<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2024-07-19">
<md:citation id="dataset993653">
<md:author id="dataset.author82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
<md:affiliation id="dataset.author82895.inst12761">
<md:name>Friedrich-Alexander-Universität, Erlangen-Nürnberg</md:name>
<md:ROR>https://ror.org/00f7hpc57</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author111464">
<md:lastName>Barth</md:lastName>
<md:firstName>Johannes Arthur</md:firstName>
<md:eMail>johannes.barth@fau.de</md:eMail>
<md:affiliation id="dataset.author111464.inst12761">
<md:name>Friedrich-Alexander-Universität, Erlangen-Nürnberg</md:name>
<md:ROR>https://ror.org/00f7hpc57</md:ROR>
</md:affiliation>
</md:author>
<md:year>2026</md:year>
<md:title>Seasonal Dataset of DIC, δ13CDIC, DOC, δ13CDOC, pCO2(aq), FCO2 and Biogeochemical Parameters in the Danube River (2023–2024)</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.pangaea.de/10.1594/PANGAEA.993653</md:URI>
<md:dateTime>2026-04-27T06:34:19</md:dateTime>
</md:citation>
<md:abstract>This dataset contains dissolved inorganic/organic carbon (DIC/DOC) concentrations, its stable  isotope ratios (δ13CDIC/DOC), partial pressure of carbon dioxide in the water column  pCO₂(aq) (pCO2(aq)) and area-integrated CO₂ emission rates derived from flux calculations (FCO2; g C d⁻¹), along with corresponding parameters (temperature, pH, calcium, bicarbonate) collected from the Danube River and its key tributaries during five seasonal sampling campaigns in 2023 and 2024. Water samples were collected using a weighted 2 L sampling bottle submerged 1–2 meters below the surface, with sampling conducted from the river center via bridges or passenger boats, and occasionally from the riverbank. In situ temperature measurements were taken with a multiparameter instrument (HQ40d, HACH™, Loveland, CO, USA). δ13ODIC/DOC was analyzed using a OI Analytical Aurora 1030W-IRMS. This dataset is providing valuable insights into carbon dynamics in a large river system and support investigations of biogeochemical cycling.  It further can inform ecosystem management and conservation strategies under changing environmental conditions.</md:abstract>
<md:reference dataciteRelType="IsSupplementTo" group="200" id="ref139384" relationType="Supplement to" relationTypeId="5">
<md:author id="ref139384.author82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:author>
<md:author id="ref139384.author111464">
<md:lastName>Barth</md:lastName>
<md:firstName>Johannes Arthur</md:firstName>
<md:eMail>johannes.barth@fau.de</md:eMail>
</md:author>
<md:prepubStatus>in review</md:prepubStatus>
<md:title>Geological, land use and biological influences on carbon cycling and CO2 degassing in the Danube River</md:title>
<md:type id="ref139384.reftype1">journal article</md:type>
<md:source id="ref139384.journal16727" relatedTermIds="34013" type="journal">Scientific Reports</md:source>
</md:reference>
<md:reference dataciteRelType="References" group="210" id="refds983395" relationType="Related to" relationTypeId="12">
<md:author id="refds983395.author82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:author>
<md:author id="refds983395.author111461">
<md:lastName>Visser</md:lastName>
<md:firstName>Anna-Neva</md:firstName>
<md:eMail>anna-neva.visser@fau.de</md:eMail>
</md:author>
<md:author id="refds983395.author111462">
<md:lastName>Schubert</md:lastName>
<md:firstName>Christina Martina</md:firstName>
<md:eMail>christina.cs.schubert@fau.de</md:eMail>
</md:author>
<md:author id="refds983395.author111463">
<md:lastName>Wander</md:lastName>
<md:firstName>Simon Thomas</md:firstName>
<md:eMail>simon.wander@fau.de</md:eMail>
</md:author>
<md:author id="refds983395.author111464">
<md:lastName>Barth</md:lastName>
<md:firstName>Johannes Arthur</md:firstName>
<md:eMail>johannes.barth@fau.de</md:eMail>
</md:author>
<md:year>2025</md:year>
<md:title>Seasonal Dataset of DO, δ¹⁸ODO and Biogeochemical Parameters in the Danube River (2023–2024)</md:title>
<md:type id="refds983395.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.org/10.1594/PANGAEA.983395</md:URI>
</md:reference>
<md:extent>
<md:geographic>
