition factors as indicators of general health. Tissue samples of gills, liver, and muscle, as well as blood, bile, and urine, were taken, immediately frozen in liquid nitrogen, and stored at -20°C before chemical analysis. Sample processing in the laboratory followed established protocols (Bünning et al. 2021). In brief, all samples were homogenized and then extracted using solid phase extraction (SPE). Bile, urine, and blood samples were treated with β-glucuronidase (Helix pomatia), followed by a liquid-liquid extraction step for blood and bile samples before SPE. All samples were analyzed by gas chromatography coupled with triple quadrupole mass spectrometry (GC-MS/MS) for the explosive compound 2,4,6-trinitrotoluene (TNT), its metabolites 2-amino-4,6-dinitrotoluene (2-ADNT) and 4-amino-2,6-dinitrotoluene (4-ADNT), and the explosive by-products 2,4-dinitrotoluene (2,4-DNT) and 1,3-dinitrobenzene (1,3-DNB). Additionally, liquid chromatography coupled with triple quadrupole mass spectrometry (LC-MS/MS) was used to quantify the nitramine explosives hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX). The dataset includes measured compound concentrations and associated sample metadata. Supplement to: Schuster, Romina Marietta; Binder, Franziska Isabell; Bünning, Lillian Tabea Hannah; Brüning, Romy; Grassel, Philipp; Wichert, Uwe; Maser, Edmund; Brenner, Matthias (submitted): Decades after the wars – flatfish common dab (Limanda limanda) caught around military wrecks loaded with munitions in the North Sea show severe health impairments. Environmental Pollution References: Bünning, Tobias Hartwig; Strehse, Jennifer; Hollmann, Ann; Bötticher, Tom; Maser, Edmund (2021): A Toolbox for the Determination of Nitroaromatic Explosives in Marine Water, Sediment, and Biota Samples on Femtogram Levels by GC-MS/MS. Toxics, 9(3), 60, https://doi.org/10.3390/toxics9030060 Additional metadata: Brüning, Romy (2026): Quantification and detection limits of explosive compounds in the study. https://download.pangaea.de/reference/140782/attachments/LOD_LOQ_Fish.pdf Project(s): DAM sustainMare - CONMAR: CONcepts for conventional MArine Munition Remediation in the German North and Baltic Sea (CONMAR) (URI: https://conmar-munition.eu/) Research Mission of the German Marine Research Alliance (DAM): Protection and sustainable use of marine areas (sustainMare) (URI: https://www.sustainmare.de/index.php.en) Funding: Federal Ministry of Education and Research (BMBF) (URI: https://www.bmftr.bund.de), grant/award no. 03F0912B: DAM sustainMare - CONMAR, AWI (URI: https://foerderportal.bund.de/foekat/jsp/SucheAction.do?actionMode=view&fkz=03F0912B) Federal Ministry of Education and Research (BMBF) (URI: https://www.bmftr.bund.de), grant/award no. 03F0912H: DAM sustainMare - CONMAR, Kiel University (URI: https://foerderportal.bund.de/foekat/jsp/SucheAction.do?actionMode=view&fkz=03F0912H) Coverage: MEDIAN LATITUDE: 54.867188 * MEDIAN LONGITUDE: 7.991719 * SOUTH-BOUND LATITUDE: 54.150000 * WEST-BOUND LONGITUDE: 7.920000 * NORTH-BOUND LATITUDE: 55.050000 * EAST-BOUND LONGITUDE: 8.010000 DATE/TIME START: 2024-03-17T07:09:45 * DATE/TIME END: 2024-03-20T07:11:05 MINIMUM ELEVATION: -47 m a.s.l. * MAXIMUM ELEVATION: -15 m