<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-04-13">
<md:citation id="dataset992687">
<md:author id="dataset.author86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:author>
<md:author id="dataset.author114913">
<md:lastName>Lourenço</md:lastName>
<md:firstName>Rafael André</md:firstName>
<md:eMail>rafaell@usp.br</md:eMail>
</md:author>
<md:author id="dataset.author86214">
<md:lastName>Taniguchi</md:lastName>
<md:firstName>Satie</md:firstName>
</md:author>
<md:author id="dataset.author114914">
<md:lastName>Martins</md:lastName>
<md:firstName>César de Castro</md:firstName>
<md:eMail>ccmart@usp.br</md:eMail>
</md:author>
<md:author id="dataset.author83356">
<md:lastName>Wainer</md:lastName>
<md:firstName>Ilana E K C</md:firstName>
<md:eMail>wainer@usp.br</md:eMail>
<md:orcid>0000-0003-3784-623X</md:orcid>
</md:author>
<md:author id="dataset.author47053">
<md:lastName>Mahiques</md:lastName>
<md:firstName>Michel Michaelovitch</md:firstName>
<md:eMail>mahiques@usp.br</md:eMail>
<md:orcid>0000-0002-5249-5610</md:orcid>
</md:author>
<md:author id="dataset.author69337">
<md:lastName>Nagai</md:lastName>
<md:firstName>Renata Hanae</md:firstName>
<md:eMail>renatanagai@gmail.com</md:eMail>
<md:orcid>0000-0002-1358-5074</md:orcid>
</md:author>
<md:author id="dataset.author69338">
<md:lastName>Figueira</md:lastName>
<md:firstName>Rubens César Lopes</md:firstName>
<md:eMail>rfigueira@usp.br</md:eMail>
<md:orcid>0000-0001-8945-4540</md:orcid>
</md:author>
<md:author id="dataset.author114915">
<md:lastName>Bouloubassi</md:lastName>
<md:firstName>Ioanna D</md:firstName>
<md:eMail>ioanna.bouloubassi@locean.ipsl.fr</md:eMail>
</md:author>
<md:author id="dataset.author86210">
<md:lastName>Bicego</md:lastName>
<md:firstName>Marcia C</md:firstName>
<md:eMail>marciabicego@usp.br</md:eMail>
</md:author>
<md:year>2026</md:year>
<md:title>n-Alkane concentrations and molecular indices (CPI, ACL, Paq) from Holocene marine sediment cores MDBT 557 and MDBT 561 (southern Brazilian shelf)</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.org/10.1594/PANGAEA.992687</md:URI>
<md:dateTime>2026-03-09T06:55:31</md:dateTime>
</md:citation>
<md:abstract>This dataset presents concentrations of long-chain n-alkanes (nC25–nC33) and derived molecular indices, including Carbon Preference Index (CPI), Average Chain Length (ACL), and Paq, from Holocene marine sediment cores MDBT 557 and MDBT 561, recovered from the southern Brazilian continental shelf. Lipid biomarkers were extracted using organic solvents, purified by column chromatography, and quantified by gas chromatography with flame ionization detection (GC-FID), with surrogate standards used to assess analytical recovery. These data characterize variations in terrigenous organic matter input, vegetation-related signals, and hydrological conditions affecting the continental margin during the Holocene.</md:abstract>
<md:reference dataciteRelType="IsSupplementTo" group="200" id="ref138086" relationType="Supplement to" relationTypeId="5">
<md:author id="ref138086.author86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:author>
<md:author id="ref138086.author114913">
<md:lastName>Lourenço</md:lastName>
<md:firstName>Rafael André</md:firstName>
<md:eMail>rafaell@usp.br</md:eMail>
</md:author>
<md:author id="ref138086.author86214">
<md:lastName>Taniguchi</md:lastName>
<md:firstName>Satie</md:firstName>
</md:author>
<md:author id="ref138086.author114914">
<md:lastName>Martins</md:lastName>
<md:firstName>César de Castro</md:firstName>
<md:eMail>ccmart@usp.br</md:eMail>
</md:author>
<md:author id="ref138086.author83356">
<md:lastName>Wainer</md:lastName>
<md:firstName>Ilana E K C</md:firstName>
<md:eMail>wainer@usp.br</md:eMail>
<md:orcid>0000-0003-3784-623X</md:orcid>
</md:author>
<md:author id="ref138086.author47053">
<md:lastName>Mahiques</md:lastName>
<md:firstName>Michel Michaelovitch</md:firstName>
<md:eMail>mahiques@usp.br</md:eMail>
<md:orcid>0000-0002-5249-5610</md:orcid>
</md:author>
<md:author id="ref138086.author69337">
<md:lastName>Nagai</md:lastName>
<md:firstName>Renata Hanae</md:firstName>
<md:eMail>renatanagai@gmail.com</md:eMail>
<md:orcid>0000-0002-1358-5074</md:orcid>
</md:author>
<md:author id="ref138086.author69338">
<md:lastName>Figueira</md:lastName>
<md:firstName>Rubens César Lopes</md:firstName>
<md:eMail>rfigueira@usp.br</md:eMail>
<md:orcid>0000-0001-8945-4540</md:orcid>
</md:author>
