<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-04-13">
<md:citation id="dataset992434">
<md:author id="dataset.author28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
<md:affiliation id="dataset.author28867.inst49">
<md:name>Leibniz Institute for Baltic Sea Research, Warnemünde</md:name>
<md:optionalName>IOW</md:optionalName>
<md:URI>https://www.io-warnemuende.de/en_index.html</md:URI>
<md:ROR>https://ror.org/03xh9nq73</md:ROR>
</md:affiliation>
<md:affiliation id="dataset.author28867.inst21719">
<md:name>University of Greifswald</md:name>
<md:ROR>https://ror.org/00r1edq15</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author87950">
<md:lastName>Ehlert von Ahn</md:lastName>
<md:firstName>Cátia Milene</md:firstName>
<md:eMail>catia.vonahn@io-warnemuende.de</md:eMail>
<md:orcid>0000-0001-7524-5908</md:orcid>
<md:affiliation id="dataset.author87950.inst49">
<md:name>Leibniz Institute for Baltic Sea Research, Warnemünde</md:name>
<md:optionalName>IOW</md:optionalName>
<md:URI>https://www.io-warnemuende.de/en_index.html</md:URI>
<md:ROR>https://ror.org/03xh9nq73</md:ROR>
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</md:author>
<md:author id="dataset.author10239">
<md:lastName>Dellwig</md:lastName>
<md:firstName>Olaf</md:firstName>
<md:eMail>olaf.dellwig@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-0028-8812</md:orcid>
<md:affiliation id="dataset.author10239.inst49">
<md:name>Leibniz Institute for Baltic Sea Research, Warnemünde</md:name>
<md:optionalName>IOW</md:optionalName>
<md:URI>https://www.io-warnemuende.de/en_index.html</md:URI>
<md:ROR>https://ror.org/03xh9nq73</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author675">
<md:lastName>Struck</md:lastName>
<md:firstName>Ulrich</md:firstName>
<md:eMail>Ulrich.Struck@mfn.berlin</md:eMail>
<md:URI>https://www.geo.fu-berlin.de/geol/fachrichtungen/pal/mitarbeiter/assoziierte-wissenschaftler/struck/index.html</md:URI>
<md:affiliation id="dataset.author675.inst21170">
<md:name>Freie Universität Berlin</md:name>
<md:ROR>https://ror.org/046ak2485</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author28305">
<md:lastName>Gehre</md:lastName>
<md:firstName>Matthias</md:firstName>
<md:eMail>matthias.gehre@ufz.de</md:eMail>
<md:affiliation id="dataset.author28305.inst468">
<md:name>Helmholtz Centre for Environmental Research - UFZ</md:name>
<md:optionalName>UFZ</md:optionalName>
<md:URI>http://www.ufz.de/</md:URI>
<md:ROR>https://ror.org/000h6jb29</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author53807">
<md:lastName>Escher</md:lastName>
<md:firstName>Peter</md:firstName>
<md:affiliation id="dataset.author53807.inst49">
<md:name>Leibniz Institute for Baltic Sea Research, Warnemünde</md:name>
<md:optionalName>IOW</md:optionalName>
<md:URI>https://www.io-warnemuende.de/en_index.html</md:URI>
<md:ROR>https://ror.org/03xh9nq73</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author114855">
<md:lastName>Vogler</md:lastName>
<md:firstName>Susann</md:firstName>
<md:eMail>susann.vogler@io-warnemuende.de</md:eMail>
<md:affiliation id="dataset.author114855.inst49">
<md:name>Leibniz Institute for Baltic Sea Research, Warnemünde</md:name>
<md:optionalName>IOW</md:optionalName>
<md:URI>https://www.io-warnemuende.de/en_index.html</md:URI>
<md:ROR>https://ror.org/03xh9nq73</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author71911">
<md:lastName>Szymczycha</md:lastName>
<md:firstName>Beata</md:firstName>
<md:eMail>beatsz@iopan.pl</md:eMail>
<md:orcid>0000-0002-5815-215X</md:orcid>
<md:affiliation id="dataset.author71911.inst22605">
<md:name>Institute of Oceanology Polish Academy of Sciences</md:name>
<md:optionalName>IO PAN</md:optionalName>
<md:URI>https://www.iopan.pl</md:URI>
<md:ROR>https://ror.org/03mp6cc45</md:ROR>
</md:affiliation>
</md:author>
<md:author id="dataset.author71885">
<md:lastName>Kotwicki</md:lastName>
<md:firstName>Lech</md:firstName>
<md:orcid>0000-0001-5876-5696</md:orcid>
<md:affiliation id="dataset.author71885.inst22605">
<md:name>Institute of Oceanology Polish Academy of Sciences</md:name>
<md:optionalName>IO PAN</md:optionalName>
<md:URI>https://www.iopan.pl</md:URI>
<md:ROR>https://ror.org/03mp6cc45</md:ROR>
</md:affiliation>
</md:author>
<md:year>2026</md:year>
<md:title>Geochemistry of shoreline sites impacted by submarine groundwater discharge in Hel, Puck Bay, Poland, southern Baltic Sea 2009 and 2010</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.org/10.1594/PANGAEA.992434</md:URI>
