<?xml version="1.0" encoding="UTF-8"?><!--*** Generated from internal PANGAEA metadata schema by dif.xslt ***--><DIF xsi:schemaLocation="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/ http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/dif_v9.4.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/">
<Entry_ID>PANGAEA_991542</Entry_ID>
<Entry_Title>Zn and Pb isotope compositions and elemental ratios in aerosols from the South Pacific Ocean during SONNE cruise SO289 (GEOTRACES section GP21)</Entry_Title>
<Data_Set_Citation>
<Dataset_Creator>Benaltabet, Tal; Gosnell, Kathleen; de Souza, Gregory F; Jasinski, Dominik; Rickli, Jörg Dominik; O'Sullivan, Edel Mary; Steiner, Zvi; Achterberg, Eric Pieter; Vance, Derek</Dataset_Creator>
<Dataset_Title>Zn and Pb isotope compositions and elemental ratios in aerosols from the South Pacific Ocean during SONNE cruise SO289 (GEOTRACES section GP21)</Dataset_Title>
<Dataset_Release_Date>2026-03-02</Dataset_Release_Date>
<Dataset_Publisher>PANGAEA</Dataset_Publisher>
<Data_Presentation_Form>Dataset</Data_Presentation_Form>
<Online_Resource>https://doi.pangaea.de/10.1594/PANGAEA.991542</Online_Resource>
</Data_Set_Citation>
<Personnel>
<Role>Investigator</Role>
<First_Name>Tal</First_Name>
<Last_Name>Benaltabet</Last_Name>
</Personnel>
<Discipline>
<Discipline_Name>Earth Science</Discipline_Name>
</Discipline>
<Parameters>
<Detailed_Variable>Sample code/label</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>DATE/TIME</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>LATITUDE</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>LONGITUDE</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Aluminium</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Manganese</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Zinc</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Lead</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ66Zn</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ66Zn, standard deviation</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Lead-206/Lead-207 ratio</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Lead-206/Lead-207 ratio, error</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Lead-208/Lead-206 ratio</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Lead-208/Lead-206 ratio, error</Detailed_Variable>
</Parameters>
<ISO_Topic_Category>geoscientificInformation</ISO_Topic_Category>
<Keyword>aerosols</Keyword>
<Keyword>Aerosol sampler</Keyword>
<Keyword>anthropogenic tracers</Keyword>
<Keyword>GEOTRACES</Keyword>
<Keyword>GP21-aerosols</Keyword>
<Keyword>Marine particles</Keyword>
<Keyword>Pb isotopes</Keyword>
<Keyword>SO289</Keyword>
<Keyword>SO289_0_Underway-8</Keyword>
<Keyword>South Pacific Ocean</Keyword>
<Keyword>Zn isotope</Keyword>
<Source_Name>
<Long_Name>Sonne_2</Long_Name>
</Source_Name>
<Temporal_Coverage>
<Start_Date>2022-02-22</Start_Date>
<Stop_Date>2022-03-31</Stop_Date>
</Temporal_Coverage>
<Data_Set_Progress>Complete</Data_Set_Progress>
<Spatial_Coverage>
<Southernmost_Latitude>-36.7</Southernmost_Latitude>
<Northernmost_Latitude>-25.8</Northernmost_Latitude>
<Westernmost_Longitude>-172.0</Westernmost_Longitude>
<Easternmost_Longitude>-73.1</Easternmost_Longitude>
</Spatial_Coverage>
<Project>
<Short_Name>GEOTRACES</Short_Name>
<Long_Name>Global marine biogeochemical cycles of trace elements and their isotopes</Long_Name>
</Project>
<Access_Constraints>unrestricted</Access_Constraints>
<Use_Constraints>CC-BY-4.0: Creative Commons Attribution 4.0 International</Use_Constraints>
<Data_Set_Language>English</Data_Set_Language>
<Data_Center>
<Data_Center_Name>
<Short_Name>PANGAEA</Short_Name>
<Long_Name>Data Publisher for Earth &amp; Environmental Science</Long_Name>
</Data_Center_Name>
<Data_Center_URL>https://www.pangaea.de/</Data_Center_URL>
<Personnel>
<Role>Data Center Contact</Role>
<First_Name>Michael</First_Name>
<Last_Name>Diepenbroek</Last_Name>
<Email>info@pangaea.de</Email>
<Contact_Address>
<Address>Leobener Str.</Address>
<City>Bremen</City>
<Province_or_State>Bremen</Province_or_State>
<Postal_Code>28359</Postal_Code>
<Country>Germany</Country>
</Contact_Address>
</Personnel>
</Data_Center>
<Distribution>