a.s.l. Event(s): HE635_48-1 * LATITUDE START: 54.150000 * LONGITUDE START: 7.920000 * LATITUDE END: 54.110000 * LONGITUDE END: 7.920000 * DATE/TIME START: 2024-03-17T07:09:45 * DATE/TIME END: 2024-03-17T07:41:30 * ELEVATION START: -47.0 m * ELEVATION END: -34.0 m * LOCATION: North Sea * CAMPAIGN: HE635 (MecoMM-NS II) * BASIS: Heincke (URI: https://doi.org/10.17815/jlsrf-3-164) * METHOD/DEVICE: Bottom trawl (BT) HE635_89-1 * LATITUDE START: 55.050000 * LONGITUDE START: 8.010000 * LATITUDE END: 55.020000 * LONGITUDE END: 8.000000 * DATE/TIME START: 2024-03-20T07:11:05 * DATE/TIME END: 2024-03-20T07:50:25 * ELEVATION START: -15.0 m * ELEVATION END: -14.0 m * LOCATION: North Sea * CAMPAIGN: HE635 (MecoMM-NS II) * BASIS: Heincke (URI: https://doi.org/10.17815/jlsrf-3-164) * METHOD/DEVICE: Bottom trawl (BT) Comment: NNW03L: dumping site code from the Federal and State Monitoring Programme (BLMP) Parameter(s): Event label (Event) * PI: Schuster, Romina Marietta (romina.schuster@awi.de) Comment (Comment) * PI: Schuster, Romina Marietta (romina.schuster@awi.de) * COMMENT: Station Sample ID (Sample ID) * PI: Schuster, Romina Marietta (romina.schuster@awi.de) DATE/TIME (Date/Time) * GEOCODE * PI: Schuster, Romina Marietta (romina.schuster@awi.de) LATITUDE (Latitude) * GEOCODE * PI: Schuster, Romina Marietta (romina.schuster@awi.de) * COMMENT: rounded to two decimal degrees LONGITUDE (Longitude) * GEOCODE * PI: Schuster, Romina Marietta (romina.schuster@awi.de) * COMMENT: rounded to two decimal degrees Location (Location) * PI: Schuster, Romina Marietta (romina.schuster@awi.de) ELEVATION [m a.s.l.] (Elevation) * GEOCODE * PI: Schuster, Romina Marietta (romina.schuster@awi.de) * METHOD/DEVICE: CTD Limanda limanda, total length [mm] (L. limanda TL) * PI: Marx, Ute (Ute.Marx@awi.de) * METHOD/DEVICE: Measuring board Limanda limanda, wet mass [g] (L. limanda wm) * PI: Marx, Ute (Ute.Marx@awi.de) * METHOD/DEVICE: Precision scale, Sartorius, R160P Limanda limanda, sex (L. limanda sex) * PI: Marx, Ute (Ute.Marx@awi.de) * METHOD/DEVICE: Visual inspection * COMMENT: f - female, m - male Limanda limanda, muscle, 2,4,6-trinitrotoluene, per dry mass [ng/g] (L. limanda muscle TNT/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Muscle TNT Limanda limanda, muscle, 4-amino-2,6-dinitrotoluene, per dry mass [ng/g] (L. limanda muscle 4-ADNT/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Muscle 4-ADNT Limanda limanda, muscle, 2-amino-4,6-dinitrotoluene, per dry mass [ng/g] (L. limanda muscle 2-ADNT/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Muscle 2-ADNT Limanda limanda, muscle, 1,3-dinitrobenzene, per dry mass [ng/g] (L. limanda muscle 1,3-DNB/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Muscle 1,3-DNB Limanda limanda, muscle, 2,4-dinitrotoluene, per dry mass [ng/g] (L. limanda muscle 2,4-DNT/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Muscle 2,4-DNT Limanda limanda, muscle, hexahydro-1,3,5-trinitro-1,3,5-triazine, per dry mass [ng/g] (L. limanda muscle RDX/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Muscle RDX Limanda limanda, muscle, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine, per dry mass [ng/g] (L. limanda muscle HMX/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Muscle