<?xml version="1.0" encoding="UTF-8"?><!--*** Generated from internal PANGAEA metadata schema by dif.xslt ***--><DIF xsi:schemaLocation="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/ http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/dif_v9.4.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/">
<Entry_ID>PANGAEA_993221</Entry_ID>
<Entry_Title>Quaternary trace metals data from ODP Site 198-1208</Entry_Title>
<Data_Set_Citation>
<Dataset_Creator>Novak, Joseph B; Abell, Jordan; Kinsley, Christopher</Dataset_Creator>
<Dataset_Title>Quaternary trace metals data from ODP Site 198-1208</Dataset_Title>
<Dataset_Release_Date>2026-04-08</Dataset_Release_Date>
<Dataset_Publisher>PANGAEA</Dataset_Publisher>
<Data_Presentation_Form>Dataset</Data_Presentation_Form>
<Online_Resource>https://doi.pangaea.de/10.1594/PANGAEA.993221</Online_Resource>
</Data_Set_Citation>
<Personnel>
<Role>Investigator</Role>
<First_Name>Joseph B</First_Name>
<Last_Name>Novak</Last_Name>
<Email>jobnovak@ucsc.edu</Email>
</Personnel>
<Discipline>
<Discipline_Name>Earth Science</Discipline_Name>
</Discipline>
<Parameters>
<Detailed_Variable>AGE</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Uranium, authigenic</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Uranium, authigenic, standard deviation</Detailed_Variable>
</Parameters>
<ISO_Topic_Category>geoscientificInformation</ISO_Topic_Category>
<Keyword>198-1208</Keyword>
<Keyword>Carbon cycle</Keyword>
<Keyword>carbon isotope gradients</Keyword>
<Keyword>Composite Core</Keyword>
<Keyword>Leg198</Keyword>
<Keyword>trace metals</Keyword>
<Sensor_Name>
<Long_Name>See description in dataset comment</Long_Name>
</Sensor_Name>
<Source_Name>
<Long_Name>Joides Resolution</Long_Name>
</Source_Name>
<Temporal_Coverage>
<Start_Date>2001-09-14</Start_Date>
<Stop_Date>2001-09-17</Stop_Date>
</Temporal_Coverage>
<Data_Set_Progress>Complete</Data_Set_Progress>
<Spatial_Coverage>
<Southernmost_Latitude>36.127166666667</Southernmost_Latitude>
<Northernmost_Latitude>36.127166666667</Northernmost_Latitude>
<Westernmost_Longitude>158.20158333333</Westernmost_Longitude>
<Easternmost_Longitude>158.20158333333</Easternmost_Longitude>
</Spatial_Coverage>
<Access_Constraints>unrestricted</Access_Constraints>
<Use_Constraints>CC-BY-4.0: Creative Commons Attribution 4.0 International</Use_Constraints>
<Data_Set_Language>English</Data_Set_Language>
<Data_Center>
<Data_Center_Name>
<Short_Name>PANGAEA</Short_Name>
<Long_Name>Data Publisher for Earth &amp; Environmental Science</Long_Name>
</Data_Center_Name>
<Data_Center_URL>https://www.pangaea.de/</Data_Center_URL>
<Personnel>
<Role>Data Center Contact</Role>
<First_Name>Michael</First_Name>
<Last_Name>Diepenbroek</Last_Name>
<Email>info@pangaea.de</Email>
<Contact_Address>
<Address>Leobener Str.</Address>
<City>Bremen</City>
<Province_or_State>Bremen</Province_or_State>
<Postal_Code>28359</Postal_Code>
<Country>Germany</Country>
</Contact_Address>
</Personnel>
</Data_Center>
<Distribution>
<Distribution_Media>online</Distribution_Media>
<Distribution_Size>320 data points</Distribution_Size>
<Distribution_Format>text/tab-separated-values</Distribution_Format>
</Distribution>
<Reference>Novak, Joseph B; Abell, Jordan; Kinsley, Christopher (2026): Quaternary trace metals data from ODP Site 198-1208 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.983610</Reference>
<Reference>Abell, Jordan T; Winckler, Gisela (2023): Long‐Term Variability in Pliocene North Pacific Ocean Export Production and Its Implications for Ocean Circulation in a Warmer World. AGU Advances, 4(4), e2022AV000853, https://doi.org/10.1029/2022AV000853</Reference>
<Reference>Abell, Jordan T; Winckler, Gisela; Anderson, Robert F; Herbert, Timothy D (2021): Poleward and weakened westerlies during Pliocene warmth. Nature, 589(7840), 70-75, https://doi.org/10.1038/s41586-020-03062-1</Reference>
<Reference>Henderson, G M (2003): The U-series Toolbox for Paleoceanography. Reviews in Mineralogy &amp; Geochemistry, 52(1), 493-531, https://doi.org/10.2113/0520493</Reference>
<Reference>Kinsley, C W; Bradtmiller, Louisa I; Zhang, Yan; McGee, David (2022): Ocean-atmosphere changes in the midlatitude North Pacific over the last 330 ka: Dust, biogenic sediment and authigenic uranium accumulation at Shatsky Rise — Dataset [dataset]. Zenodo, https://doi.org/10.5281/ZENODO.6791725</Reference>