<Distribution_Media>online</Distribution_Media>
<Distribution_Size>282 data points</Distribution_Size>
<Distribution_Format>text/tab-separated-values</Distribution_Format>
</Distribution>
<Reference>Al-Hashem, Ali A; Beck, A J; Krisch, Stephan; Menzel Barraqueta, Jan-Lukas; Steffens, Tim; Achterberg, Eric Pieter (accepted): Particulate Trace Metal Sources, Cycling, and Distributions on the Southwest African Shelf. Global Biogeochemical Cycles, 36(11), https://doi.org/10.1029/2022GB007453</Reference>
<Reference>Berger, Carolyn J M; Lippiatt, Sherry M; Lawrence, Michael G; Bruland, Kenneth W (2008): Application of a chemical leach technique for estimating labile particulate aluminum, iron, and manganese in the Columbia River plume and coastal waters off Oregon and Washington. Journal of Geophysical Research: Oceans, 113(C2), 2007JC004703, https://doi.org/10.1029/2007JC004703</Reference>
<Reference>Bermin, J; Vance, Derek; Archer, Corey; Statham, P J (2006): The determination of the isotopic composition of Cu and Zn in seawater. Chemical Geology, 226(3-4), 280-297, https://doi.org/10.1016/j.chemgeo.2005.09.025</Reference>
<Reference>Lugmair, G W; Galer, Stephen J G (1992): Age and isotopic relationships among the angrites Lewis Cliff 86010 and Angra dos Reis. Geochimica et Cosmochimica Acta, 56(4), 1673-1694, https://doi.org/10.1016/0016-7037(92)90234-A</Reference>
<Summary>This dataset contains Zn and Pb isotope compositions (δ66Zn, 206Pb/207Pb, 208Pb/206Pb) and elemental ratios (Zn/P, Zn/Al, Zn/Mn, Pb/Al) in marine particles and aerosols (labile and refractory fractions) from the South Pacific Ocean samples collected during the SONNE cruise SO289 (GEOTRACES section GP21; February 23 - April 4, 2022). Seawater (6-8 L) was collected using trace metal clean Niskin bottles and subsequently filtered through 0.2 µm pore size filters to collect marine particles. Atmospheric aerosols (&gt; PM 10) were collected using a high-volume aerosol collector for 48 – 72 hour intervals. 
Labile particulate phases in marine particles and aerosols were extracted using a mild acetic acid + hydroxylamine hydrochloride leach (Berger et al., 2008). Refractory particulate phases were digested using a HNO3-HF mixture (Al-Hashem et al., 2022). Samples were analyzed for elemental abundances using an Element XR high-resolution ICP-MS. Samples for Zn and Pb isotope analysis were purified by column chromatography (Bermin et al., 2006; Lugmair &amp; Galer, 1992) and measured on a Neptune Plus multi-collector ICP-MS. ** For all details see the full metadata description at "https://doi.pangaea.de/10.1594/PANGAEA.991542"!</Summary>
<Related_URL>
<URL>http://en.wikipedia.org/wiki/ISO_6709</URL>
<Description>LATITUDE</Description>
</Related_URL>
<Related_URL>
<URL>http://en.wikipedia.org/wiki/ISO_6709</URL>
<Description>LONGITUDE</Description>
</Related_URL>
<Related_URL>
<URL>http://en.wikipedia.org/wiki/ISO_8601</URL>
<Description>DATE/TIME</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1016/0016-7037(92)90234-A</URL>
<Description>Age and isotopic relationships among the angrites Lewis Cliff 86010 and Angra dos Reis</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1016/j.chemgeo.2005.09.025</URL>
<Description>The determination of the isotopic composition of Cu and Zn in seawater</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1029/2007JC004703</URL>
<Description>Application of a chemical leach technique for estimating labile particulate aluminum, iron, and manganese in the Columbia River plume and coastal waters off Oregon and Washington</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1029/2022GB007453</URL>
<Description>Particulate Trace Metal Sources, Cycling, and Distributions on the Southwest African Shelf</Description>
</Related_URL>
<Related_URL>
<URL>https://uol.de/icbm/forschungsplattformen-schiffe/sonne</URL>
<Description>Sonne_2</Description>
</Related_URL>
<Related_URL>
<URL>https://www.geotraces.org/</URL>
<Description>GEOTRACES</Description>
</Related_URL>
<Metadata_Name>DIF</Metadata_Name>
<Metadata_Version>9.4</Metadata_Version>
<DIF_Creation_Date>2026-03-02</DIF_Creation_Date>
<Last_DIF_Revision_Date>2026-04-29</Last_DIF_Revision_Date>
</DIF>