<md:author id="ref138086.author114915">
<md:lastName>Bouloubassi</md:lastName>
<md:firstName>Ioanna D</md:firstName>
<md:eMail>ioanna.bouloubassi@locean.ipsl.fr</md:eMail>
</md:author>
<md:author id="ref138086.author86210">
<md:lastName>Bicego</md:lastName>
<md:firstName>Marcia C</md:firstName>
<md:eMail>marciabicego@usp.br</md:eMail>
</md:author>
<md:prepubStatus>in review</md:prepubStatus>
<md:title>Holocene composition, origin, and evolution of terrigenous organic matter in the southwestern Atlantic Ocean: Insights about vegetation, climate and oceanographic variations</md:title>
<md:source id="ref138086.journal16885" type="journal">Paleoceanography and Paleoclimatology</md:source>
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<md:eMail>maarten.blaauw@qub.ac.uk</md:eMail>
<md:URI>http://chrono.qub.ac.uk/blaauw/</md:URI>
<md:orcid>0000-0002-5680-1515</md:orcid>
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<md:lastName>Christen</md:lastName>
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<md:eMail>pgrootes@leibniz.uni-kiel.de</md:eMail>
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<md:eMail>kr@uphys1.uphys.uni-heidelberg.de</md:eMail>
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<md:orcid>0000-0002-3174-5190</md:orcid>
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<md:eMail>msc1@williams.edu</md:eMail>
<md:orcid>0000-0003-3786-6353</md:orcid>
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<md:orcid>0000-0002-4445-5520</md:orcid>
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<md:eMail>lcs32@cam.ac.uk</md:eMail>
<md:orcid>0000-0002-5050-0244</md:orcid>
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<md:pages>435-462</md:pages>
</md:reference>
<md:extent>
<md:geographic>
<md:westBoundLongitude>-52.21</md:westBoundLongitude>
<md:eastBoundLongitude>-51.3</md:eastBoundLongitude>
<md:southBoundLatitude>-33.79</md:southBoundLatitude>
<md:northBoundLatitude>-33.27</md:northBoundLatitude>
<md:meanLongitude>-51.754999999999995</md:meanLongitude>
<md:meanLatitude>-33.53</md:meanLatitude>
</md:geographic>
<md:temporal>
<md:minDateTime>2019-06-02T12:20:00</md:minDateTime>
<md:maxDateTime>2019-06-02T13:22:00</md:maxDateTime>
</md:temporal>
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<md:max>-80.0</md:max>
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<md:topoType id="topotype3">vertical profile</md:topoType>
</md:extent>
<md:award id="award4843">
<md:funder id="award4843.funder20820" semanticURI="https://doi.org/10.13039/501100001807">
<md:name>São Paulo Research Foundation</md:name>
<md:optionalName>FAPESP</md:optionalName>
<md:URI>https://fapesp.br/</md:URI>
<md:crossrefFunderId>https://doi.org/10.13039/501100001807</md:crossrefFunderId>
</md:funder>
<md:number>17/20344-7</md:number>
<md:title>Mudbelts of Southern and Southeast Brazil: Implications on anthropogenic influences on the marine environment</md:title>
<md:URI>https://bv.fapesp.br/pt/bolsas/174327/mudbelts-do-sul-e-sudeste-do-brasil-implicacoes-sobre-as-influencias-antropicas-no-ambiente-marinho/</md:URI>
</md:award>
<md:event displayTypeName="Event" id="event3358250" typeName="Generic Event">
<md:label>MDBT_557</md:label>
<md:latitude>-33.79</md:latitude>
<md:longitude>-52.21</md:longitude>
<md:location id="event3358250.term53509">
<md:name>Brazilian southeastern continental shelf</md:name>
</md:location>
<md:elevation>-90.0</md:elevation>
<md:dateTime>2019-06-02T12:20:00</md:dateTime>
<md:method id="event3358250.method11107">
<md:name>Gravity corer</md:name>
<md:optionalName>GC</md:optionalName>
</md:method>
</md:event>
<md:event displayTypeName="Event" id="event3358251" typeName="Generic Event">
<md:label>MDBT_561</md:label>
<md:latitude>-33.27</md:latitude>
<md:longitude>-51.3</md:longitude>
<md:location id="event3358251.term53509">
<md:name>Brazilian southeastern continental shelf</md:name>
</md:location>
<md:elevation>-80.0</md:elevation>
<md:dateTime>2019-06-02T13:22:00</md:dateTime>
<md:method id="event3358251.method11107">
<md:name>Gravity corer</md:name>
<md:optionalName>GC</md:optionalName>
</md:method>
</md:event>
<md:size unit="data points">1296</md:size>
<md:license id="license21">
<md:label>CC-BY-4.0</md:label>
<md:name>Creative Commons Attribution 4.0 International</md:name>
<md:URI>https://creativecommons.org/licenses/by/4.0/</md:URI>
</md:license>
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<md:parameter>