<md:dateTime>2026-02-23T08:44:05</md:dateTime>
</md:citation>
<md:abstract>Pore waters were retrived from coastal sands of the southern coastline off Hel Island, Puck Bay, southern Baltic Sea. Multiport-porewater lances equipped with syringes were used to obtained vertical profiles in areas impacted by fresh submarine groundwater discharge and less impacted 'reference sites'. Samples were taken during 11 campaigns between September 2009 and October 2010. Pore waters were analyzed on-site for salinity and pH, and for major and trace elements, water isotopes (H,O) and the C isotope composition of dissolved inorganc carbon in the laboratory (via ICP-OES and gas mass spectrometry). Selected methane samples were analyzed via GCirmMS for the C and H isotope composition. It was the aim to investigate the fluxes and fresh water composition of submarine groundwater discharge and the seasonal dynamics.</md:abstract>
<md:reference dataciteRelType="References" group="210" id="ref133037" relationType="Related to" relationTypeId="12">
<md:author id="ref133037.author87950">
<md:lastName>Ehlert von Ahn</md:lastName>
<md:firstName>Cátia Milene</md:firstName>
<md:eMail>catia.vonahn@io-warnemuende.de</md:eMail>
<md:orcid>0000-0001-7524-5908</md:orcid>
</md:author>
<md:author id="ref133037.author10239">
<md:lastName>Dellwig</md:lastName>
<md:firstName>Olaf</md:firstName>
<md:eMail>olaf.dellwig@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-0028-8812</md:orcid>
</md:author>
<md:author id="ref133037.author71911">
<md:lastName>Szymczycha</md:lastName>
<md:firstName>Beata</md:firstName>
<md:eMail>beatsz@iopan.pl</md:eMail>
<md:orcid>0000-0002-5815-215X</md:orcid>
</md:author>
<md:author id="ref133037.author71885">
<md:lastName>Kotwicki</md:lastName>
<md:firstName>Lech</md:firstName>
<md:orcid>0000-0001-5876-5696</md:orcid>
</md:author>
<md:author id="ref133037.author110693">
<md:lastName>Rooze</md:lastName>
<md:firstName>Jurjen</md:firstName>
<md:orcid>0000-0001-5429-9878</md:orcid>
</md:author>
<md:author id="ref133037.author686">
<md:lastName>Endler</md:lastName>
<md:firstName>Rudolf</md:firstName>
</md:author>
<md:author id="ref133037.author53807">
<md:lastName>Escher</md:lastName>
<md:firstName>Peter</md:firstName>
</md:author>
<md:author id="ref133037.author70169">
<md:lastName>Schmiedinger</md:lastName>
<md:firstName>Iris</md:firstName>
<md:eMail>iris.schmiedinger@io-warnemuende.de</md:eMail>
</md:author>
<md:author id="ref133037.author24583">
<md:lastName>Sültenfuß</md:lastName>
<md:firstName>Jürgen</md:firstName>
<md:eMail>suelten@uni-bremen.de</md:eMail>
<md:URI>http://www.ocean.uni-bremen.de/mitarbeiter/jsuelten/index_js_eng.html</md:URI>
<md:orcid>0000-0003-3169-0422</md:orcid>
</md:author>
<md:author id="ref133037.author110606">
<md:lastName>Diak</md:lastName>
<md:firstName>Magdalena</md:firstName>
<md:eMail>diakmagdalena@gmail.com</md:eMail>
</md:author>
<md:author id="ref133037.author28305">
<md:lastName>Gehre</md:lastName>
<md:firstName>Matthias</md:firstName>
<md:eMail>matthias.gehre@ufz.de</md:eMail>
</md:author>
<md:author id="ref133037.author675">
<md:lastName>Struck</md:lastName>
<md:firstName>Ulrich</md:firstName>
<md:eMail>Ulrich.Struck@mfn.berlin</md:eMail>
<md:URI>https://www.geo.fu-berlin.de/geol/fachrichtungen/pal/mitarbeiter/assoziierte-wissenschaftler/struck/index.html</md:URI>
</md:author>
<md:author id="ref133037.author110694">
<md:lastName>Vogler</md:lastName>
<md:firstName>Susan</md:firstName>
</md:author>
<md:author id="ref133037.author28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:author>
<md:year>2024</md:year>
<md:title>Submarine groundwater discharge into a semi-enclosed coastal bay of the southern Baltic Sea: A multi-method approach</md:title>
<md:type id="ref133037.reftype1">journal article</md:type>
<md:source id="ref133037.journal12196" relatedTermIds="34022" type="journal">Oceanologia</md:source>
<md:volume>66(1)</md:volume>
<md:URI>https://doi.org/10.1016/j.oceano.2024.01.001</md:URI>
<md:pages>111-138</md:pages>
</md:reference>
<md:extent>
<md:geographic>
<md:westBoundLongitude>18.8</md:westBoundLongitude>
<md:eastBoundLongitude>18.8</md:eastBoundLongitude>
<md:southBoundLatitude>54.604999999999826</md:southBoundLatitude>
<md:northBoundLatitude>54.604999999999826</md:northBoundLatitude>
<md:meanLongitude>18.8</md:meanLongitude>
<md:meanLatitude>54.604999999999826</md:meanLatitude>