HMX Limanda limanda, bile, 2,4,6-trinitrotoluene [ng/ml] (L. limanda bile TNT) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Bile TNT Limanda limanda, bile, 4-amino-2,6-dinitrolouene [ng/ml] (L. limanda bile 4-ADNT) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Bile 4-ADNT Limanda limanda, bile, 2-amino-4,6-dinitrolouene [ng/ml] (L. limanda bile 2-ADNT) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Bile 2-ADNT Limanda limanda, bile, 1,3-dinitrobenzene [ng/ml] (L. limanda bile 1,3-DNB) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Bile 1,3-DNB Limanda limanda, bile, 2,4-dinitrotoluene [ng/ml] (L. limanda bile 2,4-DNT) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Bile 2,4-DNT Limanda limanda, bile, hexahydro-1,3,5-trinitro-1,3,5-triazine [ng/ml] (L. limanda bile RDX) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Bile RDX Limanda limanda, bile, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine [ng/ml] (L. limanda bile HMX) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Bile HMX Limanda limanda, liver, 2,4,6-trinitrotoluene, per wet mass [ng/g] (L. limanda liver TNT/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Liver TNT Limanda limanda, liver, 4-amino-2,6-dinitrotoluene, per wet mass [ng/g] (L. limanda liver 4-ADNT/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Liver 4-ADNT Limanda limanda, liver, 2-amino-4,6-dinitrotoluene, per wet mass [ng/g] (L. limanda liver 2-ADNT/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Liver 2-ADNT Limanda limanda, liver, 1,3-dinitrobenzene, per wet mass [ng/g] (L. limanda liver 1,3-DNB/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Liver 1,3-DNB Limanda limanda, liver, 2,4-dinitrotoluene, per wet mass [ng/g] (L. limanda liver 2,4-DNT/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Liver 2,4-DNT Limanda limanda, liver, hexahydro-1,3,5-trinitro-1,3,5-triazine, per wet mass [ng/g] (L. limanda liver RDX/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Liver RDX Limanda limanda, liver, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine, per wet mass [ng/g] (L. limanda liver HMX/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Liver HMX Limanda limanda, blood, 2,4,6-trinitrotoluene, per wet mass [ng/g] (L. limanda blood TNT/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Blood TNT Limanda limanda, blood, 4-amino-2,6-dinitrotoluene, per wet mass [ng/g] (L. limanda blood 4-ADNT/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Blood 4-ADNT Limanda limanda, blood, 2-amino-4,6-dinitrotoluene, per wet mass [ng/g] (L. limanda blood 2-ADNT/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Blood 2-ADNT Limanda limanda, blood, 1,3-dinitrobenzene, per wet mass [ng/g] (L. limanda blood 1,3-DNB/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Blood 1,3-DNB Limanda limanda, blood, 2,4-dinitrotoluene, per wet mass [ng/g] (L. limanda blood 2,4-DNT/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Blood 2,4-DNT Limanda limanda, blood, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine, per wet mass [ng/g] (L. limanda blood HMX/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Blood HMX Limanda limanda, blood, hexahydro-1,3,5-trinitro-1,3,5-triazine, per wet