<md:name>Event label</md:name>
<md:shortName>Event</md:shortName>
</md:parameter>
<md:PI id="col0.ds15888662.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>Event</md:caption>
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<md:parameter id="col1.ds15888662.geocode1600">
<md:name>Latitude of event</md:name>
<md:shortName>Latitude</md:shortName>
</md:parameter>
<md:PI id="col1.ds15888662.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>Latitude</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="3" col="2" format="###0.0000" id="col2.ds15888662" source="event" type="numeric">
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<md:name>Longitude of event</md:name>
<md:shortName>Longitude</md:shortName>
</md:parameter>
<md:PI id="col2.ds15888662.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>Longitude</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="4" col="3" format="yyyy-MM-dd'T'HH:mm:ss" id="col3.ds15888662" source="event" type="datetime">
<md:parameter id="col3.ds15888662.geocode1599">
<md:name>Date/Time of event</md:name>
<md:shortName>Date/Time</md:shortName>
</md:parameter>
<md:PI id="col3.ds15888662.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>Date/Time</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="1" col="4" format="####0" id="col4.ds15888662" source="event" type="numeric">
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<md:name>Elevation of event</md:name>
<md:shortName>Elevation</md:shortName>
<md:unit>m</md:unit>
</md:parameter>
<md:PI id="col4.ds15888662.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>Elevation [m]</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="5" col="5" format="0.000" id="col5.ds15888663" source="geocode" type="numeric">
<md:parameter id="col5.ds15888663.geocode2205">
<md:name>AGE</md:name>
<md:shortName>Age</md:shortName>
<md:unit>ka BP</md:unit>
<md:URI>http://en.wikipedia.org/wiki/Kyr</md:URI>
<md:term endOffset="3" fragment="1" id="col5.ds15888663.geocode2205.term1073135" semanticURI="urn:obo:pato:term:0000011" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>age</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0000011</md:URI>
</md:term>
<md:term id="col5.ds15888663.geocode2205.term43975" semanticURI="http://qudt.org/1.1/vocab/quantity#Time" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Time</md:name>
<md:optionalName>T</md:optionalName>
<md:URI>http://dbpedia.org/resource/Time</md:URI>
</md:term>
</md:parameter>
<md:method id="col5.ds15888663.method415">
<md:name>Age, 14C calibrated</md:name>
</md:method>
<md:PI id="col5.ds15888663.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:comment>Age model according to Blaauw and Christen (2011), using BACON v2.4.3, with calibration using Marine20 (Heaton et al., 2020)</md:comment>
<md:caption>Age [ka BP]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="6" format="0.00" id="col6.ds15888664" source="data" type="numeric">
<md:parameter id="col6.ds15888664.param555356">
<md:name>n-Alkanes, sum, per unit sediment mass</md:name>
<md:shortName>n-A sum/sed</md:shortName>
<md:unit>µg/g</md:unit>
<md:term endOffset="14" fragment="2" id="col6.ds15888664.param555356.term38380" startOffset="11" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sum</md:name>
<md:URI>http://www.oxforddictionaries.com/definition/american_english/sum</md:URI>
</md:term>
<md:term id="col6.ds15888664.param555356.term47957" terminologyId="10" terminologyLabel="PAN-Key">
<md:name>n-alkanes</md:name>
</md:term>
</md:parameter>
<md:method id="col6.ds15888664.method8902">
<md:name>summarized</md:name>
</md:method>
<md:PI id="col6.ds15888664.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>n-A sum/sed [µg/g]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="7" format="0.00" id="col7.ds15888665" source="data" type="numeric">
<md:parameter id="col7.ds15888665.param88030">
<md:name>Sum n-alkanes C25-C33</md:name>
<md:shortName>C25-C33</md:shortName>
<md:unit>µg/g</md:unit>
</md:parameter>
<md:method id="col7.ds15888665.method17026">
<md:name>Gas chromatography - Flame Ionization Detection (GC-FID), Agilent Technologies, HP7890B</md:name>
</md:method>
<md:PI id="col7.ds15888665.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>C25-C33 [µg/g]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="8" format="0.00" id="col8.ds15888666" source="data" type="numeric">
