<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-04-13">
<md:citation id="dataset994131">
<md:author id="dataset.author117459">
<md:lastName>Ota</md:lastName>
<md:firstName>Hayu</md:firstName>
<md:eMail>h-ota@g.ecc.u-tokyo.ac.jp</md:eMail>
<md:orcid>0009-0001-7029-2067</md:orcid>
<md:affiliation id="dataset.author117459.inst22346">
<md:name>Atmosphere and Ocean Research Institute, The University of Tokyo</md:name>
<md:ROR>https://ror.org/057zh3y96</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author41736">
<md:lastName>Kuroda</md:lastName>
<md:firstName>Junichiro</md:firstName>
<md:eMail>kuroda@aori.u-tokyo.ac.jp</md:eMail>
<md:orcid>0000-0002-2218-4854</md:orcid>
<md:affiliation id="dataset.author41736.inst22346">
<md:name>Atmosphere and Ocean Research Institute, The University of Tokyo</md:name>
<md:ROR>https://ror.org/057zh3y96</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author52385">
<md:lastName>Orihashi</md:lastName>
<md:firstName>Yuji</md:firstName>
<md:orcid>0000-0001-7715-3847</md:orcid>
<md:affiliation id="dataset.author52385.inst22761">
<md:name>Faculty of Science and Technology, Graduate School of Science and Technology, Hirosaki University</md:name>
<md:URI>http://www.hirosaki-u.ac.jp/</md:URI>
<md:ROR>https://ror.org/02syg0q74</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author85678">
<md:lastName>Schmitz</md:lastName>
<md:firstName>Mark D</md:firstName>
<md:eMail>markschmitz@boisestate.edu</md:eMail>
<md:orcid>0000-0003-2888-0321</md:orcid>
<md:affiliation id="dataset.author85678.inst22762">
<md:name>Department of Geosciences, Boise State University</md:name>
<md:optionalName>BSU</md:optionalName>
<md:URI>https://www.boisestate.edu/</md:URI>
<md:ROR>https://ror.org/02e3zdp86</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author63855">
<md:lastName>Takashima</md:lastName>
<md:firstName>Reishi</md:firstName>
<md:eMail>reishi.takashima.a7@tohoku.ac.jp</md:eMail>
<md:orcid>0000-0003-1830-6887</md:orcid>
<md:affiliation id="dataset.author63855.inst22763">
<md:name>The Center for Academic Resources and Archives, Tohoku University Museum</md:name>
</md:affiliation>
</md:author>
<md:year>2026</md:year>
<md:title>Major element compositions of the sample series  KWR4 from the Kawaruppu section</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.org/10.1594/PANGAEA.994131</md:URI>
<md:dateTime>2026-05-19T05:42:38</md:dateTime>
</md:citation>
<md:abstract>This dataset contains major element compositions of the KWR4 sample series collected from the high-resolution interval of the Kawaruppu section, Nemuro Group, Hokkaido, Japan. These data were obtained to evaluate whether the osmium isotope ratios and platinum group element concentrations of the same samples were affected by diagenetic alteration. Major element compositions were measured by a RIGAKU ZSX Primus II X-ray fluorescence (XRF) spectrometer at Atmosphere and Ocean Research Institute (AORI), the University of Tokyo (Kashiwa).</md:abstract>
<md:reference dataciteRelType="IsSupplementTo" group="200" id="ref139853" relationType="Supplement to" relationTypeId="5">
<md:author id="ref139853.author117459">
<md:lastName>Ota</md:lastName>
<md:firstName>Hayu</md:firstName>
<md:eMail>h-ota@g.ecc.u-tokyo.ac.jp</md:eMail>
<md:orcid>0009-0001-7029-2067</md:orcid>
</md:author>
<md:author id="ref139853.author41736">
<md:lastName>Kuroda</md:lastName>
<md:firstName>Junichiro</md:firstName>
<md:eMail>kuroda@aori.u-tokyo.ac.jp</md:eMail>
<md:orcid>0000-0002-2218-4854</md:orcid>
</md:author>
