/* DATA DESCRIPTION: Citation: Paine, Alice R; Frieling, Joost; Wagner, Bernd; Francke, Alexander; Lacey, Jack H; Mather, Tamsin A; Robinson, Stuart A; Pyle, David M (2026): Sedimentary mercury measurements for core ICDP DEEP 5045-1, Lake Ohrid [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.993441 Abstract: The datasets include raw and corrected measurements of mercury in sediment samples from core DEEP 5045-1 extracted from Lake Ohrid in 2013, as part of the ICDP-funded project: Scientific Collaboration on Past Speciation Conditions in Lake Ohrid (SCOPSCO). Lake Ohrid (41° 02′ N, 20° 43′ E) is a tectonic lake situated 693 m above sea level in south-east Europe. The ~447 m-long sedimentary succession extracted from the DEEP (central) site provides a continuous record of hemipelagic sediment accumulation since ~1360 ka, with age control provided by combining tephrochronological data from 16 Ar/Ar dated tephra layers, magnetostratigraphic data, and orbital-tuning of peaks in total organic carbon. Paine et al. (2024) analysed sedimentary Hg concentrations in the top 36 m of the DEEP 5045-1 sediment succession. Here, this dataset is extended to cover the full 447 m succession, with Hg measurements taken for 640 powdered bulk sediment samples between 36 and ~447 m composite depth at a sampling resolution of 64 cm (or an average of ~2000 years). Total Hg concentrations (HgT) were measured using a RA-915+ Portable Mercury Analyzer with PYRO-915+ Pyrolyser, Lumex (Bin et al., 2001) at the University of Oxford. In Lake Ohrid, endogenic calcite (CaCO3{~}) accounts for up to >80% of the total sediment carbonate mass with small contributions from biogenic and detrital terrigenous calcium carbonate. Such a high and variable carbonate content creates a high risk of Hg fluxes to the sediment being diluted, and the variability results in a positive correlation to other diluted phases (TOC, TS, quartz, clay minerals), when this effect is not suitably accounted for. Also included are details for each standard sample analyzed in conjunction with the DEEP 5045-1 samples, in order to calibrate the instrument, and thus calculate integrated Hg concentration values. Keyword(s): Balkan Peninsula; Glacial; Lake; Mercury; Mid Pleistocene Transition; Pleistocene; Sediment; Vegetation Supplement to: Paine, Alice R; Frieling, Joost; Wagner, Bernd; Francke, Alexander; Lacey, Jack H; Mather, Tamsin A; Robinson, Stuart A; Pyle, David M (in press): errestrial regulation of lacustrine Hg deposition during glacial-interglacial cycles. Paleoceanography and Paleoclimatology References: Chen, Bin; Wang, Xiaoru; Lee, Frank S C (2001): Pyrolysis coupled with atomic absorption spectrometry for the determination of mercury in Chinese medicinal materials. Analytica Chimica Acta, 447(1-2), 161-169, https://doi.org/10.1016/S0003-2670(01)01218-1 Francke, Alexander; Wagner, Bernd; Just, Janna; Leicher, Niklas; Gromig, Raphael; Baumgarten, Henrike; Vogel, Hendrik; Lacey, Jack H; Sadori, Laura; Wonik, Thomas; Leng, Melanie J; Zanchetta, Giovanni; Sulpizio, Roberto; Giaccio, Biagio (2016): Sedimentological processes and environmental variability at Lake Ohrid (Macedonia, Albania) between 637 ka and the present. Biogeosciences, 13(4), 1179-1196, https://doi.org/10.5194/bg-13-1179-2016 Lacey, Jack H; Leng, Melanie J; Francke, Alexander; Sloane, Hilary J; Milodowski, Antoni; Vogel, Hendrik; Baumgarten, Henrike; Zanchetta, Giovanni; Wagner, Bernd (2016): Northern Mediterranean climate since the Middle Pleistocene: a 637 ka stable isotope record from Lake Ohrid (Albania/Macedonia). Biogeosciences, 13(6), 1801-1820, https://doi.org/10.5194/bg-13-1801-2016 Paine, Alice R; Fendley, Isabel M; Frieling, Joost; Mather, Tamsin A; Lacey, Jack H; Wagner, Bernd; Robinson, Stuart A; Pyle, David M; Francke, Alexander; Them II, Theodore R; Panagiotopoulos, Konstantinos (2024): Mercury records covering the past 90 000 years from lakes Prespa and Ohrid, SE Europe. Biogeosciences, 21(2), 531-556, https://doi.org/10.5194/bg-21-531-2024 Wagner, Bernd; Vogel, Hendrik; Francke, Alexander; Friedrich, Tobias; Donders, Timme H; Lacey, Jack H; Leng, Melanie