<Reference>McGee, David; Winckler, Gisela; Borunda, Alejandra; Serno, Sascha; Anderson, Robert F; Recasens, Cristina; Bory, Aloys J-M; Gaiero, Diego M; Jaccard, Samuel L; Kaplan, Michael R; McManus, Jerry F; Revel, Marie; Sun, Youbin (2016): Tracking eolian dust with helium and thorium: Impacts of grain size and provenance. Geochimica et Cosmochimica Acta, 175, 47-67, https://doi.org/10.1016/j.gca.2015.11.023</Reference>
<Reference>Taylor, Stuart Ross; McLennan, Scott M (1995): The geochemical evolution of the continental crust. Reviews of Geophysics, 33(2), 241, https://doi.org/10.1029/95RG00262</Reference>
<Summary>This data set contains authigenic uranium concentrations from ODP Site 198-1208 that span ~2 to 330 thousand years ago. These data give insight into glacial-interglacial changes in sedimentary redox chemistry at the drill site. ** For all details see the full metadata description at "https://doi.pangaea.de/10.1594/PANGAEA.993221"! ** Methods:
Sample depths, ages, and Th concentrations have been previously published for the both the late Quaternary (Abell et al., 2023; Kinsley et al., 2022) and Pliocene-early Pleistocene (Abell et al., 2021). 
Because the late Quaternary data are based on measurements of distinct isotopes of U/Th (238U and 232Th) and not bulk concentrations of these elements, the lithogenic correction for these samples is made using activity ratios. 
Here we assume an activity ratio of 0.5. While the (U/Th)lith activity ratio for Pacific sediments is typically assumed to be higher at 0.7 (Henderson &amp; Anderson, 2003), use of this value would produce negative Uauth concentrations. 
A ratio of 0.5 does not lead to negative Uauth concentrations, and is consistent with estimates for other ocean basin (Henderson &amp; Anderson, 2003).
In order to make consistent comparison within a site across time, we convert this (U/Th)lith activity ratio to a concentration ratio (0.16125) for calculating Uauth concentrations within the 2.5–4.5 Ma window. 
This value is only slightly lower than if we adopted the U concentration of upper continental crust (2.8 ppm; Taylor &amp; McLennan, 1995) and the Th concentration of fine-grained dust (14 ppm; McGee et al., 2016).
We note that any value higher than this would also produce negative Uauth concentrations in this interval, lending confidence in our selected lithogenic (U/Th) ratio.</Summary>
<Related_URL>
<URL>http://en.wikipedia.org/wiki/Kyr</URL>
<Description>AGE</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1016/j.gca.2015.11.023</URL>
<Description>Tracking eolian dust with helium and thorium: Impacts of grain size and provenance</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1029/2022AV000853</URL>
<Description>Long‐Term Variability in Pliocene North Pacific Ocean Export Production and Its Implications for Ocean Circulation in a Warmer World</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1029/95RG00262</URL>
<Description>The geochemical evolution of the continental crust</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1038/s41586-020-03062-1</URL>
<Description>Poleward and weakened westerlies during Pliocene warmth</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.2113/0520493</URL>
<Description>The U-series Toolbox for Paleoceanography</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.2973/odp.proc.ir.198.2002</URL>
<Description>Leg198</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.5281/ZENODO.6791725</URL>
<Description>Ocean-atmosphere changes in the midlatitude North Pacific over the last 330 ka: Dust, biogenic sediment and authigenic uranium accumulation at Shatsky Rise — Dataset</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.pangaea.de/10.1594/PANGAEA.983610</URL>
<Description>Quaternary trace metals data from ODP Site 198-1208</Description>
</Related_URL>
<Related_URL>
<URL>https://www-odp.tamu.edu:443/resolutn.html</URL>
<Description>Joides Resolution</Description>
</Related_URL>
<Parent_DIF>PANGAEA_983612</Parent_DIF>
<Metadata_Name>DIF</Metadata_Name>
<Metadata_Version>9.4</Metadata_Version>
<DIF_Creation_Date>2026-04-08</DIF_Creation_Date>
<Last_DIF_Revision_Date>2026-04-08</Last_DIF_Revision_Date>
</DIF>