</md:geographic>
<md:temporal>
<md:minDateTime>2009-09-02T00:00:00</md:minDateTime>
<md:maxDateTime>2010-10-05T00:00:00</md:maxDateTime>
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<md:elevation geocodeId="geocode1" name="DEPTH, sediment/rock" unit="m">
<md:min>-0.2</md:min>
<md:max>0.4</md:max>
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<md:topoType id="topotype3">vertical profile</md:topoType>
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<md:award id="award4828">
<md:funder id="award4828.funder20473" semanticURI="https://doi.org/10.13039/501100002347">
<md:name>Federal Ministry of Education and Research</md:name>
<md:optionalName>BMBF</md:optionalName>
<md:URI>https://www.bmbf.de/</md:URI>
<md:crossrefFunderId>https://doi.org/10.13039/501100002347</md:crossrefFunderId>
</md:funder>
<md:number>03F0485A</md:number>
<md:title>Assessment and Modelling Baltic Ecosystem Response (AMBER) BONUS</md:title>
</md:award>
<md:award id="award1305">
<md:funder id="award1305.funder20928" semanticURI="https://doi.org/10.13039/501100001655">
<md:name>German Academic Exchange Service</md:name>
<md:optionalName>DAAD</md:optionalName>
<md:crossrefFunderId>https://doi.org/10.13039/501100001655</md:crossrefFunderId>
</md:funder>
<md:number>57381412</md:number>
<md:title>DAAD_Phd scholarship</md:title>
</md:award>
<md:event displayTypeName="Event" id="event3357717" typeName="Generic Event">
<md:label>PB_Site-Hel-02-10</md:label>
<md:latitude>54.605</md:latitude>
<md:longitude>18.8</md:longitude>
<md:location id="event3357717.term76038">
<md:name>Puck Bay, Baltic Sea, Poland</md:name>
<md:URI>https://www.geonames.org/3087689</md:URI>
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<md:dateTime>2010-02-28T00:00:00</md:dateTime>
<md:dateTime2>2010-02-28T00:00:00</md:dateTime2>
<md:method id="event3357717.method16991">
<md:name>Porewater lance</md:name>
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<md:label>PB_Site-Hel-03-10</md:label>
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<md:dateTime>2010-02-27T00:00:00</md:dateTime>
<md:dateTime2>2010-03-01T00:00:00</md:dateTime2>
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<md:name>Porewater lance</md:name>
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<md:dateTime2>2009-09-03T00:00:00</md:dateTime2>
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<md:dateTime2>2009-11-05T00:00:00</md:dateTime2>
<md:method id="event3357716.method16991">
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<md:license id="license21">
<md:label>CC-BY-4.0</md:label>
<md:name>Creative Commons Attribution 4.0 International</md:name>
<md:URI>https://creativecommons.org/licenses/by/4.0/</md:URI>
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<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
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<md:lastName>Böttcher</md:lastName>
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<md:lastName>Böttcher</md:lastName>
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<md:PI id="col4.ds15885309.pi28867">
<md:lastName>Böttcher</md:lastName>
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<md:orcid>0000-0002-8877-0303</md:orcid>
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<md:PI id="col5.ds15885310.pi28867">
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<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>Depth sed [m]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="6" format="0.0" id="col6.ds15885311" source="data" type="numeric">
<md:parameter id="col6.ds15885311.param716">
<md:name>Salinity</md:name>
<md:shortName>Sal</md:shortName>
<md:term endOffset="8" fragment="1" id="col6.ds15885311.param716.term2698012" semanticURI="urn:obo:pato:term:0085001" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>salinity</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0085001</md:URI>
</md:term>
</md:parameter>
<md:method id="col6.ds15885311.method199">
<md:name>CTD</md:name>
<md:term id="col6.ds15885311.method199.term2299371" semanticURI="SDN:L05::130" terminologyId="21" terminologyLabel="NERC-L05-L22">
<md:name>CTD</md:name>
<md:URI>http://vocab.nerc.ac.uk/collection/L05/current/130/</md:URI>
</md:term>
<md:term id="col6.ds15885311.method199.term67626" terminologyId="3" terminologyLabel="PAN-M&amp;D">
<md:name>CTD &amp; XBT</md:name>
</md:term>
</md:method>
<md:PI id="col6.ds15885311.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>Sal</md:caption>