J; Regattieri, Eleonora; Sadori, Laura; Wilke, Thomas; Zanchetta, Giovanni; Albrecht, Christian; Bertini, Adele; Combourieu-Nebout, Nathalie; Cvetkoska, Aleksandra; Giaccio, Biagio; Grazhdani, Andon; Hauffe, Torsten; Holtvoeth, Jens; Joannin, Sébastien; Jovanovska, Elena; Just, Janna; Kouli, Katerina; Kousis, Ilias; Koutsodendris, Andreas; Krastel, Sebastian; Lagos, Markus; Leicher, Niklas; Levkov, Zlatko; Lindhorst, Katja; Masi, Alessia; Melles, Martin; Mercuri, Anna Maria; Nomade, Sébastien; Nowaczyk, Norbert R; Panagiotopoulos, Konstantinos; Peyron, Odile; Reed, Jane M; Sagnotti, Leonardo; Sinopoli, Gaia; Stelbrink, Björn; Sulpizio, Roberto; Timmermann, Axel; Tofilovska, Slavica; Torri, Paola; Wagner-Cremer, Friederike; Wonik, Thomas; Zhang, Xiaosen (2019): Mediterranean winter rainfall in phase with African monsoons during the past 1.36 million years. Nature, https://doi.org/10.1038/s41586-019-1529-0 Additional metadata: Lumex standards analyzed in conjunction with the DEEP 5045-1 samples (URI: https://download.pangaea.de/reference/139082/attachments/DEEP5045-1_Lumex_Standard.xlsx) Funding: European Commission (EC) (URI: https://commission.europa.eu/index_en), grant/award no. 818717: Revealing hidden volcanic triggers for global environmental change events in Earth's geological past using mercury (Hg) (URI: https://doi.org/10.3030/818717) Coverage: LATITUDE: 41.049170 * LONGITUDE: 20.715000 MINIMUM DEPTH, sediment/rock: 1.29 m * MAXIMUM DEPTH, sediment/rock: 446.96 m Event(s): ICDP5045-1 (DEEP) * LATITUDE: 41.049170 * LONGITUDE: 20.715000 * ELEVATION: 693.0 m * LOCATION: Lake Ohrid, Macedonian/Albanian border * METHOD/DEVICE: Deep Lake Drilling System (DLDS) (URI: http://www.icdp-online.org/support/equipment/deep-lake-drilling-system/) Comment: Age (ka): Age ascribed to each sample, given in kiloyears before present (ka). Ages follow the chronology published in Wagner et al. (2019): which combines tephrochronological data from 16 39Ar/40Ar dated tephra layers, magnetostratigraphic data, and orbital-tuning of peaks in total organic carbon. The final age model was calculated using Bacon 2.2, considering broadly uniform sedimentation rates at the DEEP core site. The average errors for specific depths averaged ±5.5 kyr (95% confidence), with a maximum uncertainty of ±10.7 kyr. The resulting chronology suggests that the upper 447.12 m of the DEEP site record continuously covers the past 1.35 million years. (Wagner et al., 2019) HgT: Total Hg in the bulk sediments of DEEP 5045-1. Measured using the RA-915 Portable Mercury Analyzer with PYRO-915 Pyrolyzer, Lumex at the University of Oxford. (Paine et al., 2026; Paine et al., 2024; Bin et al.,2001) HgAR: Total sedimentary Hg accumulation relative to background, given in ng cm−2 yr−1. This calculation uses values of dry bulk density (DBD), which were calculated immediately after sampling from volumetrically sampled aliquots at the University of Cologne by Francke et al. (2016), and values for sedimentation rate (SR) given by Wagner et al. (2019). Values for HgAR are calculated with respect to the median age estimate for each sample. (Paine et al., 2026; Paine et al., 2024); Wagner et al., 2019; Francke et al., 2016). HgT-CFB: The carbonate-free concentration/abundance of Hg in the samples of DEEP 5045-1, calculated by (and presented in) Paine et al. (2026). This calculation uses values for CaCO3 (see below) calculated from total inorganic carbon (TIC) values published in Wagner et al. (2019). (Paine et al., 2026; Wagner et al., 2019; Lacey et al., 2016). Carbonate: The concentration of carbonate carbonate (CaCO3) measured in each DEEP 5045-1 sample given as a weight percentage (%), and calculated from total inorganic carbon (TIC) values published in Wagner et al. (2019), using a mass ratio of 8.33. Inorganic carbon compounds in the Lake Ohrid sediment archive are dominated by calcite with minor amounts of siderite (FeCO3) present during periods of overall low TIC. Hence, here it is assumed that all TIC is in CaCO3 in DEEP 5045-1. (Wagner et al., 2019). Parameter(s): Number (No) * PI: Paine, Alice R (https://orcid.org/0000-0003-4404-3021, alice.paine@unibas.ch) DEPTH, sediment/rock [m] (Depth sed) * GEOCODE * PI: Paine, Alice R (https://orcid.org/0000-0003-4404-3021, alice.paine@unibas.ch) AGE [ka BP] (Age) * GEOCODE * PI: Paine, Alice R (https://orcid.org/0000-0003-4404-3021, alice.paine@unibas.ch) Mercury, total [ng/g] (HgT) * PI: Paine, Alice R (https://orcid.org/0000-0003-4404-3021, alice.paine@unibas.ch) * METHOD/DEVICE: