<?xml version="1.0" encoding="UTF-8"?><md:MetaData xmlns:md="http://www.pangaea.de/MetaData" version="2026-04-13">
<md:citation id="dataset989435">
<md:author id="dataset.author83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:author>
<md:year>2026</md:year>
<md:title>Hydrogen isotopes of n-alkane biomarkers and brGDGT temperatures from Lake Tulane, Florida, USA</md:title>
<md:type id="dataset.reftype10" includeInCitation="true">dataset</md:type>
<md:URI>https://doi.org/10.1594/PANGAEA.989435</md:URI>
<md:dateTime>2026-01-26T06:29:31</md:dateTime>
</md:citation>
<md:abstract>This dataset includes temperatures derived from branched glycerol dialkyl glycerol tetraethers (brGDGTs) and regional hydrology changes reconstructed from hydrogen isotope ratios (δ2H) of n-alkanes extracted from a lacustrine sediment core from Lake Tulane, Florida, USA. In 1994, 8 cores from 6 locations (2 complete overlaps) were acquired from a transect along the north basin of Lake Tulane. Cores were taken with a 7.5-cm diameter Wright square-rod piston corer from an anchored raft. Separately, a single surface-water interface core was acquired from the north basin of Lake Tulane in 2010. brGDGTs and n-alkanes were extracted from archived core sections at 8-10 cm intervals in August of 2018 and from the surface-water interface core at 5 cm intervals in August of 2019. The archived core interval spanned Heinrich Stadials 4-2 (41,000-17,000 BP) and the surface-water interface core spanned 78-0 BP. brGDGT distributions from both cores were measured via atmospheric pressure chemical ionization high-performance liquid chromatography-mass spectrometry (APCI/HPLC–MS), and hydrogen isotope ratios of n-alkanes were measured on a Thermo Trace GC Ultra coupled to a Thermo Electron Delta V Advantage IRMS with an Isolink combustion furnace. The brGDGT data was converted to degrees Celsius (°C) following the open-sourced code provided in O'Beirne et al. (2023, doi:10.1016/j.gca.2023.08.019). Hydrogen isotope results are given in the conventional δ-notation. A proxy for seasonal precipitation and aridity (ε(C29-C23)) was created, which reflects the difference between the δ2H values of aquatic n-alkanes (δ2HC23) and terrestrial leaf wax δ2H values (δ2HC29) using the following equations: (1) α = (1000 + 𝛿2HC29)/(1000 + 𝛿2HC23), and (2) ε(C29-C23) = (α -1) x 1000.</md:abstract>
<md:reference dataciteRelType="IsSupplementTo" group="200" id="ref137408" relationType="Supplement to" relationTypeId="5">
<md:author id="ref137408.author83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:author>
<md:author id="ref137408.author114300">
<md:lastName>Hilliker</md:lastName>
<md:firstName>J L</md:firstName>
</md:author>
<md:author id="ref137408.author33117">
<md:lastName>Werne</md:lastName>
<md:firstName>Josef P</md:firstName>
<md:eMail>jwerne@pitt.edu</md:eMail>
<md:orcid>0000-0002-7019-6024</md:orcid>
</md:author>
<md:author id="ref137408.author114301">
<md:lastName>Thompson</md:lastName>
<md:firstName>A J</md:firstName>
</md:author>
<md:prepubStatus>in review</md:prepubStatus>
<md:title>Atmospheric transmission of temperature and precipitation change in Florida during North Atlantic Heinrich events</md:title>
<md:source id="ref137408.journal16885" type="journal">Paleoceanography and Paleoclimatology</md:source>
</md:reference>
<md:reference dataciteRelType="References" group="500" id="ref137401" relationType="References" relationTypeId="24">
<md:author id="ref137401.author61491">
<md:lastName>O'Beirne</md:lastName>
<md:firstName>Molly D</md:firstName>
<md:eMail>mdobeirne@pitt.edu</md:eMail>
</md:author>
<md:author id="ref137401.author83063">
<md:lastName>Scott</md:lastName>
<md:firstName>Wesley P</md:firstName>
<md:eMail>wps17@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/wesley-scott</md:URI>
</md:author>
<md:author id="ref137401.author33117">
<md:lastName>Werne</md:lastName>
<md:firstName>Josef P</md:firstName>
<md:eMail>jwerne@pitt.edu</md:eMail>
<md:orcid>0000-0002-7019-6024</md:orcid>
</md:author>
<md:year>2023</md:year>
<md:title>A critical assessment of lacustrine branched glycerol dialkyl glycerol tetraether (brGDGT) temperature calibration models</md:title>