<md:westBoundLongitude>8.154897</md:westBoundLongitude>
<md:eastBoundLongitude>29.344149</md:eastBoundLongitude>
<md:southBoundLatitude>43.621077</md:southBoundLatitude>
<md:northBoundLatitude>49.025942</md:northBoundLatitude>
<md:meanLongitude>18.675788290858723</md:meanLongitude>
<md:meanLatitude>46.49611125678669</md:meanLatitude>
</md:geographic>
<md:temporal>
<md:minDateTime>2023-07-07T00:00:00</md:minDateTime>
<md:maxDateTime>2024-09-04T00:00:00</md:maxDateTime>
</md:temporal>
<md:elevation name="Elevation" unit="m">
<md:min>-1.0</md:min>
<md:max>-1.0</md:max>
</md:elevation>
<md:topoType id="topotype11">uncoded table</md:topoType>
</md:extent>
<md:award id="award4063">
<md:funder id="award4063.funder21271" semanticURI="doi:10.13039/100018693">
<md:name>Horizon Europe</md:name>
<md:optionalName>HorizonEU</md:optionalName>
<md:URI>https://research-and-innovation.ec.europa.eu/funding/funding-opportunities/funding-programmes-and-open-calls/horizon-europe_en</md:URI>
<md:crossrefFunderId>https://doi.org/10.13039/100018693</md:crossrefFunderId>
</md:funder>
<md:number>101094070</md:number>
<md:title>DALIA - Danube Region Water Lighthouse Action</md:title>
<md:URI>doi:10.3030/101094070</md:URI>
</md:award>
<md:event id="event3268066">
<md:label>DALIA</md:label>
<md:latitude>48.095297</md:latitude>
<md:longitude>8.154897</md:longitude>
<md:elevation>-1.0</md:elevation>
<md:latitude2>45.172488</md:latitude2>
<md:longitude2>29.344149</md:longitude2>
<md:elevation2>-1.0</md:elevation2>
<md:method id="event3268066.method17212">
<md:name>Water sampler</md:name>
</md:method>
</md:event>
<md:size unit="data points">5554</md:size>
<md:license id="license21" preliminary="true">
<md:label>CC-BY-4.0</md:label>
<md:name>Creative Commons Attribution 4.0 International</md:name>
<md:URI>https://creativecommons.org/licenses/by/4.0/</md:URI>
</md:license>
<md:matrixColumn col="0" id="col0.ds15910589" source="data" type="string">
<md:parameter id="col0.ds15910589.param54969">
<md:name>Season</md:name>
<md:shortName>Season</md:shortName>
</md:parameter>
<md:PI id="col0.ds15910589.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:comment>of sampling</md:comment>
<md:caption>Season</md:caption>
</md:matrixColumn>
<md:matrixColumn col="1" id="col1.ds15910590" source="data" type="string">
<md:parameter id="col1.ds15910590.param16065">
<md:name>Sample ID</md:name>
<md:shortName>Sample ID</md:shortName>
</md:parameter>
<md:PI id="col1.ds15910590.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:caption>Sample ID</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="4" col="2" format="yyyy-MM-dd'T'HH:mm:ss" id="col2.ds15910591" source="geocode" type="datetime">
<md:parameter id="col2.ds15910591.geocode1599">
<md:name>DATE/TIME</md:name>
<md:shortName>Date/Time</md:shortName>
<md:URI>http://en.wikipedia.org/wiki/ISO_8601</md:URI>
<md:term endOffset="9" fragment="2" id="col2.ds15910591.geocode1599.term43975" semanticURI="http://qudt.org/1.1/vocab/quantity#Time" startOffset="5" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Time</md:name>
<md:optionalName>T</md:optionalName>
<md:URI>http://dbpedia.org/resource/Time</md:URI>
</md:term>
</md:parameter>
<md:PI id="col2.ds15910591.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:caption>Date/Time</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="2" col="3" format="#0.000000" id="col3.ds15910592" source="geocode" type="numeric">
<md:parameter id="col3.ds15910592.geocode1600">
<md:name>LATITUDE</md:name>
<md:shortName>Latitude</md:shortName>
<md:URI>http://en.wikipedia.org/wiki/ISO_6709</md:URI>
</md:parameter>
<md:PI id="col3.ds15910592.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:caption>Latitude</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="3" col="4" format="#0.000000" id="col4.ds15910593" source="geocode" type="numeric">
<md:parameter id="col4.ds15910593.geocode1601">
<md:name>LONGITUDE</md:name>
<md:shortName>Longitude</md:shortName>
<md:URI>http://en.wikipedia.org/wiki/ISO_6709</md:URI>
</md:parameter>
<md:PI id="col4.ds15910593.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:caption>Longitude</md:caption>
