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Thomas, David Neville; Papadimitriou, Stathys (2026): Sea ice brine biogeochemistry measured during RV POLARSTERN cruise ANT-XXIII/7 aka WWOS in 2006 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.990477

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Published: 2026-02-25 • DOI registered: 2026-03-26

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Abstract:
During the WWOS expedition of RV Polarstern in 2006 sea ice brine samples (from sackhole sampling) were routinely taken. Subsequent analyses included pH, temperature, salinity, dissolved inorganic and organic (DOC & DON) nutrients (Nitrite, nitrate, ammonium, phosphate, silicate), dissolved oxygen, alkalinity, 13C of DIC, 18O, chlorophyll, Particulate organic carbon and nitrogen, CDOM absorbance.
Keyword(s):
biogeochemical data; brine; Sea ice; Southern Ocean; Weddell Sea
Related to:
Lemke, Peter (2009): The Expedition of the Research Vessel Polarstern to the Antarctic in 2006 (ANT-XXIII/7). Berichte zur Polar- und Meeresforschung = Reports on Polar and Marine Research, 586, 147 pp, https://doi.org/10.2312/BzPM_0586_2009
References:
Norman, Louiza; Thomas, David Neville; Stedmon, Colin A; Granskog, Mats A; Papadimitriou, Stathys; Krapp, Rupert H; Meiners, Klaus M; Lannuzel, Delphine; Van Der Merwe, P; Dieckmann, Gerhard S (2011): The characteristics of dissolved organic matter (DOM) and chromophoric dissolved organic matter (CDOM) in Antarctic sea ice. Deep Sea Research Part II: Topical Studies in Oceanography, 58(9-10), 1075-1091, https://doi.org/10.1016/j.dsr2.2010.10.030
Papadimitriou, Stathys; Kennedy, Hilary; Norman, Louiza; Kennedy, D P; Dieckmann, Gerhard S; Thomas, David Neville (2012): The effect of biological activity, CaCO 3 mineral dynamics, and CO 2 degassing in the inorganic carbon cycle in sea ice in late winter‐early spring in the Weddell Sea, Antarctica. Journal of Geophysical Research: Oceans, 117(C8), 2012JC008058, https://doi.org/10.1029/2012JC008058
Stedmon, Colin A; Thomas, David Neville; Papadimitriou, Stathys; Granskog, Mats A; Dieckmann, Gerhard S (2011): Using fluorescence to characterize dissolved organic matter in Antarctic sea ice brines. Journal of Geophysical Research, 116(G3), G03027, https://doi.org/10.1029/2011JG001716
Underwood, G J C; Fietz, Susanne; Papadimitriou, Stathys; Thomas, David Neville; Dieckmann, Gerhard S (2010): Distribution and composition of dissolved extracellular polymeric substances (EPS) in Antarctic sea ice. Marine Ecology Progress Series, 404, 1-19, https://doi.org/10.3354/meps08557
Underwood, Graham J C; Aslam, Shazia N; Michel, Christine; Niemi, Andrea; Norman, Louiza; Meiners, Klaus M; Laybourn-Parry, Johanna; Paterson, Harriet; Thomas, David Neville (2013): Broad-scale predictability of carbohydrates and exopolymers in Antarctic and Arctic sea ice. Proceedings of the National Academy of Sciences of the United States of America, 110(39), 15734-15739, https://doi.org/10.1073/pnas.1302870110
Coverage:
Median Latitude: -62.623677 * Median Longitude: -51.129337 * South-bound Latitude: -65.110400 * West-bound Longitude: -57.405600 * North-bound Latitude: -59.835100 * East-bound Longitude: -40.816300
Date/Time Start: 2006-09-08T18:52:00 * Date/Time End: 2006-10-13T16:05:00
Minimum DEPTH, ice/snow: 0.150 m * Maximum DEPTH, ice/snow: 1.860 m
Event(s):