<md:author id="ref139853.author103762">
<md:lastName>Hayashi</md:lastName>
<md:firstName>Keiichi</md:firstName>
<md:eMail>hayashi-keiichi@hro.or.jp</md:eMail>
</md:author>
<md:author id="ref139853.author49863">
<md:lastName>Hoshi</md:lastName>
<md:firstName>Hiroyuki</md:firstName>
<md:eMail>hoshi@auecc.aichi-edu.ac.jp</md:eMail>
<md:orcid>0000-0002-9920-2205</md:orcid>
</md:author>
<md:author id="ref139853.author26941">
<md:lastName>Sawada</md:lastName>
<md:firstName>Ken</md:firstName>
<md:eMail>sawadak@sci.hokudai.ac.jp</md:eMail>
<md:orcid>0000-0003-3298-5716</md:orcid>
</md:author>
<md:author id="ref139853.author117517">
<md:lastName>Hosogaya</md:lastName>
<md:firstName>Kohei</md:firstName>
</md:author>
<md:author id="ref139853.author31983">
<md:lastName>Nishi</md:lastName>
<md:firstName>Hiroshi</md:firstName>
<md:eMail>hiroshi.nishi.b3@tohoku.ac.jp</md:eMail>
<md:orcid>0009-0007-4984-334X</md:orcid>
</md:author>
<md:author id="ref139853.author27808">
<md:lastName>Ishikawa</md:lastName>
<md:firstName>Akira</md:firstName>
<md:orcid>0000-0002-8938-0200</md:orcid>
</md:author>
<md:author id="ref139853.author41733">
<md:lastName>Suzuki</md:lastName>
<md:firstName>Katsuhiko</md:firstName>
<md:orcid>0000-0003-4266-5046</md:orcid>
</md:author>
<md:author id="ref139853.author103760">
<md:lastName>Ikeda</md:lastName>
<md:firstName>Masashi A</md:firstName>
<md:eMail>ma_sunny_ikeda@eis.hokudai.ac.jp</md:eMail>
</md:author>
<md:author id="ref139853.author52385">
<md:lastName>Orihashi</md:lastName>
<md:firstName>Yuji</md:firstName>
<md:orcid>0000-0001-7715-3847</md:orcid>
</md:author>
<md:author id="ref139853.author66394">
<md:lastName>Schmitz</md:lastName>
<md:firstName>Mark</md:firstName>
<md:orcid>0000-0003-2888-0321</md:orcid>
</md:author>
<md:author id="ref139853.author78145">
<md:lastName>Gyawali</md:lastName>
<md:firstName>Babu Ram</md:firstName>
<md:eMail>babugyawali@yahoo.com</md:eMail>
<md:orcid>0000-0002-9896-8399</md:orcid>
</md:author>
<md:author id="ref139853.author83172">
<md:lastName>Matsumoto</md:lastName>
<md:firstName>Hironao</md:firstName>
<md:eMail>matsumoto@aori.u-tokyo.ac.jp</md:eMail>
<md:orcid>0000-0002-1420-2565</md:orcid>
</md:author>
<md:author id="ref139853.author63855">
<md:lastName>Takashima</md:lastName>
<md:firstName>Reishi</md:firstName>
<md:eMail>reishi.takashima.a7@tohoku.ac.jp</md:eMail>
<md:orcid>0000-0003-1830-6887</md:orcid>
</md:author>
<md:year>2026</md:year>
<md:title>The Chicxulub impact signature in East Asia</md:title>
<md:type id="ref139853.reftype1">journal article</md:type>
<md:source id="ref139853.journal17037" type="journal">Communications Earth &amp; Environment</md:source>
<md:URI>https://doi.org/10.1038/s43247-026-03602-z</md:URI>
</md:reference>
<md:extent>
<md:elevation geocodeId="geocode25539" name="SECTION, height" unit="m">
<md:min>173.0</md:min>
<md:max>173.55</md:max>
</md:elevation>
<md:topoType id="topotype3">vertical profile</md:topoType>
</md:extent>
<md:award id="award4975">
<md:funder id="award4975.funder20747" semanticURI="https://doi.org/10.13039/501100001691">
<md:name>Japan Society for the Promotion of Science</md:name>
<md:optionalName>JSPS</md:optionalName>
<md:URI>https://www.jsps.go.jp/english/</md:URI>
<md:crossrefFunderId>https://doi.org/10.13039/501100001691</md:crossrefFunderId>
</md:funder>
<md:number>17K05674</md:number>
<md:title>High resolution age model and paleoenvironmental change for K/Pg boundary</md:title>
<md:URI>https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-17K05674/</md:URI>