</md:matrixColumn>
<md:matrixColumn col="7" format="0.0" id="col7.ds15885312" source="data" type="numeric">
<md:parameter id="col7.ds15885312.param764">
<md:name>pH</md:name>
<md:shortName>pH</md:shortName>
</md:parameter>
<md:method id="col7.ds15885312.method18767">
<md:name>Ion selective electrode</md:name>
</md:method>
<md:PI id="col7.ds15885312.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>pH</md:caption>
</md:matrixColumn>
<md:matrixColumn col="8" format="0.0" id="col8.ds15885313" source="data" type="numeric">
<md:parameter id="col8.ds15885313.param2267">
<md:name>Hydrogen sulfide</md:name>
<md:shortName>H2S</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="16" fragment="1" id="col8.ds15885313.param2267.term1073771" semanticURI="http://purl.obolibrary.org/obo/CHEBI_16136" startOffset="0" terminologyId="16" terminologyLabel="ChEBI">
<md:name>hydrogen sulfide</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_16136</md:URI>
</md:term>
<md:term id="col8.ds15885313.param2267.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col8.ds15885313.method17024">
<md:name>Spectrophotometry using methylene blue method  according to Cline (1969)</md:name>
</md:method>
<md:PI id="col8.ds15885313.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>H2S [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="9" format="0.0" id="col9.ds15885314" source="data" type="numeric">
<md:parameter id="col9.ds15885314.param59">
<md:name>Calcium</md:name>
<md:shortName>Ca</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col9.ds15885314.param59.term38520" semanticURI="http://purl.obolibrary.org/obo/CHEBI_22984" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>calcium</md:name>
<md:optionalName>Ca</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:22984</md:URI>
</md:term>
<md:term id="col9.ds15885314.param59.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col9.ds15885314.method18766">
<md:name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</md:name>
</md:method>
<md:PI id="col9.ds15885314.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>Ca [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="10" format="0.0" id="col10.ds15885315" source="data" type="numeric">
<md:parameter id="col10.ds15885315.param58">
<md:name>Sodium</md:name>
<md:shortName>Na</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col10.ds15885315.param58.term41048" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sodium</md:name>
</md:term>
<md:term id="col10.ds15885315.param58.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col10.ds15885315.method18766">
<md:name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</md:name>
</md:method>
<md:PI id="col10.ds15885315.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>Na [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="11" format="0.0" id="col11.ds15885316" source="data" type="numeric">
<md:parameter id="col11.ds15885316.param57">
<md:name>Potassium</md:name>
<md:shortName>K</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col11.ds15885316.param57.term40134" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>potassium</md:name>
<md:optionalName>K</md:optionalName>
</md:term>
<md:term id="col11.ds15885316.param57.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col11.ds15885316.method18766">
<md:name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</md:name>
</md:method>
<md:PI id="col11.ds15885316.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>K [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="12" format="0.0" id="col12.ds15885317" source="data" type="numeric">
<md:parameter id="col12.ds15885317.param60">
<md:name>Magnesium</md:name>
<md:shortName>Mg</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col12.ds15885317.param60.term40665" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>magnesium</md:name>
</md:term>
<md:term id="col12.ds15885317.param60.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col12.ds15885317.method18766">
<md:name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</md:name>
</md:method>
<md:PI id="col12.ds15885317.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>Mg [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="13" format="0.0" id="col13.ds15885318" source="data" type="numeric">
<md:parameter id="col13.ds15885318.param510659">
<md:name>Sulfur</md:name>
