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Santos, Felipe Rodrigues; Lourenço, Rafael André; Taniguchi, Satie; Martins, César de Castro; Wainer, Ilana E K C; Mahiques, Michel Michaelovitch; Nagai, Renata Hanae; Figueira, Rubens César Lopes; Bouloubassi, Ioanna D; Bicego, Marcia C (2026): n-Alkane concentrations and molecular indices (CPI, ACL, Paq) from Holocene marine sediment cores MDBT 557 and MDBT 561 (southern Brazilian shelf) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.992687

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Published: 2026-03-09DOI registered: 2026-03-09

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Abstract:
This dataset presents concentrations of long-chain n-alkanes (nC25–nC33) and derived molecular indices, including Carbon Preference Index (CPI), Average Chain Length (ACL), and Paq, from Holocene marine sediment cores MDBT 557 and MDBT 561, recovered from the southern Brazilian continental shelf. Lipid biomarkers were extracted using organic solvents, purified by column chromatography, and quantified by gas chromatography with flame ionization detection (GC-FID), with surrogate standards used to assess analytical recovery. These data characterize variations in terrigenous organic matter input, vegetation-related signals, and hydrological conditions affecting the continental margin during the Holocene.
Keyword(s):
alkanes; La Plata River; southern Brazilian margin; vegetation changes
Supplement to:
Santos, Felipe Rodrigues; Lourenço, Rafael André; Taniguchi, Satie; Martins, César de Castro; Wainer, Ilana E K C; Mahiques, Michel Michaelovitch; Nagai, Renata Hanae; Figueira, Rubens César Lopes; Bouloubassi, Ioanna D; Bicego, Marcia C (in review): Holocene composition, origin, and evolution of terrigenous organic matter in the southwestern Atlantic Ocean: Insights about vegetation, climate and oceanographic variations. Paleoceanography and Paleoclimatology
References:
Blaauw, Maarten; Christen, Andrés (2011): Flexible paleoclimate age-depth models using an autoregressive gamma process. Bayesian Analysis, 6(3), 457-474, https://doi.org/10.1214/11-BA618
Bray, E E; Evans, E D (1961): Distribution of n-paraffins as a clue to recognition of source beds. Geochimica et Cosmochimica Acta, 22(1), 2-15, https://doi.org/10.1016/0016-7037(61)90069-2
Heaton, Timothy J; Köhler, Peter; Butzin, Martin; Bard, Edouard; Reimer, Ron W; Austin, William EN; Ramsey, Christopher Bronk; Grootes, Pieter Meiert; Hughen, Konrad A; Kromer, Bernd; Reimer, Paula J; Adkins, Jess F; Burke, Andreas; Cook, Mea S; Olsen, Jesper; Skinner, Luke C (2020): Marine20 - the marine radiocarbon age calibration curve (0-55,000 cal BP). Radiocarbon, 62(4), 779-820, https://doi.org/10.1017/RDC.2020.68
Poynter, J G; Farrimond, Paul; Robinson, Nicole; Eglinton, Geoffrey (1989): Aeolian-Derived Higher Plant Lipids in the Marine Sedimentary Record: Links with Palaeoclimate. In: Leinen, M, Sarnthein, M (eds.), Paleoclimatology and Paleometeorology: Modern and Past Patterns of Global Atmospheric Transport, Springer Netherlands, Dordrecht, 435-462, https://doi.org/10.1007/978-94-009-0995-3_18
Funding:
São Paulo Research Foundation (FAPESP), grant/award no. 17/20344-7: Mudbelts of Southern and Southeast Brazil: Implications on anthropogenic influences on the marine environment
Coverage:
Median Latitude: -33.530000 * Median Longitude: -51.755000 * South-bound Latitude: -33.790000 * West-bound Longitude: -52.210000 * North-bound Latitude: -33.270000 * East-bound Longitude: -51.300000
Date/Time Start: 2019-06-02T12:20:00 * Date/Time End: 2019-06-02T13:22:00
Minimum Elevation: -90.0 m * Maximum Elevation: -80.0 m
Event(s):
MDBT_557 * Latitude: -33.790000 * Longitude: -52.210000 * Date/Time: 2019-06-02T12:20:00 * Elevation: -90.0 m * Location: Brazilian southeastern continental shelf * Method/Device: Gravity corer (GC)
MDBT_561 * Latitude: -33.270000 * Longitude: -51.300000 * Date/Time: 2019-06-02T13:22:00 * Elevation: -80.0 m * Location: Brazilian southeastern continental shelf * Method/Device: Gravity corer (GC)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventSantos, Felipe Rodrigues
2Latitude of eventLatitudeSantos, Felipe Rodrigues
3Longitude of eventLongitudeSantos, Felipe Rodrigues
4Date/Time of eventDate/TimeSantos, Felipe Rodrigues
5Elevation of eventElevationmSantos, Felipe Rodrigues
6AGEAgeka BPSantos, Felipe RodriguesAge, 14C calibratedGeocode – Age model according to Blaauw and Christen (2011), using BACON v2.4.3, with calibration using Marine20 (Heaton et al., 2020)
7n-Alkanes, sum, per unit sediment massn-A sum/sedµg/gSantos, Felipe Rodriguessummarized
8Sum n-alkanes C25-C33C25-C33µg/gSantos, Felipe RodriguesGas chromatography - Flame Ionization Detection (GC-FID), Agilent Technologies, HP7890B
9n-Alkanes, average chain lengthACL n-AlkaneSantos, Felipe RodriguesCalculated according to Poynter (1989)
10Average chain length, n-Alkanes, C27-C33ACL 27-33Santos, Felipe RodriguesCalculated according to Poynter (1989)
11Carbon Preference IndexCPISantos, Felipe RodriguesCalculated according to Bray and Evans (1961)
12Aquatic n-alkane proxyPaqSantos, Felipe RodriguesCalculated
Status:
Curation Level: Enhanced curation (CurationLevelC)
Size:
1296 data points

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