</md:award>
<md:award id="award2780">
<md:funder id="award2780.funder20747" semanticURI="https://doi.org/10.13039/501100001691">
<md:name>Japan Society for the Promotion of Science</md:name>
<md:optionalName>JSPS</md:optionalName>
<md:URI>https://www.jsps.go.jp/english/</md:URI>
<md:crossrefFunderId>https://doi.org/10.13039/501100001691</md:crossrefFunderId>
</md:funder>
<md:number>18KK0091</md:number>
<md:title>Improvement of Cretaceous Geologic Time Scale</md:title>
<md:URI>https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-18KK0091</md:URI>
</md:award>
<md:award id="award2779">
<md:funder id="award2779.funder20747" semanticURI="https://doi.org/10.13039/501100001691">
<md:name>Japan Society for the Promotion of Science</md:name>
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<md:URI>https://www.jsps.go.jp/english/</md:URI>
<md:crossrefFunderId>https://doi.org/10.13039/501100001691</md:crossrefFunderId>
</md:funder>
<md:number>21H04503</md:number>
<md:title>Environmental changes during the Latest Cretaceous Mass Extinction Event recorded in the complete K/Pg boundary sequence discovered firstly in East Asia</md:title>
<md:URI>https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-21H04503</md:URI>
</md:award>
<md:award id="award4977">
<md:funder id="award4977.funder20747" semanticURI="https://doi.org/10.13039/501100001691">
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<md:crossrefFunderId>https://doi.org/10.13039/501100001691</md:crossrefFunderId>
</md:funder>
<md:number>22H01342</md:number>
<md:title>The Cretaceous-Paleogene Boundary in the Southern Hemisphere: Osmium isotopic record to fingerprint flood basalt volcanism</md:title>
<md:URI>https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-23K22613/</md:URI>
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<md:award id="award4976">
<md:funder id="award4976.funder20747" semanticURI="https://doi.org/10.13039/501100001691">
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<md:URI>https://www.jsps.go.jp/english/</md:URI>
<md:crossrefFunderId>https://doi.org/10.13039/501100001691</md:crossrefFunderId>
</md:funder>
<md:number>22K18426</md:number>
<md:title>Linkage of the Earth's tipping points and the subseafloor biosphere</md:title>
<md:URI>https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-22K18426/</md:URI>
</md:award>
<md:award id="award4978">
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<md:crossrefFunderId>https://doi.org/10.13039/501100001691</md:crossrefFunderId>
</md:funder>
<md:number>23H00153</md:number>
<md:title>Analysis of internal Earth nitrogen using pupulin nitrogen isotope ratio</md:title>
<md:URI>https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-23H00153/</md:URI>
</md:award>
<md:award id="award4985">
<md:funder id="award4985.funder20747" semanticURI="https://doi.org/10.13039/501100001691">
<md:name>Japan Society for the Promotion of Science</md:name>
<md:optionalName>JSPS</md:optionalName>
<md:URI>https://www.jsps.go.jp/english/</md:URI>
<md:crossrefFunderId>https://doi.org/10.13039/501100001691</md:crossrefFunderId>
</md:funder>
<md:number>JPJSCCA20250004</md:number>
<md:title>Warm-period Climate Change Research Center with the International Ocean Drilling School [WarmCCR]</md:title>
<md:URI>https://sites.google.com/view/kochi-jsps-core2core/english?authuser=0</md:URI>
</md:award>
<md:size unit="data points">105</md:size>
<md:license id="license21">
<md:label>CC-BY-4.0</md:label>
<md:name>Creative Commons Attribution 4.0 International</md:name>