<md:shortName>S</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col13.ds15885318.param510659.term40685" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>sulfur</md:name>
</md:term>
<md:term id="col13.ds15885318.param510659.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col13.ds15885318.method18766">
<md:name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</md:name>
</md:method>
<md:PI id="col13.ds15885318.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>S [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="14" format="0.0" id="col14.ds15885319" source="data" type="numeric">
<md:parameter id="col14.ds15885319.param83981">
<md:name>Silicon</md:name>
<md:shortName>Si</md:shortName>
<md:unit>mmol/l</md:unit>
<md:term endOffset="7" fragment="1" id="col14.ds15885319.param83981.term38478" semanticURI="http://purl.obolibrary.org/obo/CHEBI_27573" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>silicon</md:name>
<md:optionalName>Si</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:27573</md:URI>
</md:term>
<md:term id="col14.ds15885319.param83981.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col14.ds15885319.method18766">
<md:name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</md:name>
</md:method>
<md:PI id="col14.ds15885319.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>Si [mmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="15" format="0.0" id="col15.ds15885320" source="data" type="numeric">
<md:parameter id="col15.ds15885320.param92377">
<md:name>Phosphorus</md:name>
<md:shortName>P</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="10" fragment="1" id="col15.ds15885320.param92377.term39985" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>phosphorus</md:name>
</md:term>
<md:term id="col15.ds15885320.param92377.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col15.ds15885320.method18766">
<md:name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</md:name>
</md:method>
<md:PI id="col15.ds15885320.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>P [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="16" format="0.0" id="col16.ds15885321" source="data" type="numeric">
<md:parameter id="col16.ds15885321.param63">
<md:name>Iron</md:name>
<md:shortName>Fe</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term id="col16.ds15885321.param63.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col16.ds15885321.method18766">
<md:name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</md:name>
</md:method>
<md:PI id="col16.ds15885321.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>Fe [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="17" format="0.0" id="col17.ds15885322" source="data" type="numeric">
<md:parameter id="col17.ds15885322.param64">
<md:name>Manganese</md:name>
<md:shortName>Mn</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="9" fragment="1" id="col17.ds15885322.param64.term38521" semanticURI="http://purl.obolibrary.org/obo/CHEBI_18291" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>manganese</md:name>
<md:optionalName>Mn</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:18291</md:URI>
</md:term>
<md:term id="col17.ds15885322.param64.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col17.ds15885322.method18766">
<md:name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</md:name>
</md:method>
<md:PI id="col17.ds15885322.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>Mn [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="18" format="0.0" id="col18.ds15885323" source="data" type="numeric">
<md:parameter id="col18.ds15885323.param722">
<md:name>Barium</md:name>
<md:shortName>Ba</md:shortName>
<md:unit>µmol/l</md:unit>
<md:term endOffset="6" fragment="1" id="col18.ds15885323.param722.term40966" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>barium</md:name>
</md:term>
<md:term id="col18.ds15885323.param722.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col18.ds15885323.method18766">
<md:name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</md:name>
</md:method>
<md:PI id="col18.ds15885323.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>Ba [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="19" format="0.0" id="col19.ds15885324" source="data" type="numeric">
<md:parameter id="col19.ds15885324.param502173">
<md:name>δ18O, porewater</md:name>
<md:shortName>δ18O pw</md:shortName>
<md:unit>‰ SMOW</md:unit>
</md:parameter>