</md:matrixColumn>
<md:matrixColumn col="5" id="col5.ds15910594" source="data" type="string">
<md:parameter id="col5.ds15910594.param88084">
<md:name>River</md:name>
<md:shortName>River</md:shortName>
<md:term endOffset="5" fragment="1" id="col5.ds15910594.param88084.term1073970" semanticURI="http://purl.obolibrary.org/obo/ENVO_00000022" startOffset="0" terminologyId="15" terminologyLabel="ENVO">
<md:name>river</md:name>
<md:URI>http://purl.obolibrary.org/obo/ENVO_00000022</md:URI>
</md:term>
</md:parameter>
<md:PI id="col5.ds15910594.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:caption>River</md:caption>
</md:matrixColumn>
<md:matrixColumn col="6" format="###0" id="col6.ds15910595" source="data" type="numeric">
<md:parameter id="col6.ds15910595.param510226">
<md:name>River kilometer</md:name>
<md:shortName>River km</md:shortName>
<md:unit>km</md:unit>
<md:term id="col6.ds15910595.param510226.term43863" semanticURI="http://qudt.org/1.1/vocab/quantity#Length" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Length</md:name>
<md:optionalName>L</md:optionalName>
<md:URI>http://dbpedia.org/resource/Length</md:URI>
</md:term>
</md:parameter>
<md:PI id="col6.ds15910595.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:comment>upstream</md:comment>
<md:caption>River km [km]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="7" format="#0.0" id="col7.ds15910596" source="data" type="numeric">
<md:parameter id="col7.ds15910596.param717">
<md:name>Temperature, water</md:name>
<md:shortName>Temp</md:shortName>
<md:unit>°C</md:unit>
<md:term endOffset="11" fragment="1" id="col7.ds15910596.param717.term43972" semanticURI="http://qudt.org/1.1/vocab/quantity#ThermodynamicTemperature" startOffset="0" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Temperature</md:name>
<md:optionalName>Θ</md:optionalName>
<md:URI>http://dbpedia.org/resource/Temperature</md:URI>
</md:term>
<md:term endOffset="18" fragment="2" id="col7.ds15910596.param717.term2606205" semanticURI="http://purl.obolibrary.org/obo/CHEBI_15377" startOffset="13" terminologyId="16" terminologyLabel="ChEBI">
<md:name>water</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_15377</md:URI>
</md:term>
</md:parameter>
<md:method id="col7.ds15910596.method13926">
<md:name>Portable 2-channel multimeter, Hach, HQ40D</md:name>
<md:term id="col7.ds15910596.method13926.term2664259" semanticURI="SDN:L22::TOOL1481" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>Hach HQ40D - Multi 2 Channels Portable Two Channel Multi Meter</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L22/current/TOOL1481/</md:URI>
</md:term>
</md:method>
<md:PI id="col7.ds15910596.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:caption>Temp [°C]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="8" format="#0.00" id="col8.ds15910597" source="data" type="numeric">
<md:parameter id="col8.ds15910597.param764">
<md:name>pH</md:name>
<md:shortName>pH</md:shortName>
</md:parameter>
<md:method id="col8.ds15910597.method13926">
<md:name>Portable 2-channel multimeter, Hach, HQ40D</md:name>
<md:term id="col8.ds15910597.method13926.term2664259" semanticURI="SDN:L22::TOOL1481" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>Hach HQ40D - Multi 2 Channels Portable Two Channel Multi Meter</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L22/current/TOOL1481/</md:URI>
</md:term>
</md:method>
<md:PI id="col8.ds15910597.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:caption>pH</md:caption>
</md:matrixColumn>
<md:matrixColumn col="9" format="#0.000" id="col9.ds15910598" source="data" type="numeric">
<md:parameter id="col9.ds15910598.param106858">
<md:name>Carbon, inorganic, dissolved</md:name>
<md:shortName>DIC</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col9.ds15910598.param106858.term38477" semanticURI="http://purl.obolibrary.org/obo/CHEBI_27594" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>carbon</md:name>
<md:optionalName>C</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:27594</md:URI>
</md:term>
<md:term endOffset="28" fragment="2" id="col9.ds15910598.param106858.term1073493" semanticURI="urn:obo:pato:term:0001986" startOffset="19" terminologyId="14" terminologyLabel="PATO">