Mercury analyzer, Lumex LTD, RA-915+ Accumulation rate, mercury [mg/m**2/ka] (Hg AR) * PI: Paine, Alice R (https://orcid.org/0000-0003-4404-3021, alice.paine@unibas.ch) * METHOD/DEVICE: Calculated Calcium carbonate [%] (CaCO3) * PI: Paine, Alice R (https://orcid.org/0000-0003-4404-3021, alice.paine@unibas.ch) Mercury, total, carbonate free fraction [ng/g] (HgT-CFB) * PI: Paine, Alice R (https://orcid.org/0000-0003-4404-3021, alice.paine@unibas.ch) * METHOD/DEVICE: Calculated License: Creative Commons Attribution 4.0 International (CC-BY-4.0) (URI: https://creativecommons.org/licenses/by/4.0/) Status: Curation Level: Enhanced curation (URI: https://wiki.pangaea.de/wiki/Curation_levels) Size: 3469 data points */ No Depth sed [m] Age [ka BP] HgT [ng/g] Hg AR [mg/m**2/ka] CaCO3 [%] HgT-CFB [ng/g] 3 1.29 2.099 43 47.91 83 7 1.93 5.058 11 1.13 59.16 27 11 2.57 8.040 36 3.78 12.92 41 15 3.21 9.545 29 5.47 1.08 29 19 3.81 10.900 33 7.89 11.58 37 23 4.47 13.052 23 3.41 0.50 23 27 5.11 15.242 29 3.87 0.33 29 31 5.75 16.230 27 10.97 0.42 27 35 6.39 17.031 33 18.41 0.83 33 39 7.03 18.064 51 21.49 1.33 52 43 7.67 19.129 32 14.58 0.92 32 47 8.29 20.777 35 8.79 0.67 35 51 8.91 22.589 38 9.42 0.50 38 55 9.55 24.330 50 14.66 1.00 51 59 10.19 26.032 55 14.02 1.42 56 63 10.83 27.542 30 9.10 0.42 30 67 11.47 28.955 46 15.88 1.08 46 71 12.11 30.051 46 19.32 1.42 47 75 12.75 30.955 25 12.49 0.42 25 79 13.39 32.248 30 12.27 1.00 30 83 14.03 33.768 59 15.42 1.08 60 87 14.67 35.508 26 5.90 0.75 26 91 15.31 37.420 38 8.35 0.50 38 95 15.95 38.788 30 8.88 1.58 30 99 16.59 39.719 50 24.62 1.58 51 103 17.39 40.877 55 27.05 0.58 55 107 18.03 42.195 49 13.87 0.42 49 111 18.67 43.655 55 15.47 0.50 55 115 19.31 45.241 46 11.74 0.58 46 119 19.95 46.840 40 12.87 1.08 40 123 20.59 48.439 37 7.93 0.33 37 127 21.23 50.253 53 12.68 0.83 53 131 21.87 52.352 42 7.26 1.42 43 135 22.51 54.325 42 7.98 0.67 42 139 23.15 56.161 36 10.60 15.50 43 143 23.79 58.096 50 11.11 2.33 51 147 24.43 60.161 46 9.89 0.67 46 151 25.07 62.035 51 12.74 6.08 54 155 25.71 63.538 41 12.80 0.92 41 159 26.35 65.122 58 19.61 1.75 59 163 26.99 66.885 62 19.72 0.83 63 167 27.63 68.617 57 17.77 1.08 58 171 28.27 70.332 66 19.45 4.17 69 175 28.91 72.041 68 17.22 0.33 68 179 29.55 73.732 57 13.38 1.58 58 183 30.19 75.404 39 11.94 5.42 41 187 30.83 76.996 37 8.82 0.67 37 191 31.47 78.529 61 16.31 0.67 61 195 32.11 79.873 27 10.38 9.58 30 199 32.75 81.216 28 11.21 27.92 39 203 33.39 82.583 21 7.38 35.92 33 207 34.03 83.978 23 8.49 45.50 42 211 34.67 85.576 39 13.02 11.17 44 215 35.31 87.190 34 9.94 18.33 42 219 35.95 88.842 42 12.83 1.67 43 223 36.59 90.520 28 6.66 15.92 33 227 37.23 92.606 34 7.12 7.50 37 231 37.87 94.686 32 6.67 7.92 35 235 38.51 96.361 33 7.74 9.75 37 239 39.15 98.038 24 6.38 21.25 30 243 39.79 99.792 13 3.20 35.42 20 247 40.43 101.555 15 3.11 15.25 18 251 41.07 102.979 11 3.91 34.08 17 255 41.71 104.390 28 9.97 11.67 32 259 42.35 105.826 27 8.79 31.92 40 263 42.99 107.281 52 16.32 13.83 60 267 43.63 109.326 39 8.10 16.58 47 271 44.27 111.418 40 8.53 23.17 52 275 44.91 113.842 43 7.43 20.67 54 279 45.55 116.300 47 8.34 19.58 58 283 46.19 118.957 24 3.55 22.50 31 287 46.83 121.639 23 3.96 33.83 35 291 47.47 124.230 15 2.90 58.16 36 295 48.11 126.859 13 2.70 69.25 42 299 48.75 129.188 21 4.22 22.25 27 303 49.39 131.443 53 11.41 10.75 59 307 50.03 133.465 38 9.69 1.33 39 311 50.67 135.379 38 10.21 5.75 40 315 51.32 137.203 60 11.17 1.50 61 319 51.95 138.918 33 8.86 4.50 35 323 52.59 140.600 48 13.16 2.50 49 327 53.23 142.297 62 20.18 0.75 62 331 53.87 143.947 43 13.37 0.58 43 335 54.51 145.622 69 19.67 1.00 70 339 55.15 147.244 55 16.75 1.25 56 343 55.79 148.860 47 13.82 1.08 48 347 56.43 150.291 49 16.54 0.42 49 351 57.07 151.613 29 10.93 4.33 30 355 57.71 152.979 40 15.01 1.67 41 359 58.35 154.412 42 14.16 1.00 42 363 58.99 155.510 45 22.08 1.17 46 367 59.63 156.308 47 29.85 0.83 47 371 60.27 157.054 48 34.93 2.50 49 375 60.91 157.767 55 40.26 2.50 56 379 61.55 158.507 38 29.65 0.75 38 383 62.19 159.267 32 22.45 0.42 32 387 62.83 160.075 57 40.73 1.00 58 391 63.47 160.951 50 28.37 1.25 51 395 64.11 161.815 53 33.24 1.08 54 399 64.75 162.704 52 29.89 0.42 52 403 65.39 163.626 65 34.10 4.33 68 407 66.03 164.626 72 32.64 1.67 73 411 66.67 165.633 54 24.20 1.00 55 415 67.31 166.632 31 