<md:type id="ref137401.reftype1">journal article</md:type>
<md:source id="ref137401.journal6009" relatedTermIds="33971" type="journal">Geochimica et Cosmochimica Acta</md:source>
<md:volume>359</md:volume>
<md:URI>https://doi.org/10.1016/j.gca.2023.08.019</md:URI>
<md:pages>100-118</md:pages>
</md:reference>
<md:extent>
<md:geographic>
<md:westBoundLongitude>81.500361</md:westBoundLongitude>
<md:eastBoundLongitude>81.500361</md:eastBoundLongitude>
<md:southBoundLatitude>27.585833</md:southBoundLatitude>
<md:northBoundLatitude>27.585833</md:northBoundLatitude>
<md:meanLongitude>81.500361</md:meanLongitude>
<md:meanLatitude>27.585833</md:meanLatitude>
</md:geographic>
<md:temporal>
<md:minDateTime>2018-08-11T00:00:00</md:minDateTime>
<md:maxDateTime>2018-08-11T00:00:00</md:maxDateTime>
</md:temporal>
<md:topoType id="topotype3">vertical profile</md:topoType>
</md:extent>
<md:event displayTypeName="Event" id="event3343254" typeName="Generic Event">
<md:label>Lake_Tulane_AC</md:label>
<md:optionalLabel>Lake Tulane Archive Core</md:optionalLabel>
<md:latitude>27.585833</md:latitude>
<md:longitude>81.500361</md:longitude>
<md:location id="event3343254.term37878">
<md:name>Florida, USA</md:name>
</md:location>
<md:dateTime>2018-08-11T00:00:00</md:dateTime>
<md:method id="event3343254.method10902">
<md:name>Core</md:name>
<md:optionalName>CORE</md:optionalName>
</md:method>
</md:event>
<md:event displayTypeName="Event" id="event3343253" typeName="Generic Event">
<md:label>Lake_Tulane_SC</md:label>
<md:optionalLabel>Lake Tulane Surface Core</md:optionalLabel>
<md:latitude>27.585833</md:latitude>
<md:longitude>81.500361</md:longitude>
<md:location id="event3343253.term37878">
<md:name>Florida, USA</md:name>
</md:location>
<md:dateTime>2018-08-11T00:00:00</md:dateTime>
<md:method id="event3343253.method10902">
<md:name>Core</md:name>
<md:optionalName>CORE</md:optionalName>
</md:method>
</md:event>
<md:size unit="data points">269</md:size>
<md:license id="license21">
<md:label>CC-BY-4.0</md:label>
<md:name>Creative Commons Attribution 4.0 International</md:name>
<md:URI>https://creativecommons.org/licenses/by/4.0/</md:URI>
</md:license>
<md:matrixColumn behaviour="7" col="0" id="col0.ds15844967" source="event" type="string">
<md:parameter>
<md:name>Event label</md:name>
<md:shortName>Event</md:shortName>
</md:parameter>
<md:PI id="col0.ds15844967.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:caption>Event</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="2" col="1" format="###0.0000" id="col1.ds15844967" source="event" type="numeric">
<md:parameter id="col1.ds15844967.geocode1600">
<md:name>Latitude of event</md:name>
<md:shortName>Latitude</md:shortName>
</md:parameter>
<md:PI id="col1.ds15844967.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:caption>Latitude</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="3" col="2" format="###0.0000" id="col2.ds15844967" source="event" type="numeric">
<md:parameter id="col2.ds15844967.geocode1601">
<md:name>Longitude of event</md:name>
<md:shortName>Longitude</md:shortName>
</md:parameter>
<md:PI id="col2.ds15844967.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:caption>Longitude</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="4" col="3" format="yyyy-MM-dd" id="col3.ds15844967" source="event" type="datetime">
<md:parameter id="col3.ds15844967.geocode1599">
<md:name>Date/Time of event</md:name>
<md:shortName>Date/Time</md:shortName>
</md:parameter>
<md:PI id="col3.ds15844967.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:caption>Date/Time</md:caption>
</md:matrixColumn>
<md:matrixColumn col="4" id="col4.ds15844968" source="data" type="string">
<md:parameter id="col4.ds15844968.param48492">
<md:name>Core</md:name>
<md:shortName>Core</md:shortName>
</md:parameter>
<md:PI id="col4.ds15844968.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:caption>Core</md:caption>
</md:matrixColumn>
<md:matrixColumn col="5" id="col5.ds15844969" source="data" type="string">
<md:parameter id="col5.ds15844969.param78085">
<md:name>Device type</md:name>
<md:shortName>Device</md:shortName>
</md:parameter>
