<?xml version="1.0" encoding="UTF-8"?><!--*** Generated from internal PANGAEA metadata schema by dif.xslt ***--><DIF xsi:schemaLocation="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/ http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/dif_v9.4.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/">
<Entry_ID>PANGAEA_992434</Entry_ID>
<Entry_Title>Geochemistry of shoreline sites impacted by submarine groundwater discharge in Hel, Puck Bay, Poland, southern Baltic Sea 2009 and 2010</Entry_Title>
<Data_Set_Citation>
<Dataset_Creator>Böttcher, Michael Ernst; Ehlert von Ahn, Cátia Milene; Dellwig, Olaf; Struck, Ulrich; Gehre, Matthias; Escher, Peter; Vogler, Susann; Szymczycha, Beata; Kotwicki, Lech</Dataset_Creator>
<Dataset_Title>Geochemistry of shoreline sites impacted by submarine groundwater discharge in Hel, Puck Bay, Poland, southern Baltic Sea 2009 and 2010</Dataset_Title>
<Dataset_Release_Date>2026-02-23</Dataset_Release_Date>
<Dataset_Publisher>PANGAEA</Dataset_Publisher>
<Data_Presentation_Form>Dataset</Data_Presentation_Form>
<Online_Resource>https://doi.pangaea.de/10.1594/PANGAEA.992434</Online_Resource>
</Data_Set_Citation>
<Personnel>
<Role>Investigator</Role>
<First_Name>Michael Ernst</First_Name>
<Last_Name>Böttcher</Last_Name>
<Email>michael.boettcher@io-warnemuende.de</Email>
</Personnel>
<Discipline>
<Discipline_Name>Earth Science</Discipline_Name>
</Discipline>
<Parameters>
<Detailed_Variable>Event label</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>LATITUDE</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>LONGITUDE</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>DATE/TIME</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Type</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>DEPTH, sediment/rock</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Salinity</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>pH</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Hydrogen sulfide</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Calcium</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Sodium</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Potassium</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Magnesium</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Sulfur</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Silicon</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Phosphorus</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Iron</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Manganese</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Barium</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ18O, porewater</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ Deuterium, porewater</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ13C, dissolved inorganic carbon</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Alkalinity, total</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ13C, methane, porewater</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ Deuterium, methane</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Ammonium</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Name</Detailed_Variable>
</Parameters>
<ISO_Topic_Category>geoscientificInformation</ISO_Topic_Category>
<Keyword>coastal sand</Keyword>
<Keyword>Hel Island</Keyword>
<Keyword>PB_Site-Hel-02-10</Keyword>
<Keyword>PB_Site-Hel-03-10</Keyword>
<Keyword>PB_Site-Hel-05-10</Keyword>
<Keyword>PB_Site-Hel-09-09</Keyword>
<Keyword>PB_Site-Hel-10-10</Keyword>
<Keyword>PB_Site-Hel-11-09</Keyword>
<Keyword>porewater geochemistry</Keyword>
<Keyword>Porewater lance</Keyword>
<Keyword>Puck Bay</Keyword>
<Keyword>Seasonality</Keyword>
<Keyword>southern Baltic Sea</Keyword>
<Keyword>stable isotope composition</Keyword>
<Keyword>Submarine groundwater discharge</Keyword>
<Sensor_Name>
<Long_Name>CTD</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Ion selective electrode</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Spectrophotometry using methylene blue method  according to Cline (1969)</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Inductively coupled plasma–optical emission spectrometer (ICP-OES), Thermo Fisher ScientificScientific, iCAP 6300</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Cavity ring-down spectroscopy (CRDS), isotopic water analyzer, Picarro Inc., L1102-i</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Isotope ratio mass spectrometer (IRMS), MAT; coupled with Gas bench</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Potentiometric titration</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>Gas chromatography - isotope ratio mass spectrometry (GC-IRMS)</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>QuAAtro AutoAnalyzer</Long_Name>