14.41 1.17 31 419 67.95 167.586 52 30.38 10.75 58 423 68.59 168.526 48 28.25 2.50 49 427 69.23 169.467 70 36.23 2.08 71 431 69.87 170.375 56 28.71 0.33 56 435 70.51 171.271 53 30.01 5.33 56 439 71.15 172.160 68 35.69 3.50 70 443 71.79 173.067 50 24.69 0.33 50 447 72.43 174.045 37 16.49 1.92 38 451 73.07 175.012 45 23.10 1.50 46 455 73.71 175.916 47 26.05 1.92 48 459 74.35 176.819 68 39.96 2.58 70 463 74.99 177.630 47 25.12 0.50 47 467 75.63 178.446 64 41.66 1.42 65 471 76.27 179.297 41 22.97 1.75 42 475 76.91 180.161 43 22.52 0.75 43 479 77.55 181.125 32 17.79 0.42 32 483 78.19 182.086 49 26.53 0.92 49 487 78.83 183.167 53 27.73 4.67 56 491 79.47 184.211 52 28.15 0.33 52 495 80.11 185.097 51 35.44 1.33 52 499 80.75 185.978 54 33.76 1.08 55 503 81.39 187.046 44 22.83 9.17 48 507 82.03 188.119 52 26.30 2.17 53 511 82.67 189.107 42 22.66 0.75 42 515 83.31 190.085 50 26.59 1.42 51 519 83.95 191.035 58 32.39 1.08 59 523 84.59 191.996 46 26.33 10.50 51 527 85.23 192.943 59 32.29 1.92 60 531 85.87 193.904 55 29.13 1.67 56 535 86.51 194.965 41 18.71 15.83 49 539 87.15 196.047 57 27.74 2.00 58 543 87.79 197.288 31 13.67 16.00 37 547 88.43 198.552 55 21.48 10.08 61 551 89.07 199.695 48 24.70 14.08 56 555 89.71 200.808 29 13.85 57.08 68 559 90.35 201.889 46 22.03 51.00 94 563 90.99 202.971 46 25.24 25.33 62 567 91.63 204.115 51 24.97 17.17 62 571 92.27 205.293 49 24.36 9.58 54 575 92.91 207.223 42 11.27 19.92 52 579 93.55 209.437 64 14.71 19.17 79 583 94.19 211.367 31 9.80 43.25 55 587 94.83 213.152 24 6.53 50.00 48 591 95.47 215.262 35 8.17 52.91 74 595 96.11 217.532 46 10.77 38.83 75 599 96.75 219.968 45 10.61 0.58 45 603 97.39 222.565 54 11.40 0.83 54 611 98.67 226.272 68 24.87 8.58 74 615 99.31 228.027 58 19.71 3.08 60 619 99.95 229.046 60 36.19 1.58 61 623 100.59 230.398 48 15.05 2.25 49 627 101.23 231.785 71 31.41 5.33 75 631 101.87 233.151 66 23.66 0.50 66 635 102.51 234.545 51 18.15 0.67 51 639 103.15 235.881 35 13.94 5.75 37 643 103.79 237.163 41 16.38 24.42 54 647 104.43 238.531 26 8.45 37.75 42 651 105.07 239.986 35 11.98 46.33 65 655 105.71 241.322 31 11.49 26.75 42 659 106.35 242.509 79 42.62 1.17 80 663 106.99 243.729 48 23.82 0.67 48 667 107.63 245.028 59 28.00 3.58 61 671 108.27 246.320 26 9.77 0.67 26 675 108.91 247.554 56 27.05 0.92 57 679 109.55 248.904 54 26.36 1.67 55 683 110.19 250.438 53 16.41 5.25 56 687 110.83 251.993 49 17.82 1.50 50 691 111.47 253.658 46 16.19 2.50 47 695 112.11 255.365 29 9.96 1.58 29 699 112.75 257.224 40 12.20 0.83 40 703 113.39 259.091 28 8.77 0.33 28 707 114.03 261.061 35 9.62 0.50 35 715 114.03 261.061 29 8.86 0.50 29 719 115.31 264.584 33 11.58 0.83 33 723 115.95 266.221 34 0.92 34 727 116.59 267.819 39 1.42 40 731 117.23 269.423 41 16.78 1.33 42 735 117.87 271.103 53 19.34 2.50 54 739 118.51 272.785 52 22.65 1.33 53 743 119.15 274.320 58 24.57 1.08 59 747 119.79 275.828 55 22.66 0.00 55 751 120.43 277.213 50 24.00 0.83 50 755 121.07 278.580 44 18.84 11.42 50 759 121.71 280.010 46 19.63 0.58 46 763 122.35 281.431 38 16.22 1.58 39 767 122.99 282.779 37 12.29 10.17 41 771 123.63 284.145 34 9.24 2.33 35 775 124.27 285.853 34 9.51 8.92 37 779 124.91 287.580 26 7.99 30.42 37 783 125.55 289.285 17 5.06 40.83 29 787 126.19 290.966 20 6.53 32.25 30 791 126.83 292.474 30 12.24 20.00 38 795 127.47 293.993 38 16.83 6.50 41 799 128.11 295.490 43 19.34 7.83 47 803 128.75 297.005 39 19.07 3.42 40 807 129.39 298.269 36 17.97 1.42 37 811 130.03 299.468 41 23.17 6.92 44 815 130.67 300.618 40 20.26 7.33 43 819 131.31 301.776 50 21.89 1.92 51 823 131.95 302.966 40 16.35 2.42 41 827 132.59 304.154 37 16.42 11.00 42 831 133.23 305.450 41 15.83 4.42 43 835 133.87 306.771 34 12.51 8.42 37 839 134.51 308.094 37 16.33 17.50 45 843 135.15 309.412 32 13.95 22.83 41 847 135.79 310.622 32 16.22 22.33 41 851 136.43 311.775 32 14.22 27.08 44 855 137.07 312.958 20 8.34 36.50 32 859 137.71 314.163 20 8.78 38.58 33 863 138.35 315.372 23 11.64 40.17 38 867 138.99 316.611 17 7.54 44.41 31 871 139.63 317.989 23 9.73 41.50 39 875 140.27 319.486 38 13.58 44 879 140.91 321.012 32 9.45 13.50 37 883 141.55 322.575 26 7.74 21.25 33 887 142.19 324.290 23 6.60 34.58 35 891 142.83 326.118 15 4.10 53.16 32 895 143.47 327.986 13 3.70 51.25 27 899 144.11 329.939 15 4.25 49.08 29 903 144.75 331.887 22 6.56 47.91 42 907 145.39 333.812 31 8.46 12.00 35 911 146.03 335.777 31 