PS69/542-2 (WS-1) * Latitude Start: -60.466000 * Longitude Start: -40.816300 * Latitude End: -60.445500 * Longitude End: -40.784800 * Date/Time Start: 2006-09-08T18:52:00 * Date/Time End: 2006-09-08T21:25:00 * Elevation Start: -759.0 m * Elevation End: -737.0 m * Location: Scotia Sea, southwest Atlantic * Campaign: ANT-XXIII/7 (PS69 WWOS) * Basis: Polarstern * Method/Device: Ice station (ICE)
PS69/543-1 (WS-2) * Latitude Start: -60.600500 * Longitude Start: -41.642500 * Latitude End: -60.598800 * Longitude End: -41.497900 * Date/Time Start: 2006-09-09T13:30:00 * Date/Time End: 2006-09-09T20:48:00 * Elevation Start: -2611.0 m * Elevation End: -2298.0 m * Location: Weddell Sea * Campaign: ANT-XXIII/7 (PS69 WWOS) * Basis: Polarstern * Method/Device: Ice station (ICE)
PS69/545-2 * Latitude: -60.672800 * Longitude: -42.156000 * Date/Time: 2006-09-10T14:15:00 * Elevation: -2518.0 m * Location: Weddell Sea * Campaign: ANT-XXIII/7 (PS69 WWOS) * Basis: Polarstern * Method/Device: Ice station (ICE)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventThomas, David Neville
2DATE/TIMEDate/TimeThomas, David NevilleGeocode
3LATITUDELatitudeThomas, David NevilleGeocode
4LONGITUDELongitudeThomas, David NevilleGeocode
5Sample IDSample IDThomas, David Neville
6DEPTH, ice/snowDepth ice/snowmThomas, David NevilleGeocode – sackhole depth which is measured from the top of the ice to bottom of the sackhole
7Temperature, brineT brine°CThomas, David NevilleThermometer, HANNA Instruments, HI93530 [calibrated K-Thermocouple probe]
8SalinitySalThomas, David NevilleConductivity meter, SEMAT, Cond 315i/SET; measured with conductivity probe, WTW, TetraCon 325
9pHpHThomas, David NevillepH meter (Metrohm electrodes)measured at laboratory temperature with a Metrohm pH meter, platinum temperature probe, Ag/AgCl reference electrode, and glass indicator electrode calibrated daily with NBS standards
10Alkalinity, totalATµmol/kgThomas, David NevillePotentiometric titrationpotentiometric titration with 0.05 N HCl (Titrisol) using a Metrohm system of automatic burette, pH meter, platinum temperature probe, Ag/AgCl reference electrode, and glass indicator electrode calibrated daily with NBS standards
11Carbon, inorganic, dissolvedDICµmol/kgThomas, David NevilleVacuum line manometer, Chell instrumentsdetermined following in vacuo reaction with 85% H3PO4 and cryogenic CO2 gas distillation using an in-line manometer
12δ13C, dissolved inorganic carbonδ13C DIC‰ PDBThomas, David NevilleMass spectrometer, VG SIRA II and Mass spectrometer, PDZ Europa Ltd.samples filtered (precombusted GF/F), acidified and dried. The Isotopic measurements of carbon were determined on CO2 generated by vacuum combusion and isotopes measured using VG SIRA II and PDZ-EUROPA 20/20 isotope ratio mass spectrometers
13OxygenO2µmol/kgThomas, David NevilleWinkler titration with photometric end-point detection
14Dissolved oxygen saturationDO sat%Thomas, David NevilleCalculatedin situ
15Chlorophyll aChl aµg/lThomas, David NevilleFluorometer, Turner Design, TD-700samples filtered (precombusted GF/F), extracted in 90% acetone and analysed on fluorometer
16PhaeopigmentsPhaeµg/lThomas, David NevilleFluorometer, Turner Design, TD-700samples filtered (precombusted GF/F), extracted in 90% acetone, acidified and analysed on fluorometer
17Carbon, organic, dissolvedDOCµmol/kgThomas, David NevilleTOC analyzer, MQ 1001
18Nitrogen, organic, dissolvedDONµmol/kgThomas, David NevilleFlow injection analyser, Lachat Instrumentsdetermined by subtraction of NO3 and NH4 from the total dissolved nitrogen (TDN) analyzed by FIA on the LACHAT autoanalyzer using on-line peroxodisulfate oxidation coupled with ultraviolet radiation at pH 9.0 and 100°C