<md:method id="col19.ds15885324.method18764">
<md:name>Cavity ring-down spectroscopy (CRDS), isotopic water analyzer, Picarro Inc., L1102-i</md:name>
</md:method>
<md:PI id="col19.ds15885324.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:comment>vs. VSMOW</md:comment>
<md:caption>δ18O pw [‰ SMOW]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="20" format="0.0" id="col20.ds15885325" source="data" type="numeric">
<md:parameter id="col20.ds15885325.param502174">
<md:name>δ Deuterium, porewater</md:name>
<md:shortName>δD pw</md:shortName>
<md:unit>‰ SMOW</md:unit>
</md:parameter>
<md:method id="col20.ds15885325.method18764">
<md:name>Cavity ring-down spectroscopy (CRDS), isotopic water analyzer, Picarro Inc., L1102-i</md:name>
</md:method>
<md:PI id="col20.ds15885325.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:comment>vs. VSMOW</md:comment>
<md:caption>δD pw [‰ SMOW]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="21" format="0.0" id="col21.ds15885326" source="data" type="numeric">
<md:parameter id="col21.ds15885326.param770">
<md:name>δ13C, dissolved inorganic carbon</md:name>
<md:shortName>δ13C DIC</md:shortName>
<md:unit>‰ PDB</md:unit>
<md:term endOffset="4" fragment="1" id="col21.ds15885326.param770.term1073089" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>δ13C</md:name>
<md:URI>http://en.wikipedia.org/wiki/List_of_elements_by_stability_of_isotopes</md:URI>
</md:term>
<md:term endOffset="32" fragment="2" id="col21.ds15885326.param770.term40625" startOffset="6" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>dissolved inorganic carbon</md:name>
<md:optionalName>DIC</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col21.ds15885326.method18768">
<md:name>Isotope ratio mass spectrometer (IRMS), MAT; coupled with Gas bench</md:name>
</md:method>
<md:PI id="col21.ds15885326.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:comment>vs. VPDB</md:comment>
<md:caption>δ13C DIC [‰ PDB]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="22" format="0" id="col22.ds15885327" source="data" type="numeric">
<md:parameter id="col22.ds15885327.param143493">
<md:name>Alkalinity, total</md:name>
<md:shortName>AT</md:shortName>
<md:unit>µmol/l</md:unit>
<md:URI>https://en.wikipedia.org/wiki/Alkalinity</md:URI>
<md:term endOffset="17" fragment="1" id="col22.ds15885327.param143493.term38253" startOffset="12" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>total</md:name>
<md:URI>https://www.oxforddictionaries.com/definition/american_english/total</md:URI>
</md:term>
<md:term id="col22.ds15885327.param143493.term44030" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Molar Concentration</md:name>
</md:term>
</md:parameter>
<md:method id="col22.ds15885327.method8475">
<md:name>Potentiometric titration</md:name>
</md:method>
<md:PI id="col22.ds15885327.pi28867">
<md:lastName>Böttcher</md:lastName>
<md:firstName>Michael Ernst</md:firstName>
<md:eMail>michael.boettcher@io-warnemuende.de</md:eMail>
<md:orcid>0000-0002-8877-0303</md:orcid>
</md:PI>
<md:caption>AT [µmol/l]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="23" format="0.0" id="col23.ds15885328" source="data" type="numeric">
<md:parameter id="col23.ds15885328.param530893">
<md:name>δ13C, methane, porewater</md:name>
<md:shortName>δ13C CH4 pw</md:shortName>
<md:unit>‰ PDB</md:unit>
<md:term endOffset="4" fragment="1" id="col23.ds15885328.param530893.term1073089" startOffset="0" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>δ13C</md:name>
<md:URI>http://en.wikipedia.org/wiki/List_of_elements_by_stability_of_isotopes</md:URI>
</md:term>
<md:term endOffset="13" fragment="2" id="col23.ds15885328.param530893.term1073620" semanticURI="http://purl.obolibrary.org/obo/CHEBI_16183" startOffset="6" terminologyId="16" terminologyLabel="ChEBI">
<md:name>methane</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_16183</md:URI>
</md:term>
</md:parameter>
<md:method id="col23.ds15885328.method16175">
<md:name>Gas chromatography - isotope ratio mass spectrometry (GC-IRMS)</md:name>
</md:method>
<md:PI id="col23.ds15885328.pi28867">
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<md:comment>vs. VPDB</md:comment>
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<md:comment>vs. VSMOW; porewater</md:comment>
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<md:entry key="lastModified" value="2026-03-24T12:34:15"/>
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