9.40 7.58 34 915 146.67 337.806 37 12.63 6.75 40 919 147.31 339.896 43 14.51 3.08 44 923 147.95 342.090 41 14.60 2.83 42 927 148.59 344.241 41 14.56 2.17 42 931 149.23 346.349 44 14.90 3.25 45 935 150.51 350.391 63 20.93 2.25 64 939 151.15 352.404 47 16.84 1.00 47 943 151.79 354.483 34 9.38 0.67 34 947 152.43 356.578 40 12.67 0.33 40 951 153.07 358.754 39 12.60 6.00 41 955 153.71 360.942 43 14.49 1.50 44 959 154.35 363.062 47 16.49 1.83 48 963 154.99 365.066 48 16.99 2.42 49 967 155.63 366.658 42 16.07 0.83 42 971 156.27 368.353 38 14.68 2.50 39 975 156.91 370.444 45 13.77 1.00 45 979 157.55 372.636 49 14.30 0.42 49 983 158.19 375.295 32 8.14 15.42 38 987 158.83 378.067 27 5.65 7.33 29 991 159.47 381.503 24 4.54 15.75 28 995 160.11 384.866 32 5.50 10.67 36 999 160.75 387.841 27 5.89 25.58 36 1003 161.39 390.811 26 4.88 24.75 35 1007 162.03 392.998 36 10.62 3.83 37 1011 162.67 395.133 32 8.44 8.08 35 1015 163.31 396.434 24 11.56 35.67 37 1019 163.95 397.706 22 6.40 1.67 22 1023 164.59 399.215 17 6.70 47.00 32 1027 165.23 400.732 33 13.14 6.08 35 1031 165.87 402.368 21 8.10 43.00 37 1035 166.51 403.998 18 6.73 38.08 29 1039 167.15 406.107 34 9.83 6.75 36 1043 167.79 408.260 18 5.02 27.67 25 1047 168.43 409.791 26 10.34 29.75 37 1051 169.07 411.300 11 4.94 54.08 24 1055 169.71 413.187 9 3.07 58.08 21 1059 170.35 415.133 6 2.28 68.33 20 1063 170.99 416.749 8 3.24 56.58 18 1067 171.63 418.300 9 3.53 67.00 27 1071 172.27 420.213 8 2.38 65.50 22 1075 172.91 422.207 19 4.79 51.75 39 1079 173.55 423.953 16 4.68 43.83 28 1083 174.19 425.644 18 5.94 27.42 25 1087 174.83 427.532 30 10.57 1.75 31 1091 175.47 429.495 30 10.13 4.08 31 1095 176.11 431.322 39 15.82 1.25 39 1099 176.75 433.137 47 18.06 0.33 47 1103 177.39 436.128 46 10.27 1.33 47 1107 178.03 439.651 46 8.04 0.67 46 1111 178.67 442.730 43 9.80 1.08 43 1115 179.31 445.595 34 7.59 0.50 34 1119 179.95 448.202 34 8.54 0.75 34 1123 180.59 450.674 41 9.71 1.00 41 1127 181.21 453.193 38 8.81 2.75 39 1131 181.87 455.997 41 11.44 0.83 41 1135 182.51 458.164 42 12.20 1.08 42 1139 183.15 459.921 30 11.98 10.67 34 1143 183.79 461.623 33 11.36 1.08 33 1147 184.43 463.307 46 17.08 1.92 47 1151 185.07 465.147 31 11.15 3.92 32 1155 185.71 467.164 33 11.78 3.00 34 1159 186.35 468.980 35 14.23 8.08 38 1163 186.99 470.575 43 16.44 8.50 47 1167 187.63 472.053 40 14.75 2.17 41 1171 188.27 473.421 36 15.16 7.67 39 1175 188.91 474.841 22 7.78 31.33 32 1179 189.55 476.330 32 10.43 2.33 33 1183 190.19 477.834 32 10.31 4.25 33 1187 190.83 479.397 18 6.75 34.58 28 1191 191.47 480.845 22 7.81 33.92 33 1195 192.11 482.048 26 13.31 22.42 34 1199 192.75 483.366 16 6.35 43.75 28 1203 193.39 484.896 13 4.61 52.00 27 1207 194.03 486.441 6 2.53 69.41 21 1211 194.67 487.992 8 2.62 62.08 20 1215 195.31 489.573 12 3.69 48.75 23 1219 195.95 491.326 9 3.45 67.41 29 1223 196.59 493.230 20 4.25 42.16 35 1227 197.23 495.765 11 2.10 51.75 23 1231 197.87 498.285 13 2.40 42.66 23 1235 198.51 500.877 7 1.28 68.75 22 1239 199.15 503.678 8 1.53 57.33 19 1243 199.79 507.504 15 1.86 30.75 22 1247 200.43 511.176 27 4.05 20.33 34 1251 201.07 513.682 25 5.84 32.33 37 1255 201.71 516.149 23 4.77 1.50 23 1259 202.35 518.225 40 9.77 6.75 43 1263 202.99 520.283 14 4.17 44.41 25 1267 203.63 522.600 20 4.13 40.58 34 1271 204.27 524.948 6 1.65 66.08 19 1275 204.91 527.320 7 1.83 68.33 21 1279 205.55 529.699 19 5.47 33.42 29 1283 206.19 531.124 7 3.20 59.08 16 1287 206.83 532.570 27 12.75 21.08 34 1291 207.47 533.725 30 19.21 5.25 32 1295 208.11 534.872 26 14.34 7.58 28 1299 208.75 536.074 28 13.85 6.92 30 1303 209.39 537.292 47 22.28 1.33 48 1307 210.03 539.638 23 5.81 21.42 29 1311 210.67 542.062 18 4.21 25.17 24 1315 211.32 544.127 19 4.42 17.50 23 1319 211.95 546.108 16 4.55 26.25 22 1323 212.59 548.243 30 7.27 12.50 34 1327 213.23 550.399 18 5.74 22.75 23 1331 213.87 552.473 20 5.48 18.92 25 1335 214.51 554.566 20 6.05 26.58 27 1339 215.15 556.490 19 5.37 21.17 24 1343 215.79 558.379 25 10.00 28.75 35 1347 216.43 560.167 11 3.53 34.08 17 1351 217.07 561.950 15 5.57 34.75 23 1355 217.71 563.418 21 7.00 19.08 26 1359 218.35 564.775 16 6.55 26.33 22 1363 218.99 566.088 20 9.20 30.75 29 1367 219.63 567.394 32 15.58 15.83 38 1371 220.27 568.743 22 10.12 22.50 28 1375 220.91 570.137 27 11.51 27.33 37 1379 221.55 571.569 23 10.52 27.58 32 1383 222.19 573.054 13 4.29 40.83 22 1387 