<md:URI>https://creativecommons.org/licenses/by/4.0/</md:URI>
</md:license>
<md:matrixColumn col="0" id="col0.ds15922902" source="data" type="string">
<md:parameter id="col0.ds15922902.param790">
<md:name>Sample code/label</md:name>
<md:shortName>Sample label</md:shortName>
</md:parameter>
<md:PI id="col0.ds15922902.pi117459">
<md:lastName>Ota</md:lastName>
<md:firstName>Hayu</md:firstName>
<md:eMail>h-ota@g.ecc.u-tokyo.ac.jp</md:eMail>
<md:orcid>0009-0001-7029-2067</md:orcid>
</md:PI>
<md:caption>Sample label</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="1" col="1" format="0.00" id="col1.ds15922903" source="geocode" type="numeric">
<md:parameter id="col1.ds15922903.geocode25539">
<md:name>SECTION, height</md:name>
<md:shortName>Section</md:shortName>
<md:unit>m</md:unit>
<md:term endOffset="15" fragment="1" id="col1.ds15922903.geocode25539.term1073288" semanticURI="urn:obo:pato:term:0000119" startOffset="9" terminologyId="14" terminologyLabel="PATO">
<md:name>height</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0000119</md:URI>
</md:term>
<md:term id="col1.ds15922903.geocode25539.term43863" semanticURI="http://qudt.org/1.1/vocab/quantity#Length" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Length</md:name>
<md:optionalName>L</md:optionalName>
<md:URI>http://dbpedia.org/resource/Length</md:URI>
</md:term>
</md:parameter>
<md:PI id="col1.ds15922903.pi117459">
<md:lastName>Ota</md:lastName>
<md:firstName>Hayu</md:firstName>
<md:eMail>h-ota@g.ecc.u-tokyo.ac.jp</md:eMail>
<md:orcid>0009-0001-7029-2067</md:orcid>
</md:PI>
<md:comment>Stratigraphic levels are given in meters from the base of the Kawaruppu section, which is defined as 0 m.</md:comment>
<md:caption>Section [m]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="2" id="col2.ds15922904" source="data" type="string">
<md:parameter id="col2.ds15922904.param29333">
<md:name>Main Lithology</md:name>
<md:shortName>Main lith</md:shortName>
</md:parameter>
<md:PI id="col2.ds15922904.pi117459">
<md:lastName>Ota</md:lastName>
<md:firstName>Hayu</md:firstName>
<md:eMail>h-ota@g.ecc.u-tokyo.ac.jp</md:eMail>
<md:orcid>0009-0001-7029-2067</md:orcid>
</md:PI>
<md:caption>Main lith</md:caption>
</md:matrixColumn>
<md:matrixColumn col="3" format="0.000" id="col3.ds15922905" source="data" type="numeric">
<md:parameter id="col3.ds15922905.param1825">
<md:name>Sodium oxide</md:name>
<md:shortName>Na2O</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="12" fragment="1" id="col3.ds15922905.param1825.term49257" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sodium oxide</md:name>
<md:optionalName>Na2O</md:optionalName>
<md:URI>https://pubchem.ncbi.nlm.nih.gov/compound/73971</md:URI>
</md:term>
<md:term id="col3.ds15922905.param1825.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col3.ds15922905.method19080">
<md:name>X-ray fluorescence spectrometer (XRF), Rigaku Holdings Corporation, ZSX Primus II</md:name>
</md:method>
<md:PI id="col3.ds15922905.pi117459">
<md:lastName>Ota</md:lastName>
<md:firstName>Hayu</md:firstName>
<md:eMail>h-ota@g.ecc.u-tokyo.ac.jp</md:eMail>
<md:orcid>0009-0001-7029-2067</md:orcid>
</md:PI>
<md:comment>mass%</md:comment>
<md:caption>Na2O [%]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="4" format="0.000" id="col4.ds15922906" source="data" type="numeric">
<md:parameter id="col4.ds15922906.param707">
<md:name>Magnesium oxide</md:name>