<md:name>dissolved</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0001986</md:URI>
</md:term>
<md:term id="col9.ds15910598.param106858.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col9.ds15910598.method17189">
<md:name>TIC–TOC analyzer, OI Analytical, Aurora 1030W</md:name>
</md:method>
<md:PI id="col9.ds15910598.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:caption>DIC [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="10" format="#0.00" id="col10.ds15910599" source="data" type="numeric">
<md:parameter id="col10.ds15910599.param770">
<md:name>δ13C, dissolved inorganic carbon</md:name>
<md:shortName>δ13C DIC</md:shortName>
<md:unit>‰ PDB</md:unit>
<md:term endOffset="4" fragment="1" id="col10.ds15910599.param770.term1073089" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>δ13C</md:name>
<md:URI>http://en.wikipedia.org/wiki/List_of_elements_by_stability_of_isotopes</md:URI>
</md:term>
<md:term endOffset="32" fragment="2" id="col10.ds15910599.param770.term40625" startOffset="6" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>dissolved inorganic carbon</md:name>
<md:optionalName>DIC</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col10.ds15910599.method17189">
<md:name>TIC–TOC analyzer, OI Analytical, Aurora 1030W</md:name>
</md:method>
<md:PI id="col10.ds15910599.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:comment>vs. VPDB</md:comment>
<md:caption>δ13C DIC [‰ PDB]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="11" format="#0.00" id="col11.ds15910600" source="data" type="numeric">
<md:parameter id="col11.ds15910600.param548539">
<md:name>Carbon, organic, dissolved</md:name>
<md:shortName>DOC</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col11.ds15910600.param548539.term38477" semanticURI="http://purl.obolibrary.org/obo/CHEBI_27594" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>carbon</md:name>
<md:optionalName>C</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:27594</md:URI>
</md:term>
<md:term endOffset="15" fragment="2" id="col11.ds15910600.param548539.term44419" startOffset="8" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>organic</md:name>
</md:term>
<md:term endOffset="26" fragment="3" id="col11.ds15910600.param548539.term1073493" semanticURI="urn:obo:pato:term:0001986" startOffset="17" terminologyId="14" terminologyLabel="PATO">
<md:name>dissolved</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0001986</md:URI>
</md:term>
<md:term id="col11.ds15910600.param548539.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col11.ds15910600.method17189">
<md:name>TIC–TOC analyzer, OI Analytical, Aurora 1030W</md:name>
</md:method>
<md:PI id="col11.ds15910600.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:caption>DOC [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="12" format="#0.00" id="col12.ds15910601" source="data" type="numeric">
<md:parameter id="col12.ds15910601.param87094">
<md:name>δ13C, dissolved organic carbon</md:name>
<md:shortName>δ13C DOC</md:shortName>
<md:unit>‰ PDB</md:unit>
<md:term endOffset="4" fragment="1" id="col12.ds15910601.param87094.term1073089" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>δ13C</md:name>
<md:URI>http://en.wikipedia.org/wiki/List_of_elements_by_stability_of_isotopes</md:URI>
</md:term>
<md:term endOffset="30" fragment="2" id="col12.ds15910601.param87094.term40999" startOffset="6" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>dissolved organic carbon</md:name>
</md:term>
</md:parameter>
<md:method id="col12.ds15910601.method17189">
<md:name>TIC–TOC analyzer, OI Analytical, Aurora 1030W</md:name>
</md:method>
<md:PI id="col12.ds15910601.pi82895">
<md:lastName>Maier</md:lastName>
<md:firstName>Jan</md:firstName>
<md:eMail>jan.m.maier@fau.de</md:eMail>
<md:orcid>0009-0000-5925-0002</md:orcid>
</md:PI>
<md:comment>vs. VPDB</md:comment>
<md:caption>δ13C DOC [‰ PDB]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="13" format="#0" id="col13.ds15910602" source="data" type="numeric">
<md:parameter id="col13.ds15910602.param763">
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