mass [ng/g] (L. limanda blood RDX/wm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Blood RDX Limanda limanda, urine, 2,4,6-trinitrotoluene [ng/ml] (L. limanda urine TNT) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Urine TNT Limanda limanda, urine, 4-amino-2,6-dinitrotoluene [ng/ml] (L. limanda urine 4-ADNT) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Urine 4-ADNT Limanda limanda, urine, 2-amino-4,6-dinitrotoluene [ng/ml] (L. limanda urine 2-ADNT) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Urine 2-ADNT Limanda limanda, urine, 1,3-dinitrobenzene [ng/ml] (L. limanda urine 1,3-DNB) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Urine 1,3-DNB Limanda limanda, urine, 2,4-dinitrotoluene [ng/ml] (L. limanda urine 2,4-DNT) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Urine 2,4-DNT Limanda limanda, urine, hexahydro-1,3,5-trinitro-1,3,5-triazine [ng/ml] (L. limanda urine RDX) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Urine RDX Limanda limanda, urine, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine [ng/ml] (L. limanda urine HMX) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Brüning, Romy (https://orcid.org/0009-0000-5589-4249, bruening@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Urine HMX Limanda limanda, gills, 2,4,6-trinitrotoluene, per dry mass [ng/g] (L. limanda gills TNT/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Gills TNT Limanda limanda, gills, 4-amino-2,6-dinitrotoluene, per dry mass [ng/g] (L. limanda gills 4-ADNT/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Gills 4-ADNT Limanda limanda, gills, 2-amino-4,6-dinitrotoluene, per dry mass [ng/g] (L. limanda gills 2-ADNT/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Gills 2-ADNT Limanda limanda, gills, 1,3-dinitrobenzene, per dry mass [ng/g] (L. limanda gills 1,3-DNB/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Gills 1,3-DNB Limanda limanda, gills, 2,4-dinitrotoluene, per dry mass [ng/g] (L. limanda gills 2,4-DNT/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Gas chromatography, coupled with tandem mass spectrometer (GC-MS/MS), Thermo Scientific, TSQ8000 Evo * COMMENT: Gills 2,4-DNT Limanda limanda, gills, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine, per dry mass [ng/g] (L. limanda gills HMX/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Gills HMX Limanda limanda, gills, hexahydro-1,3,5-trinitro-1,3,5-triazine, per dry mass [ng/g] (L. limanda gills RDX/dm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 Validation flag/comment (Flag comm) * PI: Bünning, Lillian Tabea Hannah (https://orcid.org/0000-0002-2147-6804, buenning@toxi.uni-kiel.de) * METHOD/DEVICE: Liquid chromatography tandem mass spectrometry (LC-MS/MS), AB SCIEX, QTRAP 5500 * COMMENT: Gills RDX License: Creative Commons Attribution 4.0 International (CC-BY-4.0) (URI: https://creativecommons.org/licenses/by/4.0/) Status: Curation Level: Enhanced curation (URI: https://wiki.pangaea.de/wiki/Curation_levels) Size: 4398 data points */ Event Comment (Station) Sample ID Date/Time Latitude (rounded to two decimal degrees) Longitude (rounded to two decimal degrees) Location Elevation [m a.s.l.] (CTD) L. limanda TL [mm] (Measuring board) L. limanda wm [g] (Precision