<md:PI id="col5.ds15844969.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:caption>Device</md:caption>
</md:matrixColumn>
<md:matrixColumn behaviour="5" col="6" format="0" id="col6.ds15844970" source="geocode" type="numeric">
<md:parameter id="col6.ds15844970.geocode2205">
<md:name>AGE</md:name>
<md:shortName>Age</md:shortName>
<md:unit>ka BP</md:unit>
<md:URI>http://en.wikipedia.org/wiki/Kyr</md:URI>
<md:term endOffset="3" fragment="1" id="col6.ds15844970.geocode2205.term1073135" semanticURI="urn:obo:pato:term:0000011" startOffset="0" terminologyId="14" terminologyLabel="PATO">
<md:name>age</md:name>
<md:URI>http://purl.obolibrary.org/obo/PATO_0000011</md:URI>
</md:term>
<md:term id="col6.ds15844970.geocode2205.term43975" semanticURI="http://qudt.org/1.1/vocab/quantity#Time" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Time</md:name>
<md:optionalName>T</md:optionalName>
<md:URI>http://dbpedia.org/resource/Time</md:URI>
</md:term>
</md:parameter>
<md:PI id="col6.ds15844970.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:caption>Age [ka BP]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="7" format="0.00" id="col7.ds15844971" source="data" type="numeric">
<md:parameter id="col7.ds15844971.param717">
<md:name>Temperature, water</md:name>
<md:shortName>Temp</md:shortName>
<md:unit>°C</md:unit>
<md:term endOffset="11" fragment="1" id="col7.ds15844971.param717.term43972" semanticURI="http://qudt.org/1.1/vocab/quantity#ThermodynamicTemperature" startOffset="0" terminologyId="13" terminologyLabel="PAN-Quantity">
<md:name>Temperature</md:name>
<md:optionalName>Θ</md:optionalName>
<md:URI>http://dbpedia.org/resource/Temperature</md:URI>
</md:term>
<md:term endOffset="18" fragment="2" id="col7.ds15844971.param717.term2606205" semanticURI="http://purl.obolibrary.org/obo/CHEBI_15377" startOffset="13" terminologyId="16" terminologyLabel="ChEBI">
<md:name>water</md:name>
<md:URI>http://purl.obolibrary.org/obo/CHEBI_15377</md:URI>
</md:term>
</md:parameter>
<md:method id="col7.ds15844971.method18052">
<md:name>Reconstructed, using branched GDGTs</md:name>
</md:method>
<md:PI id="col7.ds15844971.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:caption>Temp [°C]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="8" format="0" id="col8.ds15844972" source="data" type="numeric">
<md:parameter id="col8.ds15844972.param531876">
<md:name>δ Deuterium, n-alkane C23</md:name>
<md:shortName>δD n-alkane C23</md:shortName>
<md:unit>‰</md:unit>
<md:term endOffset="27" fragment="2" id="col8.ds15844972.param531876.term48224" startOffset="24" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>tricosane</md:name>
<md:optionalName>C23</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col8.ds15844972.method12510">
<md:name>See Device type column</md:name>
</md:method>
<md:PI id="col8.ds15844972.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:comment>vs. VSMOW</md:comment>
<md:caption>δD n-alkane C23 [‰]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="9" format="0" id="col9.ds15844973" source="data" type="numeric">
<md:parameter id="col9.ds15844973.param531880">
<md:name>δ Deuterium, n-alkane C27</md:name>
<md:shortName>δD n-alkane C27</md:shortName>
<md:unit>‰</md:unit>
<md:term endOffset="27" fragment="2" id="col9.ds15844973.param531880.term48228" startOffset="24" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>heptacosane</md:name>
<md:optionalName>C27</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col9.ds15844973.method12510">
<md:name>See Device type column</md:name>
</md:method>
<md:PI id="col9.ds15844973.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:comment>vs. VSMOW</md:comment>
<md:caption>δD n-alkane C27 [‰]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="10" format="0" id="col10.ds15844974" source="data" type="numeric">
<md:parameter id="col10.ds15844974.param531882">
<md:name>δ Deuterium, n-alkane C29</md:name>
<md:shortName>δD n-alkane C29</md:shortName>
<md:unit>‰</md:unit>
<md:term endOffset="27" fragment="2" id="col10.ds15844974.param531882.term44232" startOffset="24" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>nonacosane</md:name>
