<?xml version="1.0" encoding="UTF-8"?><!--*** Generated from internal PANGAEA metadata schema by dif.xslt ***--><DIF xsi:schemaLocation="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/ http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/dif_v9.4.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/">
<Entry_ID>PANGAEA_991015</Entry_ID>
<Entry_Title>Measured iron isotopic compositions of Fe-Mn crust sample CXD31</Entry_Title>
<Data_Set_Citation>
<Dataset_Creator>Chu, Yongzhi; Li, Xiaohu; Xie, Ruifang C; Conway, Tim M; Xu, Antao; Dong, Yanhui</Dataset_Creator>
<Dataset_Title>Measured iron isotopic compositions of Fe-Mn crust sample CXD31</Dataset_Title>
<Dataset_Release_Date>2026-04-01</Dataset_Release_Date>
<Dataset_Publisher>PANGAEA</Dataset_Publisher>
<Data_Presentation_Form>Dataset</Data_Presentation_Form>
<Online_Resource>https://doi.pangaea.de/10.1594/PANGAEA.991015</Online_Resource>
</Data_Set_Citation>
<Personnel>
<Role>Investigator</Role>
<First_Name>Yongzhi</First_Name>
<Last_Name>Chu</Last_Name>
</Personnel>
<Discipline>
<Discipline_Name>Earth Science</Discipline_Name>
</Discipline>
<Parameters>
<Detailed_Variable>Age</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ56Fe</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ56Fe, standard deviation</Detailed_Variable>
</Parameters>
<ISO_Topic_Category>geoscientificInformation</ISO_Topic_Category>
<Keyword>Aeolian dust</Keyword>
<Keyword>CXD31</Keyword>
<Keyword>Dredge, rock</Keyword>
<Keyword>DY105-12/14_CXD31</Keyword>
<Keyword>Ferromanganese crust</Keyword>
<Keyword>Iron biogeochemsitry</Keyword>
<Keyword>Isotopic fingerprinting</Keyword>
<Keyword>Marine geochemistry</Keyword>
<Keyword>North Pacific</Keyword>
<Sensor_Name>
<Long_Name>Multiple-collector inductively coupled plasma mass spectrometer (MC-ICPMS)</Long_Name>
</Sensor_Name>
<Temporal_Coverage>
<Start_Date>2003-07-19</Start_Date>
<Stop_Date>2003-07-19</Stop_Date>
</Temporal_Coverage>
<Data_Set_Progress>Complete</Data_Set_Progress>
<Spatial_Coverage>
<Southernmost_Latitude>19.9</Southernmost_Latitude>
<Northernmost_Latitude>19.9</Northernmost_Latitude>
<Westernmost_Longitude>173.2</Westernmost_Longitude>
<Easternmost_Longitude>173.2</Easternmost_Longitude>
</Spatial_Coverage>
<Access_Constraints>unrestricted</Access_Constraints>
<Use_Constraints>CC-BY-4.0: Creative Commons Attribution 4.0 International</Use_Constraints>
<Data_Set_Language>English</Data_Set_Language>
<Data_Center>
<Data_Center_Name>
<Short_Name>PANGAEA</Short_Name>
<Long_Name>Data Publisher for Earth &amp; Environmental Science</Long_Name>
</Data_Center_Name>
<Data_Center_URL>https://www.pangaea.de/</Data_Center_URL>
<Personnel>
<Role>Data Center Contact</Role>
<First_Name>Michael</First_Name>
<Last_Name>Diepenbroek</Last_Name>
<Email>info@pangaea.de</Email>
<Contact_Address>
<Address>Leobener Str.</Address>
<City>Bremen</City>
<Province_or_State>Bremen</Province_or_State>
<Postal_Code>28359</Postal_Code>
<Country>Germany</Country>
</Contact_Address>
</Personnel>
</Data_Center>
<Distribution>
<Distribution_Media>online</Distribution_Media>
<Distribution_Size>78 data points</Distribution_Size>
<Distribution_Format>text/tab-separated-values</Distribution_Format>
</Distribution>
<Summary>Iron (Fe) is a key micronutrient regulating marine productivity and the global carbon cycle, yet reconstructing the relative contributions of different Fe sources through time remains challenging. Here we present high-resolution iron isotopic compositions (δ56Fe), measured by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS), from a Fe-Mn crust sample (CXD31) recovered from the North Pacific Ocean, spanning the past ~23 Myr. The Fe isotopic values vary within the range of modern marine Fe sources, reflecting dynamic mixing among atmospheric dust, sedimentary inputs, and hydrothermal contributions. Using isotope mass-balance calculations, we reconstruct temporal changes in the relative importance of these Fe sources since the Miocene. Three intervals characterized by elevated δ56Fe values (~16.9, ~11.6, and ~2.7 Ma) indicate enhanced inputs of isotopically heavy Fe, which we attribute to increased aeolian dust supply linked to progressive aridification of inland Asia. These Fe isotope data provide a long-term record of Fe source variability in the North Pacific and offer new constraints on the coupling between continental climate evolution and oceanic Fe cycling. ** For all details see the full metadata description at "https://doi.pangaea.de/10.1594/PANGAEA.991015"!</Summary>
<Metadata_Name>DIF</Metadata_Name>
<Metadata_Version>9.4</Metadata_Version>
<DIF_Creation_Date>2026-04-01</DIF_Creation_Date>
<Last_DIF_Revision_Date>2026-04-01</Last_DIF_Revision_Date>
</DIF>
