<?xml version="1.0" encoding="UTF-8"?><resource xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.3/metadata.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4"><identifier identifierType="DOI">10.1594/PANGAEA.994131</identifier><creators><creator><creatorName>Ota, Hayu</creatorName><givenName>Hayu</givenName><familyName>Ota</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0009-0001-7029-2067</nameIdentifier><affiliation affiliationIdentifierScheme="ROR" affiliationIdentifier="https://ror.org/057zh3y96">Atmosphere and Ocean Research Institute, The University of Tokyo</affiliation></creator><creator><creatorName>Kuroda, Junichiro</creatorName><givenName>Junichiro</givenName><familyName>Kuroda</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-2218-4854</nameIdentifier><affiliation affiliationIdentifierScheme="ROR" affiliationIdentifier="https://ror.org/057zh3y96">Atmosphere and Ocean Research Institute, The University of Tokyo</affiliation></creator><creator><creatorName>Orihashi, Yuji</creatorName><givenName>Yuji</givenName><familyName>Orihashi</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0001-7715-3847</nameIdentifier><affiliation affiliationIdentifierScheme="ROR" affiliationIdentifier="https://ror.org/02syg0q74">Faculty of Science and Technology, Graduate School of Science and Technology, Hirosaki University</affiliation></creator><creator><creatorName>Schmitz, Mark D</creatorName><givenName>Mark D</givenName><familyName>Schmitz</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0003-2888-0321</nameIdentifier><affiliation affiliationIdentifierScheme="ROR" affiliationIdentifier="https://ror.org/02e3zdp86">Department of Geosciences, Boise State University</affiliation></creator><creator><creatorName>Takashima, Reishi</creatorName><givenName>Reishi</givenName><familyName>Takashima</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0003-1830-6887</nameIdentifier><affiliation>The Center for Academic Resources and Archives, Tohoku University Museum</affiliation></creator></creators><titles><title>Major element compositions of the sample series  KWR4 from the Kawaruppu section</title></titles><publisher>PANGAEA</publisher><publicationYear>2026</publicationYear><subjects><subject>Cretaceous-Paleogene boundary</subject><subject>East Asia</subject><subject>IODP³</subject><subject>Osmium</subject><subject>zircon U-Pb geochronology</subject><subject subjectScheme="Parameter">Sample code/label</subject><subject subjectScheme="Parameter">SECTION, height</subject><subject subjectScheme="Parameter">Main Lithology</subject><subject subjectScheme="Parameter">Sodium oxide</subject><subject subjectScheme="Parameter">Magnesium oxide</subject><subject subjectScheme="Parameter">Aluminium oxide</subject><subject subjectScheme="Parameter">Silicon dioxide</subject><subject subjectScheme="Parameter">Phosphorus pentoxide</subject><subject subjectScheme="Parameter">Potassium oxide</subject><subject subjectScheme="Parameter">Calcium oxide</subject><subject subjectScheme="Parameter">Titanium dioxide</subject><subject subjectScheme="Parameter">Chromium(III) oxide</subject><subject subjectScheme="Parameter">Manganese oxide</subject><subject subjectScheme="Parameter">Iron oxide, Fe2O3</subject><subject subjectScheme="Parameter">Nickel oxide</subject><subject subjectScheme="Parameter">Loss on ignition</subject><subject subjectScheme="Method">X-ray fluorescence spectrometer (XRF), Rigaku Holdings Corporation, ZSX Primus II</subject></subjects><resourceType resourceTypeGeneral="Dataset">Dataset</resourceType><relatedIdentifiers><relatedIdentifier relatedIdentifierType="DOI" relationType="IsSupplementTo">10.1038/s43247-026-03602-z</relatedIdentifier></relatedIdentifiers><sizes><size>105 data points</size></sizes><formats><format>text/tab-separated-values</format></formats><rightsList><rights rightsURI="https://creativecommons.org/licenses/by/4.0/" schemeURI="https://spdx.org/licenses/" rightsIdentifierScheme="SPDX" rightsIdentifier="CC-BY-4.0">Creative Commons Attribution 4.0 International</rights></rightsList><descriptions><description descriptionType="Abstract">This dataset contains major element compositions of the KWR4 sample series collected from the high-resolution interval of the Kawaruppu section, Nemuro Group, Hokkaido, Japan. These data were obtained to evaluate whether the osmium isotope ratios and platinum group element concentrations of the same samples were affected by diagenetic alteration. Major element compositions were measured by a RIGAKU ZSX Primus II X-ray fluorescence (XRF) spectrometer at Atmosphere and Ocean Research Institute (AORI), the University of Tokyo (Kashiwa).</description></descriptions><fundingReferences><fundingReference><funderName>Japan Society for the Promotion of Science</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100001691</funderIdentifier><awardNumber awardURI="https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-17K05674/">17K05674</awardNumber><awardTitle>High resolution age model and paleoenvironmental change for K/Pg boundary</awardTitle></fundingReference><fundingReference><funderName>Japan Society for the Promotion of Science</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100001691</funderIdentifier><awardNumber awardURI="https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-18KK0091">18KK0091</awardNumber><awardTitle>Improvement of Cretaceous Geologic Time Scale</awardTitle></fundingReference><fundingReference><funderName>Japan Society for the Promotion of Science</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100001691</funderIdentifier><awardNumber awardURI="https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-21H04503">21H04503</awardNumber><awardTitle>Environmental changes during the Latest Cretaceous Mass Extinction Event recorded in the complete K/Pg boundary sequence discovered firstly in East Asia</awardTitle></fundingReference><fundingReference><funderName>Japan Society for the Promotion of Science</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100001691</funderIdentifier><awardNumber awardURI="https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-23K22613/">22H01342</awardNumber><awardTitle>The Cretaceous-Paleogene Boundary in the Southern Hemisphere: Osmium isotopic record to fingerprint flood basalt volcanism</awardTitle></fundingReference><fundingReference><funderName>Japan Society for the Promotion of Science</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100001691</funderIdentifier><awardNumber awardURI="https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-22K18426/">22K18426</awardNumber><awardTitle>Linkage of the Earth's tipping points and the subseafloor biosphere</awardTitle></fundingReference><fundingReference><funderName>Japan Society for the Promotion of Science</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100001691</funderIdentifier><awardNumber awardURI="https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-23H00153/">23H00153</awardNumber><awardTitle>Analysis of internal Earth nitrogen using pupulin nitrogen isotope ratio</awardTitle></fundingReference><fundingReference><funderName>Japan Society for the Promotion of Science</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100001691</funderIdentifier><awardNumber awardURI="https://sites.google.com/view/kochi-jsps-core2core/english?authuser=0">JPJSCCA20250004</awardNumber><awardTitle>Warm-period Climate Change Research Center with the International Ocean Drilling School [WarmCCR]</awardTitle></fundingReference></fundingReferences></resource>