<md:optionalName>C29</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:7613</md:URI>
</md:term>
</md:parameter>
<md:method id="col10.ds15844974.method12510">
<md:name>See Device type column</md:name>
</md:method>
<md:PI id="col10.ds15844974.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:comment>vs. VSMOW</md:comment>
<md:caption>δD n-alkane C29 [‰]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="11" format="0" id="col11.ds15844975" source="data" type="numeric">
<md:parameter id="col11.ds15844975.param531884">
<md:name>δ Deuterium, n-alkane C31</md:name>
<md:shortName>δD n-alkane C31</md:shortName>
<md:unit>‰</md:unit>
<md:term endOffset="27" fragment="2" id="col11.ds15844975.param531884.term44230" startOffset="24" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>hentriacontane</md:name>
<md:optionalName>C31</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:5659</md:URI>
</md:term>
</md:parameter>
<md:method id="col11.ds15844975.method12510">
<md:name>See Device type column</md:name>
</md:method>
<md:PI id="col11.ds15844975.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:comment>vs. VSMOW</md:comment>
<md:caption>δD n-alkane C31 [‰]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="12" format="0" id="col12.ds15844976" source="data" type="numeric">
<md:parameter id="col12.ds15844976.param531886">
<md:name>δ Deuterium, n-alkane C33</md:name>
<md:shortName>δD n-alkane C33</md:shortName>
<md:unit>‰</md:unit>
<md:term endOffset="27" fragment="2" id="col12.ds15844976.param531886.term44231" startOffset="24" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>tritriacontane</md:name>
<md:optionalName>C33</md:optionalName>
<md:URI>https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:9751</md:URI>
</md:term>
</md:parameter>
<md:method id="col12.ds15844976.method12510">
<md:name>See Device type column</md:name>
</md:method>
<md:PI id="col12.ds15844976.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:comment>vs. VSMOW</md:comment>
<md:caption>δD n-alkane C33 [‰]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="13" format="0" id="col13.ds15844977" source="data" type="numeric">
<md:parameter id="col13.ds15844977.param531888">
<md:name>δ Deuterium, n-alkane C35</md:name>
<md:shortName>δD n-alkane C35</md:shortName>
<md:unit>‰</md:unit>
<md:term endOffset="27" fragment="2" id="col13.ds15844977.param531888.term48234" startOffset="24" terminologyId="18" terminologyLabel="PAN-MicroBio">
<md:name>pentatriacontane</md:name>
<md:optionalName>C35</md:optionalName>
</md:term>
</md:parameter>
<md:method id="col13.ds15844977.method12510">
<md:name>See Device type column</md:name>
</md:method>
<md:PI id="col13.ds15844977.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:comment>vs. VSMOW</md:comment>
<md:caption>δD n-alkane C35 [‰]</md:caption>
</md:matrixColumn>
<md:matrixColumn col="14" format="0" id="col14.ds15844978" source="data" type="numeric">
<md:parameter id="col14.ds15844978.param162302">
<md:name>ε</md:name>
<md:shortName>ε</md:shortName>
<md:unit>‰</md:unit>
</md:parameter>
<md:method id="col14.ds15844978.method12510">
<md:name>See Device type column</md:name>
</md:method>
<md:PI id="col14.ds15844978.pi83064">
<md:lastName>Arnold</md:lastName>
<md:firstName>T Elliott</md:firstName>
<md:eMail>tea27@pitt.edu</md:eMail>
<md:URI>https://www.geology.pitt.edu/people/elliott-arnold</md:URI>
</md:PI>
<md:comment>c29-c23 (‰ VSMOW)</md:comment>
<md:caption>ε [‰]</md:caption>
</md:matrixColumn>
<md:status>
<md:curationLevel id="curlevel30">
<md:label>CurationLevelC</md:label>
<md:name>Enhanced curation</md:name>
<md:URI>https://wiki.pangaea.de/wiki/Curation_levels</md:URI>
</md:curationLevel>
</md:status>
<md:keywords>
<md:techKeyword type="autoGenerated">citable</md:techKeyword>
<md:keyword id="keywords.term50804" type="fromDatabase">Branched GDGTs</md:keyword>
<md:keyword id="keywords.term48489" type="fromDatabase">Hydrogen isotopes</md:keyword>
<md:keyword id="keywords.term68636" type="fromDatabase">Lake core</md:keyword>
<md:keyword id="keywords.term76992" type="fromDatabase">Lake Tulane</md:keyword>
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