222.83 574.527 11 4.07 47.25 21 1391 223.47 575.989 9 3.44 51.16 19 1395 224.11 577.431 10 3.58 52.66 21 1399 224.75 578.894 6 2.10 66.66 17 1403 225.39 580.265 10 4.78 39.42 17 1407 226.03 581.573 19 9.69 24.50 25 1411 226.67 582.899 24 13.44 11.83 27 1415 227.31 584.277 22 11.08 16.50 26 1419 227.95 585.819 19 6.92 13.50 22 1423 228.59 587.566 18 5.71 20.50 23 1427 229.23 589.203 10 3.60 34.92 15 1431 229.87 590.748 18 6.92 23.25 23 1435 230.51 592.355 18 7.77 41.58 31 1439 231.15 594.097 15 5.35 30.08 21 1443 231.79 595.922 10 2.84 38.92 16 1447 232.43 597.965 15 4.80 25.92 20 1451 233.07 599.883 11 3.44 42.58 19 1455 233.71 601.572 6 2.41 57.58 15 1459 234.35 603.251 12 4.86 32.83 18 1463 234.99 604.860 8 51.75 16 1467 235.63 606.525 7 2.70 53.08 14 1471 236.27 608.317 9 2.94 54.66 20 1475 236.91 610.002 5 1.79 62.16 13 1479 237.55 611.482 5 1.98 61.33 13 1483 238.19 612.976 6 2.37 54.66 12 1487 238.83 614.468 6 2.52 58.08 13 1491 239.47 615.964 6 2.43 59.25 14 1495 240.11 617.499 3 1.42 68.91 11 1499 240.75 619.036 6 2.45 63.58 15 1503 241.39 620.485 8 3.96 55.66 19 1507 242.03 621.943 23 12.38 33.33 34 1511 242.67 623.510 20 7.62 13.25 23 1515 243.31 625.089 23 10.32 1.33 23 1519 243.95 626.592 21 9.46 1.83 21 1523 244.59 628.144 30 14.45 1.25 30 1527 245.23 629.890 31 13.71 6.00 33 1531 245.87 631.628 27 11.76 6.33 29 1535 246.51 633.725 27 9.53 1.83 28 1539 247.15 635.783 34 10.91 1.33 34 1543 247.79 637.396 20 8.95 6.50 21 1547 248.43 639.012 21 9.39 2.17 21 1551 249.07 641.166 23 6.51 2.50 24 1555 249.71 643.320 25 8.24 1.25 25 1559 250.35 645.347 18 6.42 1.00 18 1563 250.99 647.365 24 9.40 8.42 26 1567 251.63 649.350 24 7.89 1.58 24 1571 252.27 651.332 25 9.02 0.42 25 1575 252.91 652.888 33 17.42 2.75 34 1579 253.55 654.400 39 20.14 2.00 40 1583 254.19 656.666 39 12.56 1.58 40 1587 254.83 659.013 29 8.73 6.50 31 1591 255.47 661.515 37 8.09 7.33 40 1595 256.11 664.037 38 11.14 2.25 39 1599 256.75 666.338 19 5.59 18.58 23 1603 257.39 668.577 17 5.09 31.08 25 1607 258.03 670.763 30 9.23 10.58 34 1611 258.67 672.960 23 6.68 15.25 27 1615 259.31 675.013 35 9.77 2.42 36 1619 259.95 677.036 35 9.70 6.17 37 1623 260.72 681.973 28 4.50 14.00 33 1627 261.36 687.399 20 2.49 31.67 29 1631 262.00 692.012 8 1.12 58.91 19 1635 262.64 696.370 5 0.83 71.08 17 1639 263.28 699.386 10 1.95 57.08 23 1643 263.92 701.859 12 2.73 50.83 24 1647 264.56 704.571 14 3.17 35.33 22 1651 265.20 707.399 9 2.11 58.75 21 1655 265.84 710.312 9 2.03 47.66 18 1659 266.48 713.288 25 5.98 9.25 28 1663 267.12 716.583 23 5.00 2.42 24 1667 267.76 720.112 28 6.25 5.00 29 1671 268.40 722.564 35 11.37 6.00 37 1675 269.04 724.343 44 16.75 3.67 46 1679 269.68 726.386 41 14.18 2.50 42 1683 270.32 728.659 34 8.76 2.58 35 1687 270.96 730.867 31 8.88 1.00 31 1691 271.60 733.100 18 4.81 29.25 25 1695 272.24 735.337 14 3.80 38.33 23 1699 272.88 737.576 21 6.14 26.17 28 1703 273.52 739.510 20 7.15 24.25 26 1707 274.16 741.087 15 7.16 31.33 22 1711 274.80 742.573 17 6.98 26.00 23 1715 275.44 743.978 26 12.55 0.75 26 1719 276.08 745.466 36 17.22 4.50 38 1723 276.72 747.118 37 15.91 3.42 38 1727 277.36 748.791 29 12.84 6.92 31 1731 278.00 750.555 31 12.40 2.67 32 1735 278.64 752.221 41 16.59 2.33 42 1739 279.28 753.737 24 11.41 2.25 25 1743 279.92 755.316 34 15.61 2.92 35 1747 280.56 756.951 35 15.38 1.50 36 1751 281.20 758.610 13 5.32 39.67 22 1755 281.84 760.349 31 12.50 4.50 32 1759 282.48 762.108 32 11.92 3.58 33 1763 283.12 763.928 13 4.80 45.16 24 1767 283.76 765.715 39 13.81 1.67 40 1771 284.40 767.491 18 7.34 38.00 29 1775 285.04 769.287 10 4.08 57.08 23 1779 285.68 771.128 31 10.98 14.25 36 1783 286.32 773.137 14 5.20 44.83 25 1787 286.96 775.781 10 2.84 56.91 23 1791 287.60 778.482 6 1.64 62.50 16 1795 288.23 781.583 4 0.90 73.66 16 1799 288.88 784.726 8 1.84 63.16 22 1803 289.52 787.433 12 3.47 39.75 20 1807 290.16 790.090 22 6.34 5.33 23 1811 290.80 791.863 23 9.93 6.25 25 1815 291.44 793.651 36 12.79 2.25 37 1819 292.08 796.304 45 11.89 1.42 46 1823 292.72 798.945 36 8.96 3.00 37 1827 293.36 801.548 30 7.72 3.58 31 1831 294.00 804.145 34 9.49 0.92 34 1835 294.64 806.922 31 8.49 2.08 32 1839 295.28 809.729 15 3.74 15.92 18 1843 295.92 812.025 20 3.09 12.58 23 1847 296.56 814.289 24 7.03 4.67 25 1851 297.20 816.361 15 4.67 39.58 25 1855 297.84 818.418 9 3.13 58.41 21 1859 298.48 820.279 7 2.69 