<md:shortName>MgO</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="15" fragment="1" id="col4.ds15922906.param707.term1074058" semanticURI="http://purl.obolibrary.org/obo/CHEBI_31794" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>magnesium oxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_31794</md:URI>
</md:term>
<md:term id="col4.ds15922906.param707.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col4.ds15922906.method19080">
<md:name>X-ray fluorescence spectrometer (XRF), Rigaku Holdings Corporation, ZSX Primus II</md:name>
</md:method>
<md:PI id="col4.ds15922906.pi117459">
<md:lastName>Ota</md:lastName>
<md:firstName>Hayu</md:firstName>
<md:eMail>h-ota@g.ecc.u-tokyo.ac.jp</md:eMail>
<md:orcid>0009-0001-7029-2067</md:orcid>
</md:PI>
<md:comment>mass%</md:comment>
<md:caption>MgO [%]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="5" format="0.000" id="col5.ds15922907" source="data" type="numeric">
<md:parameter id="col5.ds15922907.param704">
<md:name>Aluminium oxide</md:name>
<md:shortName>Al2O3</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="15" fragment="1" id="col5.ds15922907.param704.term1074034" semanticURI="http://purl.obolibrary.org/obo/CHEBI_30187" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>aluminium oxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_30187</md:URI>
</md:term>
<md:term id="col5.ds15922907.param704.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col5.ds15922907.method19080">
<md:name>X-ray fluorescence spectrometer (XRF), Rigaku Holdings Corporation, ZSX Primus II</md:name>
</md:method>
<md:PI id="col5.ds15922907.pi117459">
<md:lastName>Ota</md:lastName>
<md:firstName>Hayu</md:firstName>
<md:eMail>h-ota@g.ecc.u-tokyo.ac.jp</md:eMail>
<md:orcid>0009-0001-7029-2067</md:orcid>
</md:PI>
<md:comment>mass%</md:comment>
<md:caption>Al2O3 [%]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="6" format="0.000" id="col6.ds15922908" source="data" type="numeric">
<md:parameter id="col6.ds15922908.param702">
<md:name>Silicon dioxide</md:name>
<md:shortName>SiO2</md:shortName>
<md:unit>%</md:unit>
<md:URI>https://en.wikipedia.org/wiki/Silicon_dioxide</md:URI>
<md:term endOffset="15" fragment="1" id="col6.ds15922908.param702.term1073224" semanticURI="http://purl.obolibrary.org/obo/CHEBI_30563" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>silicon dioxide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_30563</md:URI>
</md:term>
<md:term id="col6.ds15922908.param702.term43794" semanticURI="http://qudt.org/1.1/vocab/quantity#DimensionlessRatio" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Dimensionless Ratio</md:name>
<md:optionalName>ψ</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col6.ds15922908.method19080">
<md:name>X-ray fluorescence spectrometer (XRF), Rigaku Holdings Corporation, ZSX Primus II</md:name>
</md:method>
<md:PI id="col6.ds15922908.pi117459">
<md:lastName>Ota</md:lastName>
<md:firstName>Hayu</md:firstName>
<md:eMail>h-ota@g.ecc.u-tokyo.ac.jp</md:eMail>
<md:orcid>0009-0001-7029-2067</md:orcid>
</md:PI>
<md:comment>mass%</md:comment>
<md:caption>SiO2 [%]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="7" format="0.000" id="col7.ds15922909" source="data" type="numeric">
<md:parameter id="col7.ds15922909.param709">
<md:name>Phosphorus pentoxide</md:name>
<md:shortName>P2O5</md:shortName>
<md:unit>%</md:unit>
<md:term endOffset="16" fragment="1" id="col7.ds15922909.param709.term1074191" semanticURI="http://purl.obolibrary.org/obo/CHEBI_37349" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>phosphorus oxide</md:name>
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