<?xml version="1.0" encoding="UTF-8"?><resource xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.3/metadata.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4"><identifier identifierType="URL">https://doi.pangaea.de/10.1594/PANGAEA.996213</identifier><creators><creator><creatorName>Marín-Samper, Laura</creatorName><givenName>Laura</givenName><familyName>Marín-Samper</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-6825-0992</nameIdentifier></creator><creator><creatorName>Arístegui, Javier</creatorName><givenName>Javier</givenName><familyName>Arístegui</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-7526-7741</nameIdentifier></creator><creator><creatorName>Faucher, Giulia</creatorName><givenName>Giulia</givenName><familyName>Faucher</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0001-8930-477X</nameIdentifier><affiliation affiliationIdentifierScheme="ROR" affiliationIdentifier="https://ror.org/02h2x0161">GEOMAR - Helmholtz Centre for Ocean Research Kiel</affiliation></creator><creator><creatorName>Kittu, Leila</creatorName><givenName>Leila</givenName><familyName>Kittu</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-3986-8179</nameIdentifier><affiliation affiliationIdentifierScheme="ROR" affiliationIdentifier="https://ror.org/02h2x0161">GEOMAR - Helmholtz Centre for Ocean Research Kiel</affiliation></creator><creator><creatorName>Boersma, Maarten</creatorName><givenName>Maarten</givenName><familyName>Boersma</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0003-1010-026X</nameIdentifier><affiliation affiliationIdentifierScheme="ROR" affiliationIdentifier="https://ror.org/032e6b942">Alfred Wegener Institute for Polar and Marine Research, Bremerhaven (1986-2013)</affiliation></creator><creator><creatorName>Riebesell, Ulf</creatorName><givenName>Ulf</givenName><familyName>Riebesell</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-9442-452X</nameIdentifier><affiliation affiliationIdentifierScheme="ROR" affiliationIdentifier="https://ror.org/02h2x0161">GEOMAR - Helmholtz Centre for Ocean Research Kiel</affiliation></creator></creators><titles><title>KOSMOS 2023 Helgoland mesocosm study on ocean alkalinity enhancement: Microbial metabolic rates</title></titles><publisher>PANGAEA</publisher><publicationYear>2026</publicationYear><subjects><subject>metabolic rates</subject><subject>ocean alkalinity enhancement</subject><subject>Ocean Alkalinity Enhancement (OAE)</subject><subject>Phytoplankton</subject><subject>Primary production</subject><subject subjectScheme="Parameter">Type of study</subject><subject subjectScheme="Parameter">Event label</subject><subject subjectScheme="Parameter">Day of experiment</subject><subject subjectScheme="Parameter">DATE/TIME</subject><subject subjectScheme="Parameter">Identification number</subject><subject subjectScheme="Parameter">Treatment: dilution type</subject><subject subjectScheme="Parameter">Treatment: alkalinity, total</subject><subject subjectScheme="Parameter">Treatment</subject><subject subjectScheme="Parameter">Sample code/label</subject><subject subjectScheme="Parameter">Respiration rate, oxygen, community</subject><subject subjectScheme="Parameter">Net community production of oxygen</subject><subject subjectScheme="Parameter">Gross community production of oxygen</subject><subject subjectScheme="Parameter">Balance</subject><subject subjectScheme="Parameter">Depth, description</subject><subject subjectScheme="Method">Mesocosm experiment</subject><subject subjectScheme="Campaign">KOSMOS_2023</subject><subject subjectScheme="Project">DAM CDRmare - RETAKE: CO2 removal by alkalinity enhancement: potential, benefits and risks (RETAKE)</subject><subject subjectScheme="Project">Ocean Alk-Align (OceanAlkAlign)</subject><subject subjectScheme="Project">Ocean-based Negative Emission Technologies (OceanNETs)</subject><subject subjectScheme="Project">Research Mission of the German Marine Research Alliance (DAM): Marine carbon sinks in decarbonisation pathways (CDRmare)</subject></subjects><dates><date dateType="Collected">2023-03-14T00:00:00/2023-04-17T00:00:00</date></dates><resourceType resourceTypeGeneral="Dataset">Dataset</resourceType><sizes><size>2798 data points</size></sizes><formats><format>text/tab-separated-values</format></formats><rightsList><rights rightsURI="https://creativecommons.org/licenses/by/4.0/" schemeURI="https://spdx.org/licenses/" rightsIdentifierScheme="SPDX" rightsIdentifier="CC-BY-4.0">Creative Commons Attribution 4.0 International</rights><rights>Data access is restricted (moratorium, sensitive data, license constraints)</rights></rightsList><descriptions><description descriptionType="Abstract">Ocean alkalinity enhancement (OAE) is a marine carbon dioxide removal (mCDR) approach that can also mitigate ocean acidification. However, its biological impacts are expected to depend on the magnitude, timing, and dilution of alkalinity additions. To investigate these factors, a mesocosm experiment simulated hydrated lime additions using two six-level alkalinity gradients (up to ΔTA 1250 µmol kg⁻¹): one with immediate full-column mixing and another with mixing delayed by two days. These treatments simulated rapid (e.g. from a moving vessel in open ocean) and slow (e .g. point source or land-based applications in poorly mixed environments)dilution scenarios, representing different hydrodynamic conditions that may occur following real-world alkalinity additions. Gross production (GP), net community production (NCP) and community respiration (CR),  determined from in vitro oxygen production and consumption, together with chlorophyll a, were monitored over a 35-day period. Spring bloom initiation was delayed non-linearly at low fCO₂, with reduced absolute and biomass-normalized production occurring in treatments exposed to fCO₂ below ~70 and 30 µatm respectively. These findings indicate that phytoplankton communities may be generally resilient to realistic OAE scenarios while helping to define ecologically relevant fCO₂ thresholds for safe OAE deployment.</description></descriptions><geoLocations><geoLocation><geoLocationPoint><pointLongitude>7.900000000000001</pointLongitude><pointLatitude>54.183300000000024</pointLatitude></geoLocationPoint></geoLocation><geoLocation><geoLocationPlace>Helgoland</geoLocationPlace></geoLocation></geoLocations><fundingReferences><fundingReference><funderName>Federal Ministry of Education and Research</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100002347</funderIdentifier><awardNumber awardURI="https://foerderportal.bund.de/foekat/jsp/SucheAction.do?actionMode=view&amp;fkz=03F0895A">03F0895A</awardNumber><awardTitle>DAM CDRmare - RETAKE, GEOMAR</awardTitle></fundingReference><fundingReference><funderName>Horizon 2020 of the European Commission</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100007601</funderIdentifier><awardNumber awardURI="https://doi.org/10.3030/731065">731065</awardNumber><awardTitle>Network of Leading European AQUAtic MesoCOSM Facilities Connecting Mountains to Oceans from the Arctic to the Mediterranean</awardTitle></fundingReference><fundingReference><funderName>Horizon 2020 of the European Commission</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100007601</funderIdentifier><awardNumber awardURI="doi:10.3030/869357">869357</awardNumber><awardTitle>OceanNETs: Ocean-based Negative Emission Technologies</awardTitle></fundingReference></fundingReferences></resource>