scale, Sartorius, R...) L. limanda sex (f - female, m - male, Visual ...) L. limanda muscle TNT/dm [ng/g] (Gas chromatography, coupled w...) Flag comm (Muscle TNT, Gas chromatograph...) L. limanda muscle 4-ADNT/dm [ng/g] (Gas chromatography, coupled w...) Flag comm (Muscle 4-ADNT, Gas chromatogr...) L. limanda muscle 2-ADNT/dm [ng/g] (Gas chromatography, coupled w...) Flag comm (Muscle 2-ADNT, Gas chromatogr...) L. limanda muscle 1,3-DNB/dm [ng/g] (Gas chromatography, coupled w...) Flag comm (Muscle 1,3-DNB, Gas chromatog...) L. limanda muscle 2,4-DNT/dm [ng/g] (Gas chromatography, coupled w...) Flag comm (Muscle 2,4-DNT, Gas chromatog...) L. limanda muscle RDX/dm [ng/g] (Liquid chromatography tandem ...) Flag comm (Muscle RDX, Liquid chromatogr...) L. limanda muscle HMX/dm [ng/g] (Liquid chromatography tandem ...) Flag comm (Muscle HMX, Liquid chromatogr...) L. limanda bile TNT [ng/ml] (Gas chromatography, coupled w...) Flag comm (Bile TNT, Gas chromatography,...) L. limanda bile 4-ADNT [ng/ml] (Gas chromatography, coupled w...) Flag comm (Bile 4-ADNT, Gas chromatograp...) L. limanda bile 2-ADNT [ng/ml] (Gas chromatography, coupled w...) Flag comm (Bile 2-ADNT, Gas chromatograp...) L. limanda bile 1,3-DNB [ng/ml] (Gas chromatography, coupled w...) Flag comm (Bile 1,3-DNB, Gas chromatogra...) L. limanda bile 2,4-DNT [ng/ml] (Gas chromatography, coupled w...) Flag comm (Bile 2,4-DNT, Gas chromatogra...) L. limanda bile RDX [ng/ml] (Liquid chromatography tandem ...) Flag comm (Bile RDX, Liquid chromatograp...) L. limanda bile HMX [ng/ml] (Liquid chromatography tandem ...) Flag comm (Bile HMX, Liquid chromatograp...) L. limanda liver TNT/wm [ng/g] (Gas chromatography, coupled w...) Flag comm (Liver TNT, Gas chromatography...) L. limanda liver 4-ADNT/wm [ng/g] (Gas chromatography, coupled w...) Flag comm (Liver 4-ADNT, Gas chromatogra...) L. limanda liver 2-ADNT/wm [ng/g] (Gas chromatography, coupled w...) Flag comm (Liver 2-ADNT, Gas chromatogra...) L. limanda liver 1,3-DNB/wm [ng/g] (Gas chromatography, coupled w...) Flag comm (Liver 1,3-DNB, Gas chromatogr...) L. limanda liver 2,4-DNT/wm [ng/g] (Gas chromatography, coupled w...) Flag comm (Liver 2,4-DNT, Gas chromatogr...) L. limanda liver RDX/wm [ng/g] (Liquid chromatography tandem ...) Flag comm (Liver RDX, Liquid chromatogra...) L. limanda liver HMX/wm [ng/g] (Liquid chromatography tandem ...) Flag comm (Liver HMX, Liquid chromatogra...) L. limanda blood TNT/wm [ng/g] (Gas chromatography, coupled w...) Flag comm (Blood TNT, Gas chromatography...) L. limanda blood 4-ADNT/wm [ng/g] (Gas chromatography, coupled w...) Flag comm (Blood 4-ADNT, Gas chromatogra...) L. limanda blood 2-ADNT/wm [ng/g] (Gas chromatography, coupled w...) Flag comm (Blood 2-ADNT, Gas chromatogra...) L. limanda blood 1,3-DNB/wm [ng/g] (Gas chromatography, coupled w...) Flag comm (Blood 1,3-DNB, Gas chromatogr...) L. limanda blood 2,4-DNT/wm [ng/g] (Gas chromatography, coupled w...) Flag comm (Blood 2,4-DNT, Gas chromatogr...) L. limanda blood HMX/wm [ng/g] (Liquid chromatography tandem ...) Flag comm (Blood HMX, Liquid chromatogra...) L. limanda blood RDX/wm [ng/g] (Liquid chromatography tandem ...) Flag comm (Blood RDX, Liquid chromatogra...) L. limanda urine TNT [ng/ml] (Gas chromatography, coupled w...) Flag comm (Urine TNT, Gas chromatography...) L. limanda urine 4-ADNT [ng/ml] (Gas chromatography, coupled w...) Flag comm (Urine 4-ADNT, Gas chromatogra...) L. limanda urine 2-ADNT [ng/ml] (Gas chromatography, coupled w...) Flag comm (Urine 2-ADNT, Gas chromatogra...) L. limanda urine 1,3-DNB [ng/ml] (Gas chromatography, coupled w...) Flag comm (Urine 1,3-DNB, Gas chromatogr...) L. limanda urine 2,4-DNT [ng/ml] (Gas chromatography, coupled w...) Flag comm (Urine 2,4-DNT, Gas chromatogr...) L. limanda urine RDX [ng/ml] (Liquid chromatography tandem ...) Flag comm (Urine RDX, Liquid chromatogra...) L. limanda urine HMX [ng/ml] (Liquid chromatography tandem ...) Flag comm (Urine HMX, Liquid chromatogra...) L. limanda gills TNT/dm [ng/g] (Gas chromatography, coupled w...) Flag comm (Gills TNT, Gas chromatography...) L. limanda gills 4-ADNT/dm [ng/g] (Gas chromatography, coupled w...) Flag comm (Gills 4-ADNT, Gas chromatogra...) L. limanda gills 2-ADNT/dm [ng/g] (Gas chromatography, coupled w...) Flag comm (Gills 2-ADNT, Gas chromatogra...) L. limanda gills 1,3-DNB/dm [ng/g] (Gas chromatography, coupled w...) Flag comm (Gills 1,3-DNB, Gas chromatogr...) L. limanda gills 2,4-DNT/dm [ng/g] (Gas chromatography, coupled w...) Flag comm (Gills 2,4-DNT, Gas chromatogr...) L. limanda gills HMX/dm [ng/g] (Liquid chromatography tandem ...) Flag comm (Gills HMX, Liquid chromatogra...) L. limanda gills RDX/dm [ng/g] (Liquid chromatography tandem ...) Flag comm (Gills RDX, Liquid chromatogra...) HE635_48-1 dumping area southwest of Heligoland 1 2024-03-17T07:09:45 54.15 7.92 North Sea -47 200 73 f 0.5 LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 0.8 >LOQ 0.6 >LOQ 0.5 LOQ 0.1 LOQ 0.3 LOQ 0.0 LOQ 1.8 >LOQ 1.9 >LOQ 1.3 LOQ 0.1 LOQ 1.2 >LOQ 0.7 >LOQ 0.8 LOQ 0.3 LOQ 0.2 LOQ 0.2 LOQ 0.2 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.2 LOQ 0.1 LOQ 1.5 >LOQ 1.1 >LOQ 0.5 LOQ 0.0 LOQ 0.5 >LOQ 0.3 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 0.0 LOQ 0.4 LOQ 0.3 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.7 >LOQ 0.4 LOQ 0.1 LOQ 0.2 LOQ 0.7 >LOQ 0.4 LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 0.3 >LOQ 0.5 >LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 0.0 LOQ 0.5 >LOQ 0.0 LOQ 0.1 LOQ 0.6 >LOQ 0.3 LOQ 2.2 >LOQ 0.7 LOQ 0.1 LOQ 0.0 LOQ 0.1 LOQ 0.0 LOQ 0.1 LOQ 3.8 >LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 2.2 >LOQ 2.8 >LOQ 0.6 LOQ 2.3 >LOQ 1.3 >LOQ 0.0 LOQ 0.0 LOQ 0.9 >LOQ 0.0 LOQ 0.7 >LOQ 0.7 >LOQ 0.0 LOQ 0.1 LOQ 0.1 LOQ 0.0 LOQ 0.1 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 1.5 >LOQ 2.1 >LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 3.0 >LOQ 3.2 >LOQ 1.3 >LOQ 0.0 LOQ 0.1 LOQ 0.0 LOQ 1.0 >LOQ 0.6 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 1.6 >LOQ 0.9 LOQ 0.1 LOQ >LOQ >LOQ LOQ 0.9 >LOQ 1.0 >LOQ 1.6 >LOQ 0.0 LOQ 0.0 LOQ 3.6 >LOQ 1.8 >LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 0.3 LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 0.1 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.1 LOQ 0.1 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 2.2 >LOQ 0.0 LOQ 0.1 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 0.0 LOQ 1.7 >LOQ 0.0 LOQ 0.0 LOQ 0.4 LOQ 0.0