<?xml version="1.0" encoding="UTF-8"?><!--*** Generated from internal PANGAEA metadata schema by dif.xslt ***--><DIF xsi:schemaLocation="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/ http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/dif_v9.4.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/">
<Entry_ID>PANGAEA_992726</Entry_ID>
<Entry_Title>Calcium isotopes (δ44Ca) of stalagmite HS4 in Heshang Cave, Central China</Entry_Title>
<Data_Set_Citation>
<Dataset_Creator>Liao, Jin; Day, Christopher</Dataset_Creator>
<Dataset_Title>Calcium isotopes (δ44Ca) of stalagmite HS4 in Heshang Cave, Central China</Dataset_Title>
<Dataset_Release_Date>2026-03-16</Dataset_Release_Date>
<Dataset_Publisher>PANGAEA</Dataset_Publisher>
<Data_Presentation_Form>Dataset</Data_Presentation_Form>
<Online_Resource>https://doi.pangaea.de/10.1594/PANGAEA.992726</Online_Resource>
</Data_Set_Citation>
<Personnel>
<Role>Investigator</Role>
<First_Name>Jin</First_Name>
<Last_Name>Liao</Last_Name>
<Email>liaojin_earth@163.com</Email>
</Personnel>
<Discipline>
<Discipline_Name>Earth Science</Discipline_Name>
</Discipline>
<Parameters>
<Detailed_Variable>Sample number</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>AGE</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Age, error</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>DISTANCE</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ44/42 Ca</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ44/42 Ca, error</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Rayleigh fractional model, crystallization</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Rayleigh fractional model, crystallization, error</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Precipitation, annual total</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Precipitation, annual total, error</Detailed_Variable>
</Parameters>
<ISO_Topic_Category>geoscientificInformation</ISO_Topic_Category>
<Keyword>Archaeological cultures</Keyword>
<Keyword>Calcium isotopes</Keyword>
<Keyword>Central China</Keyword>
<Keyword>Heshang_Cave_HS4</Keyword>
<Keyword>speleothem</Keyword>
<Keyword>Speleothem sample</Keyword>
<Keyword>trace elements</Keyword>
<Sensor_Name>
<Long_Name>Age, Uranium-Thorium</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Age, 14C calibration OxCal (Ramsey, 2008)</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Measured</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Inductively coupled plasma mass spectrometer (ICP-MS), Attom, Nu Instruments</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Calculated, 2 standard deviation</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>According to Owen et al. (2016)</Long_Name>
</Sensor_Name>
<Data_Set_Progress>Complete</Data_Set_Progress>
<Spatial_Coverage>
<Southernmost_Latitude>30.45</Southernmost_Latitude>
<Northernmost_Latitude>30.45</Northernmost_Latitude>
<Westernmost_Longitude>110.4167</Westernmost_Longitude>
<Easternmost_Longitude>110.4167</Easternmost_Longitude>
</Spatial_Coverage>
<Access_Constraints>unrestricted</Access_Constraints>
<Use_Constraints>CC-BY-4.0: Creative Commons Attribution 4.0 International</Use_Constraints>
<Data_Set_Language>English</Data_Set_Language>
<Data_Center>
<Data_Center_Name>
<Short_Name>PANGAEA</Short_Name>
<Long_Name>Data Publisher for Earth &amp; Environmental Science</Long_Name>
</Data_Center_Name>
<Data_Center_URL>https://www.pangaea.de/</Data_Center_URL>
<Personnel>
<Role>Data Center Contact</Role>
<First_Name>Michael</First_Name>
<Last_Name>Diepenbroek</Last_Name>
<Email>info@pangaea.de</Email>
<Contact_Address>
<Address>Leobener Str.</Address>
<City>Bremen</City>
<Province_or_State>Bremen</Province_or_State>
<Postal_Code>28359</Postal_Code>
<Country>Germany</Country>
</Contact_Address>
</Personnel>
</Data_Center>
<Distribution>
<Distribution_Media>online</Distribution_Media>
<Distribution_Size>344 data points</Distribution_Size>
<Distribution_Format>text/tab-separated-values</Distribution_Format>
</Distribution>
<Reference>Liao, Jin; Day, Christopher; Hu, Chaoyong; Liu, Y; Henderson, Gideon M (2026): Precise chronology of hydrological changes at ∼4.2 kyr in Central China to assess the impact of flooding on Neolithic societies. National Science Review, 13(2), nwaf567, https://doi.org/10.1093/nsr/nwaf567</Reference>
<Reference>Owen, R A; Day, C C; Hu, C-Y; Liu, Y-H; Pointing, M D; Blättler, Clara L; Henderson, G M (2016): Calcium isotopes in caves as a proxy for aridity: Modern calibration and application to the 8.2 kyr event. Earth and Planetary Science Letters, 443, 129-138, https://doi.org/10.1016/j.epsl.2016.03.027</Reference>
<Summary>Stalagmite calcium (d44Ca) isotope data was used to reconstruct regional paleorainfall amount in the Central China between 4.6 kyr BP and 3.5 kyr BP. The stalagmite (HS4) was collected from Heshang Cave in the Middle Yangtze Valley, Central China (30º27′N, 110º25′E, 294 m.a.s.l). HS4 Stalagmite length in this study ranges between 112.63 and 151.03 cm. The working half of HS4 was slabbed. Micro drilling of 343 continuous samples was undertaken by using a New-Wave Micromill. Every eighth sample was measured for d44Ca. The measurement resolution is ~25 years. The data was measured using a Nu Instruments multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS) at the University of Oxford, Department of Earth Sciences in 2016. ** For all details see the full metadata description at "https://doi.pangaea.de/10.1594/PANGAEA.992726"!</Summary>
<Related_URL>
<URL>http://en.wikipedia.org/wiki/Kyr</URL>
<Description>AGE</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1016/j.epsl.2016.03.027</URL>
<Description>According to Owen et al. (2016)</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1016/j.epsl.2016.03.027</URL>
<Description>Calcium isotopes in caves as a proxy for aridity: Modern calibration and application to the 8.2 kyr event</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1016/j.quascirev.2007.01.019</URL>
<Description>Age, 14C calibration OxCal (Ramsey, 2008)</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1093/nsr/nwaf567</URL>
<Description>Precise chronology of hydrological changes at ∼4.2 kyr in Central China to assess the impact of flooding on Neolithic societies</Description>
</Related_URL>
<Metadata_Name>DIF</Metadata_Name>
<Metadata_Version>9.4</Metadata_Version>
<DIF_Creation_Date>2026-03-16</DIF_Creation_Date>
<Last_DIF_Revision_Date>2026-03-16</Last_DIF_Revision_Date>
</DIF>