65.41 19 1863 299.12 822.122 10 3.16 49.50 20 1867 299.76 823.729 17 6.90 28.75 24 1871 300.40 825.272 12 4.71 46.33 22 1875 301.04 827.055 12 3.68 47.25 23 1879 301.68 828.910 31 8.04 0.92 31 1883 302.32 831.629 14 2.95 39.50 23 1887 302.96 834.569 7 1.34 60.25 17 1891 303.60 838.322 9 1.46 59.83 22 1895 304.24 842.303 6 1.13 72.16 21 1899 304.89 846.313 9 1.44 56.25 21 1903 305.52 850.236 19 3.05 19.00 23 1907 306.16 854.301 11 1.77 48.25 21 1911 306.80 858.381 6 1.02 65.16 18 1915 307.44 862.376 8 64.50 24 1919 308.08 866.348 9 1.22 60.08 22 1923 308.72 869.354 21 4.28 12.42 24 1927 309.36 871.761 23 6.86 6.17 25 1931 310.00 873.781 27 9.93 1.17 27 1935 310.64 875.541 26 11.77 5.92 28 1939 311.28 877.509 34 12.27 0.75 34 1943 311.92 879.652 32 10.89 1.00 32 1947 312.56 881.669 38 13.16 8.42 41 1951 313.20 883.609 33 12.57 11.08 37 1955 313.84 885.612 28 11.50 19.83 35 1959 314.48 887.725 38 12.02 5.83 40 1963 315.12 890.312 35 8.28 1.58 36 1967 315.76 893.441 34 7.05 8.67 37 1971 316.40 896.871 29 5.40 7.17 31 1975 317.04 900.699 28 5.29 12.67 32 1979 317.68 904.384 22 4.11 25.92 30 1983 318.32 907.954 16 3.24 40.75 27 1987 318.96 911.942 30 5.10 6.33 32 1991 319.60 916.692 30 4.29 1.83 31 1995 320.24 920.321 51 8.75 1.83 52 1999 320.88 921.865 46 17.68 3.33 48 2003 321.52 923.343 49 19.75 1.50 50 2007 322.16 924.738 53 22.97 0.83 53 2011 322.80 926.201 33 12.37 2.17 34 2015 323.44 927.843 29 9.77 5.58 31 2019 324.08 929.458 32 12.84 10.00 36 2023 324.72 931.041 30 13.14 6.25 32 2027 325.36 932.629 26 9.31 21.50 33 2031 326.00 934.226 36 13.54 4.17 38 2035 326.64 935.848 43 17.30 6.92 46 2039 327.28 937.568 18 6.43 41.58 31 2043 327.92 939.242 10 3.11 51.41 20 2047 328.56 940.804 13 5.51 58.08 31 2051 329.20 942.401 19 7.57 32.58 28 2055 329.84 944.121 14 5.01 45.75 26 2059 330.48 945.839 21 5.93 31.58 31 2063 331.12 947.681 15 4.57 45.83 28 2067 331.76 949.489 9 2.89 68.00 27 2071 332.40 951.187 12 4.04 58.25 29 2075 333.04 952.880 10 2.77 56.83 23 2079 333.68 954.795 9 2.80 71.83 31 2083 334.34 956.755 14 4.63 54.16 31 2087 334.96 958.551 22 7.59 42.91 39 2091 335.60 960.439 26 9.08 31.67 38 2095 336.24 962.065 31 12.71 22.42 40 2099 336.88 963.697 33 13.62 7.58 36 2103 337.52 965.098 51 17.94 2.17 52 2107 338.16 966.459 45 23.70 3.75 47 2111 338.80 967.718 42 20.89 2.17 43 2115 339.44 968.959 39 16.24 7.08 42 2119 340.08 970.227 41 18.06 3.25 42 2123 340.72 971.493 32 15.39 4.42 33 2127 341.36 972.781 39 15.79 5.08 41 2131 342.00 974.094 21 11.14 36.75 33 2135 342.64 975.445 26 10.72 28.08 36 2139 343.28 976.800 33 14.43 19.42 41 2143 343.92 978.021 37 19.65 15.67 44 2147 344.56 979.233 28 14.34 21.67 36 2151 345.20 980.355 24 14.72 37.00 38 2155 345.84 981.459 23 15.75 39.83 38 2159 346.48 982.668 37 16.75 12.00 42 2163 347.12 983.949 37 16.26 2.08 38 2167 347.76 985.691 43 15.88 2.17 44 2171 348.40 987.652 28 7.76 17.42 34 2175 349.04 990.562 25 4.31 21.42 32 2179 349.68 993.923 15 2.89 49.25 30 2183 350.32 997.407 10 1.66 57.25 23 2187 350.96 1001.048 24 3.62 40.08 40 2191 351.60 1004.182 44 7.41 2.17 45 2195 352.24 1007.065 48 8.82 2.33 49 2199 352.88 1009.328 43 8.56 2.25 44 2203 353.52 1011.159 40 14.05 0.92 40 2207 354.16 1012.938 47 13.49 1.08 48 2211 354.80 1014.691 38 12.73 7.92 41 2215 355.44 1016.443 14 3.20 37.83 23 2219 356.08 1018.190 37 10.46 11.42 42 2223 356.72 1019.964 40 11.08 2.42 41 2227 357.36 1021.743 18 4.81 41.17 31 2231 358.00 1023.484 9 2.10 51.58 18 2235 358.64 1025.199 10 2.99 59.16 24 2239 359.28 1026.899 12 3.16 41.00 20 2243 359.92 1028.609 13 3.99 47.50 25 2247 360.56 1030.239 17 4.17 37.92 27 2251 361.20 1031.723 37 12.42 8.92 41 2255 361.84 1033.337 40 13.96 2.25 41 2259 362.48 1035.111 36 9.69 4.67 38 2263 363.12 1037.119 36 12.11 2.83 37 2267 363.76 1039.553 33 7.96 1.58 34 2271 364.40 1041.987 26 7.82 28.25 36 2275 365.04 1044.502 49 8.92 1.08 50 2279 365.68 1047.069 55 12.52 4.75 58 2283 366.32 1049.710 51 10.48 6.17 54 2287 366.96 1052.303 45 11.14 9.17 50 2291 367.60 1054.748 44 8.82 4.25 46 2295 368.24 1057.146 41 9.57 8.83 45 2299 368.88 1059.119 55 14.30 2.58 56 2303 369.52 1061.030 31 10.07 39.42 51 2307 370.16 1062.718 22 7.90 38.42 36 2311 370.80 1064.377 11 3.82 53.25 24 2315 371.44 1066.017 10 3.41 62.50 26 2319 372.08 1067.679 8 2.85 68.41 24 2323 372.72 1069.397 6 2.05 73.00 23 2327 373.36 1071.130 4 1.42 