<?xml version="1.0" encoding="UTF-8"?><resource xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.3/metadata.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4"><identifier identifierType="URL">https://doi.pangaea.de/10.1594/PANGAEA.991015</identifier><creators><creator><creatorName>Chu, Yongzhi</creatorName><givenName>Yongzhi</givenName><familyName>Chu</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-2549-0670</nameIdentifier><affiliation affiliationIdentifierScheme="ROR" affiliationIdentifier="https://ror.org/0220qvk04">Shanghai Jiao Tong University</affiliation></creator><creator><creatorName>Li, Xiaohu</creatorName><givenName>Xiaohu</givenName><familyName>Li</familyName></creator><creator><creatorName>Xie, Ruifang C</creatorName><givenName>Ruifang C</givenName><familyName>Xie</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-6628-9236</nameIdentifier></creator><creator><creatorName>Conway, Tim M</creatorName><givenName>Tim M</givenName><familyName>Conway</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-3069-9786</nameIdentifier></creator><creator><creatorName>Xu, Antao</creatorName><givenName>Antao</givenName><familyName>Xu</familyName><nameIdentifier schemeURI="http://orcid.org/" nameIdentifierScheme="ORCID">0000-0002-5644-0852</nameIdentifier></creator><creator><creatorName>Dong, Yanhui</creatorName><givenName>Yanhui</givenName><familyName>Dong</familyName></creator></creators><titles><title>Measured iron isotopic compositions of Fe-Mn crust sample CXD31</title></titles><publisher>PANGAEA</publisher><publicationYear>2026</publicationYear><subjects><subject>Aeolian dust</subject><subject>Ferromanganese crust</subject><subject>Iron biogeochemsitry</subject><subject>Isotopic fingerprinting</subject><subject>Marine geochemistry</subject><subject>North Pacific</subject><subject subjectScheme="Parameter">Age</subject><subject subjectScheme="Parameter">δ56Fe</subject><subject subjectScheme="Parameter">δ56Fe, standard deviation</subject><subject subjectScheme="Method">Dredge, rock</subject><subject subjectScheme="Method">Multiple-collector inductively coupled plasma mass spectrometer (MC-ICPMS)</subject></subjects><dates><date dateType="Collected">2003-07-19T00:00:00</date></dates><resourceType resourceTypeGeneral="Dataset">Dataset</resourceType><sizes><size>78 data points</size></sizes><formats><format>text/tab-separated-values</format></formats><rightsList><rights rightsURI="https://creativecommons.org/licenses/by/4.0/" schemeURI="https://spdx.org/licenses/" rightsIdentifierScheme="SPDX" rightsIdentifier="CC-BY-4.0">Creative Commons Attribution 4.0 International</rights></rightsList><descriptions><description descriptionType="Abstract">Iron (Fe) is a key micronutrient regulating marine productivity and the global carbon cycle, yet reconstructing the relative contributions of different Fe sources through time remains challenging. Here we present high-resolution iron isotopic compositions (δ56Fe), measured by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS), from a Fe-Mn crust sample (CXD31) recovered from the North Pacific Ocean, spanning the past ~23 Myr. The Fe isotopic values vary within the range of modern marine Fe sources, reflecting dynamic mixing among atmospheric dust, sedimentary inputs, and hydrothermal contributions. Using isotope mass-balance calculations, we reconstruct temporal changes in the relative importance of these Fe sources since the Miocene. Three intervals characterized by elevated δ56Fe values (~16.9, ~11.6, and ~2.7 Ma) indicate enhanced inputs of isotopically heavy Fe, which we attribute to increased aeolian dust supply linked to progressive aridification of inland Asia. These Fe isotope data provide a long-term record of Fe source variability in the North Pacific and offer new constraints on the coupling between continental climate evolution and oceanic Fe cycling.</description></descriptions><geoLocations><geoLocation><geoLocationPoint><pointLongitude>173.2</pointLongitude><pointLatitude>19.9</pointLatitude></geoLocationPoint></geoLocation></geoLocations><fundingReferences><fundingReference><funderName>National Key Research and Development Program of China</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100012166</funderIdentifier><awardNumber>2023YFC2811205</awardNumber></fundingReference><fundingReference><funderName>National Key Research and Development Program of China</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100012166</funderIdentifier><awardNumber>2023YFC2811305</awardNumber></fundingReference><fundingReference><funderName>National Natural Science Foundation of China</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100001809</funderIdentifier><awardNumber>42376035</awardNumber></fundingReference><fundingReference><funderName>National Natural Science Foundation of China</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100001809</funderIdentifier><awardNumber>U2244222</awardNumber></fundingReference><fundingReference><funderName>Second Institute of Oceanography, State Oceanic Administration</funderName><funderIdentifier funderIdentifierType="Crossref Funder ID">https://doi.org/10.13039/501100013288</funderIdentifier><awardNumber>SZ2563</awardNumber></fundingReference></fundingReferences></resource>