</Sensor_Name>
<Temporal_Coverage>
<Start_Date>2009-09-02</Start_Date>
<Stop_Date>2010-10-05</Stop_Date>
</Temporal_Coverage>
<Data_Set_Progress>Complete</Data_Set_Progress>
<Spatial_Coverage>
<Southernmost_Latitude>54.604999999999826</Southernmost_Latitude>
<Northernmost_Latitude>54.604999999999826</Northernmost_Latitude>
<Westernmost_Longitude>18.8</Westernmost_Longitude>
<Easternmost_Longitude>18.8</Easternmost_Longitude>
<Minimum_Depth>-0.2 m (DEPTH, sediment/rock)</Minimum_Depth>
<Maximum_Depth>0.4 m (DEPTH, sediment/rock)</Maximum_Depth>
</Spatial_Coverage>
<Access_Constraints>unrestricted</Access_Constraints>
<Use_Constraints>CC-BY-4.0: Creative Commons Attribution 4.0 International</Use_Constraints>
<Data_Set_Language>English</Data_Set_Language>
<Data_Center>
<Data_Center_Name>
<Short_Name>PANGAEA</Short_Name>
<Long_Name>Data Publisher for Earth &amp; Environmental Science</Long_Name>
</Data_Center_Name>
<Data_Center_URL>https://www.pangaea.de/</Data_Center_URL>
<Personnel>
<Role>Data Center Contact</Role>
<First_Name>Michael</First_Name>
<Last_Name>Diepenbroek</Last_Name>
<Email>info@pangaea.de</Email>
<Contact_Address>
<Address>Leobener Str.</Address>
<City>Bremen</City>
<Province_or_State>Bremen</Province_or_State>
<Postal_Code>28359</Postal_Code>
<Country>Germany</Country>
</Contact_Address>
</Personnel>
</Data_Center>
<Distribution>
<Distribution_Media>online</Distribution_Media>
<Distribution_Size>2037 data points</Distribution_Size>
<Distribution_Format>text/tab-separated-values</Distribution_Format>
</Distribution>
<Reference>Ehlert von Ahn, Cátia Milene; Dellwig, Olaf; Szymczycha, Beata; Kotwicki, Lech; Rooze, Jurjen; Endler, Rudolf; Escher, Peter; Schmiedinger, Iris; Sültenfuß, Jürgen; Diak, Magdalena; Gehre, Matthias; Struck, Ulrich; Vogler, Susan; Böttcher, Michael Ernst (2024): Submarine groundwater discharge into a semi-enclosed coastal bay of the southern Baltic Sea: A multi-method approach. Oceanologia, 66(1), 111-138, https://doi.org/10.1016/j.oceano.2024.01.001</Reference>
<Summary>Pore waters were retrived from coastal sands of the southern coastline off Hel Island, Puck Bay, southern Baltic Sea. Multiport-porewater lances equipped with syringes were used to obtained vertical profiles in areas impacted by fresh submarine groundwater discharge and less impacted 'reference sites'. Samples were taken during 11 campaigns between September 2009 and October 2010. Pore waters were analyzed on-site for salinity and pH, and for major and trace elements, water isotopes (H,O) and the C isotope composition of dissolved inorganc carbon in the laboratory (via ICP-OES and gas mass spectrometry). Selected methane samples were analyzed via GCirmMS for the C and H isotope composition. It was the aim to investigate the fluxes and fresh water composition of submarine groundwater discharge and the seasonal dynamics. ** For all details see the full metadata description at "https://doi.pangaea.de/10.1594/PANGAEA.992434"!</Summary>
<Related_URL>
<URL>http://en.wikipedia.org/wiki/ISO_6709</URL>
<Description>LATITUDE</Description>
</Related_URL>
<Related_URL>
<URL>http://en.wikipedia.org/wiki/ISO_6709</URL>
<Description>LONGITUDE</Description>
</Related_URL>
<Related_URL>
<URL>http://en.wikipedia.org/wiki/ISO_8601</URL>
<Description>DATE/TIME</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1016/j.oceano.2024.01.001</URL>
<Description>Submarine groundwater discharge into a semi-enclosed coastal bay of the southern Baltic Sea: A multi-method approach</Description>
</Related_URL>
<Related_URL>
<URL>https://en.wikipedia.org/wiki/Alkalinity</URL>
<Description>Alkalinity, total</Description>
</Related_URL>
<Related_URL>
<URL>https://en.wikipedia.org/wiki/Deuterium</URL>
<Description>δ Deuterium, methane</Description>
</Related_URL>
<Related_URL>
<URL>https://www.geonames.org/3087689</URL>
<Description>Puck Bay, Baltic Sea, Poland</Description>
</Related_URL>
<Metadata_Name>DIF</Metadata_Name>
<Metadata_Version>9.4</Metadata_Version>
<DIF_Creation_Date>2026-02-23</DIF_Creation_Date>
<Last_DIF_Revision_Date>2026-04-30</Last_DIF_Revision_Date>
</DIF>