86.50 29 2331 374.00 1073.159 6 1.82 82.41 32 2335 374.64 1075.208 5 1.50 81.66 27 2339 375.28 1077.440 8 1.88 70.50 26 2343 375.92 1079.670 7 1.64 79.25 32 2347 376.56 1081.921 9 2.17 49.91 18 2351 377.20 1084.145 16 4.00 55.83 36 2355 377.84 1086.435 19 4.78 49.75 38 2359 378.48 1088.695 21 5.88 45.25 38 2363 379.12 1091.103 25 6.80 40.17 42 2367 379.76 1093.530 31 9.69 25.67 42 2371 380.40 1095.675 44 15.42 3.42 46 2375 381.04 1097.821 41 15.47 13.83 48 2379 381.68 1099.850 53 21.56 4.33 55 2383 382.32 1101.822 55 20.44 5.17 58 2387 382.96 1103.711 61 17.49 3.17 63 2391 383.60 1105.588 23 4.97 48.91 45 2395 384.24 1107.543 18 5.23 44.16 32 2399 384.90 1109.583 18 5.37 40.25 30 2403 385.52 1111.466 10 2.57 48.91 20 2407 386.16 1113.389 16 5.86 55.33 36 2411 386.80 1115.272 31 8.79 19.00 38 2415 387.44 1117.140 54 17.02 0.67 54 2419 388.08 1119.151 48 12.76 1.25 49 2423 388.72 1121.228 42 12.35 9.75 47 2427 389.36 1123.509 47 12.92 1.75 48 2431 390.00 1125.884 45 14.07 6.00 48 2435 390.64 1128.350 50 12.35 3.33 52 2439 391.28 1130.873 36 12.37 25.42 48 2443 391.92 1133.699 54 13.35 1.00 55 2447 392.56 1136.696 54 13.90 4.92 57 2451 393.20 1139.689 44 9.07 2.83 45 2455 393.84 1142.707 48 8.60 1.42 49 2459 394.48 1145.800 39 7.03 5.25 41 2463 395.12 1148.966 33 6.54 15.08 39 2467 395.76 1151.304 44 13.40 5.58 47 2471 396.40 1152.861 27 12.05 33.33 40 2475 397.04 1154.573 23 7.85 41.42 39 2479 397.68 1156.443 18 5.64 41.42 31 2483 398.32 1158.349 25 7.32 25.75 34 2487 398.96 1160.344 18 5.51 45.91 33 2491 399.60 1162.184 10 3.59 65.91 28 2495 400.24 1163.867 10 3.86 53.66 21 2499 400.88 1165.576 6 2.38 66.91 20 2503 401.52 1167.347 10 3.48 51.00 20 2507 402.16 1169.121 9 3.16 64.33 25 2511 402.80 1170.910 16 5.14 50.50 32 2515 403.44 1173.171 21 4.46 48.50 41 2519 404.08 1176.377 25 4.70 46.33 47 2523 404.72 1179.553 19 3.23 43.58 34 2527 405.36 1182.740 22 3.82 39.33 36 2531 406.00 1186.218 25 4.24 26.67 34 2535 406.64 1190.541 40 6.75 1.75 41 2539 407.28 1194.745 41 6.09 1.58 42 2543 407.92 1198.563 49 6.35 2.08 50 2547 408.56 1202.474 33 4.50 7.67 36 2551 409.20 1206.855 39 5.60 5.75 41 2555 409.84 1210.863 49 7.25 2.92 50 2559 410.48 1213.336 52 14.91 2.33 53 2563 411.12 1215.781 61 15.71 2.08 62 2567 411.76 1218.217 61 12.87 4.50 64 2571 412.40 1220.637 36 10.54 29.75 51 2575 413.04 1223.101 21 6.32 49.25 41 2579 413.68 1225.557 6 1.65 73.83 21 2583 414.32 1227.860 9 2.63 63.50 25 2587 414.96 1230.139 6 1.86 62.66 17 2591 415.60 1231.972 4 1.34 81.25 20 2595 416.24 1233.770 5 1.64 73.91 18 2599 416.88 1235.661 5 1.60 71.08 17 2603 417.52 1237.572 5 1.47 72.83 18 2607 418.16 1239.441 6 1.62 66.16 16 2611 418.80 1241.329 7 1.92 67.16 20 2615 419.44 1243.307 21 5.62 34.92 32 2619 420.08 1245.285 35 12.24 5.50 37 2623 420.72 1247.006 38 15.16 4.67 40 2627 421.36 1248.725 47 19.03 6.08 50 2631 422.00 1251.425 44 12.22 11.67 50 2635 422.64 1254.192 36 9.10 4.42 38 2639 423.28 1257.696 59 13.69 3.25 61 2643 423.92 1261.318 47 11.62 15.92 56 2647 424.56 1264.512 39 10.45 8.75 43 2651 425.20 1267.689 44 11.01 10.00 49 2655 425.84 1274.217 31 3.48 36.25 49 2659 426.48 1281.541 21 2.13 51.58 43 2663 427.12 1286.119 17 2.58 53.41 36 2667 427.76 1290.012 47 7.45 7.00 51 2671 428.40 1292.669 40 11.73 4.33 42 2675 429.04 1294.938 55 19.19 0.67 55 2679 429.68 1297.276 38 12.74 3.50 39 2683 430.32 1299.672 47 18.13 11.42 53 2687 430.96 1302.262 29 6.51 31.17 42 2691 431.60 1304.963 19 4.31 50.66 39 2695 432.24 1307.225 10 3.09 62.25 26 2699 432.88 1309.334 10 3.10 69.58 33 2703 433.52 1311.494 9 2.66 70.83 32 2707 434.16 1313.697 7 2.61 71.16 25 2711 434.80 1315.951 9 2.74 75.33 36 2715 435.44 1318.256 10 2.95 68.83 30 2719 436.08 1320.466 8 2.69 66.91 23 2723 436.72 1322.624 16 4.69 62.50 43 2727 437.36 1327.749 14 2.59 1.42 14 2731 438.05 1336.046 15 1.90 17.58 18 2735 438.64 1340.586 17 2.76 53.50 37 2739 439.28 1343.337 8 1.80 82.25 44 2743 439.92 1345.576 11 2.99 81.83 61 2747 440.56 1347.332 3 0.91 89.83 27 2751 441.20 1349.068 4 1.28 93.58 56 2755 441.84 1350.785 3 1.37 94.50 58 2759 442.48 1352.449 3 1.20 94.91 53 2763 443.12 1354.033 4 1.54 94.08 59 2767 443.76 1355.655 2 0.71 94.83 31 2771 444.40 1357.397 2 0.76 92.25 24 2775 445.04 1359.098 3 1.06 91.91 32 2779 445.68 1360.765 3 1.41 93.91 53 2783 446.32 1362.401 4 1.76 88.91 38 2787 446.96 1363.959 6 2.83 83.50 36