19Ammonium[NH4]+µmol/kgThomas, David NevilleFluorescence spectrophotometer, Hitachi, F-2000
20Nitrite[NO2]-µmol/kgThomas, David NevilleFlow injection analyzer, Lachat Instruments, QuikChem 8000
21Nitrate and Nitrite[NO3]- + [NO2]-µmol/kgThomas, David NevilleFlow injection analyzer, Lachat Instruments, QuikChem 8000
22Phosphate[PO4]3-µmol/kgThomas, David NevilleFlow injection analyzer, Lachat Instruments, QuikChem 8000
23SilicateSi(OH)4µmol/kgThomas, David NevilleFlow injection analyzer, Lachat Instruments, QuikChem 8000
24Nitrogen, organic, particulatePONµmol/kgThomas, David NevilleCN analyzer, Europa Scientificsamples filtered (precombusted GF/F) and acidified and dried. Filters analysed with a CN analyser, using acetanilide as a standard
25Carbon, organic, particulatePOCµmol/kgThomas, David NevilleCN analyzer, Europa Scientificsamples filtered (precombusted GF/F) and acidified and dried. Filters analysed with a CN analyser, using acetanilide as a standard
26δ18O, iceδ18O ice‰ SMOWThomas, David NevilleIsotope ratio mass spectrometer, PDZ Europa Ltd., 20-20was conducted by off-line equilibration with CO2 and subsequent measurement of the oxygen isotope ratios using a PDZ–EUROPA GEO 20/20 mass spectrometer, with normalisation relative to North Sea seawater
27Absorption coefficient, colored dissolved organic matter at 240 nmaCDOM_2401/mThomas, David NevilleUV-VIS-Spektrophotometer, Shimadzu, 1601samples filtered (precombusted GF/F) & absorbance of CDOM was measured at room temperature using a dual beam Shimadzu 1601 UV-Vis spectrophotometer over the range 200 to 750 nm at a resolution of 0.5 nm
28Absorption coefficient, colored dissolved organic matter at 280 nmaCDOM_2801/mThomas, David NevilleUV-VIS-Spektrophotometer, Shimadzu, 1601samples filtered (precombusted GF/F) & absorbance of CDOM was measured at room temperature using a dual beam Shimadzu 1601 UV-Vis spectrophotometer over the range 200 to 750 nm at a resolution of 0.5 nm
29Absorption coefficient, colored dissolved organic matter at 300 nmaCDOM_3001/mThomas, David NevilleUV-VIS-Spektrophotometer, Shimadzu, 1601samples filtered (precombusted GF/F) & absorbance of CDOM was measured at room temperature using a dual beam Shimadzu 1601 UV-Vis spectrophotometer over the range 200 to 750 nm at a resolution of 0.5 nm
30Absorption coefficient, colored dissolved organic matter at 330 nmaCDOM_3301/mThomas, David NevilleUV-VIS-Spektrophotometer, Shimadzu, 1601samples filtered (precombusted GF/F) & absorbance of CDOM was measured at room temperature using a dual beam Shimadzu 1601 UV-Vis spectrophotometer over the range 200 to 750 nm at a resolution of 0.5 nm
31Absorption coefficient, colored dissolved organic matter at 350 nmaCDOM_3501/mThomas, David NevilleUV-VIS-Spektrophotometer, Shimadzu, 1601samples filtered (precombusted GF/F) & absorbance of CDOM was measured at room temperature using a dual beam Shimadzu 1601 UV-Vis spectrophotometer over the range 200 to 750 nm at a resolution of 0.5 nm
32Absorption coefficient, colored dissolved organic matter at 440 nmaCDOM_4401/mThomas, David NevilleUV-VIS-Spektrophotometer, Shimadzu, 1601samples filtered (precombusted GF/F) & absorbance of CDOM was measured at room temperature using a dual beam Shimadzu 1601 UV-Vis spectrophotometer over the range 200 to 750 nm at a resolution of 0.5 nm
Status:
Curation Level: Enhanced curation (CurationLevelC) * Processing Level: PANGAEA data processing level 3 (ProcLevel3)
Size:
3143 data points

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