<md:parameter id="col8.ds15888666.param27728">
<md:name>n-Alkanes, average chain length</md:name>
<md:shortName>ACL n-Alkane</md:shortName>
<md:term endOffset="8" fragment="1" id="col8.ds15888666.param27728.term39182" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>n-alkane</md:name>
</md:term>
</md:parameter>
<md:method id="col8.ds15888666.method18843">
<md:name>Calculated according to Poynter (1989)</md:name>
<md:URI>https://doi.org/10.1007/978-94-009-0995-3_18</md:URI>
</md:method>
<md:PI id="col8.ds15888666.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>ACL n-Alkane</md:caption>
</md:matrixColumn>
<md:matrixColumn col="9" format="0.00" id="col9.ds15888667" source="data" type="numeric">
<md:parameter id="col9.ds15888667.param169593">
<md:name>Average chain length, n-Alkanes, C27-C33</md:name>
<md:shortName>ACL 27-33</md:shortName>
<md:term endOffset="30" fragment="1" id="col9.ds15888667.param169593.term39182" startOffset="22" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>n-alkane</md:name>
</md:term>
</md:parameter>
<md:method id="col9.ds15888667.method18843">
<md:name>Calculated according to Poynter (1989)</md:name>
<md:URI>https://doi.org/10.1007/978-94-009-0995-3_18</md:URI>
</md:method>
<md:PI id="col9.ds15888667.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>ACL 27-33</md:caption>
</md:matrixColumn>
<md:matrixColumn col="10" format="0.00" id="col10.ds15888668" source="data" type="numeric">
<md:parameter id="col10.ds15888668.param5225">
<md:name>Carbon Preference Index</md:name>
<md:shortName>CPI</md:shortName>
<md:term endOffset="23" fragment="1" id="col10.ds15888668.param5225.term38305" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>carbon preference index</md:name>
<md:optionalName>CPI</md:optionalName>
<md:URI>https://doi.org/10.1016/j.marchem.2006.05.001</md:URI>
</md:term>
</md:parameter>
<md:method id="col10.ds15888668.method18842">
<md:name>Calculated according to Bray and Evans (1961)</md:name>
<md:URI>https://doi.org/10.1016/0016-7037(61)90069-2</md:URI>
</md:method>
<md:PI id="col10.ds15888668.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>CPI</md:caption>
</md:matrixColumn>
<md:matrixColumn col="11" format="0.00" id="col11.ds15888669" source="data" type="numeric">
<md:parameter id="col11.ds15888669.param539226">
<md:name>Aquatic n-alkane proxy</md:name>
<md:shortName>Paq</md:shortName>
</md:parameter>
<md:method id="col11.ds15888669.method50">
<md:name>Calculated</md:name>
</md:method>
<md:PI id="col11.ds15888669.pi86211">
<md:lastName>Santos</md:lastName>
<md:firstName>Felipe Rodrigues</md:firstName>
<md:eMail>feliperod@usp.br</md:eMail>
<md:orcid>0000-0001-8756-5036</md:orcid>
</md:PI>
<md:caption>Paq</md:caption>
</md:matrixColumn>
<md:status>
<md:curationLevel id="curlevel30">
<md:label>CurationLevelC</md:label>
<md:name>Enhanced curation</md:name>
<md:URI>https://wiki.pangaea.de/wiki/Curation_levels</md:URI>
</md:curationLevel>
</md:status>
<md:keywords>
<md:techKeyword type="autoGenerated">citable</md:techKeyword>
<md:keyword id="keywords.term71533" type="fromDatabase">alkanes</md:keyword>
<md:keyword id="keywords.term69901" type="fromDatabase">La Plata River</md:keyword>
<md:keyword id="keywords.term75919" type="fromDatabase">southern Brazilian margin</md:keyword>
<md:keyword id="keywords.term688" type="fromDatabase">vegetation changes</md:keyword>
<md:techKeyword type="autoGenerated">author10304</md:techKeyword>
<md:techKeyword type="autoGenerated">author10930</md:techKeyword>
<md:techKeyword type="autoGenerated">author114913</md:techKeyword>
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<md:techKeyword type="autoGenerated">author38487</md:techKeyword>
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</md:keywords>
<md:technicalInfo>
<md:entry key="xmlLastModified" value="2026-04-30T20:45:44Z"/>
<md:entry key="lastModified" value="2026-03-09T06:55:31"/>
<md:entry key="filename" value="MDBT_557_MDBT_561_n-alkane"/>
<md:entry key="mimeType" value="text/tab-separated-values"/>
<md:entry key="status" value="published"/>
<md:entry key="status_num" value="4"/>
<md:entry key="DOIRegistryStatus" value="registered"/>
<md:entry key="DOIRegistryStatus_num" value="4"/>
<md:entry key="DOIRegistrationDate" value="2026-03-09T06:55:45"/>
<md:entry key="loginOption" value="unrestricted"/>
<md:entry key="loginOption_num" value="1"/>
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