<?xml version="1.0" encoding="UTF-8"?><!--*** Generated from internal PANGAEA metadata schema by dif.xslt ***--><DIF xsi:schemaLocation="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/ http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/dif_v9.4.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/">
<Entry_ID>PANGAEA_989435</Entry_ID>
<Entry_Title>Hydrogen isotopes of n-alkane biomarkers and brGDGT temperatures from Lake Tulane, Florida, USA</Entry_Title>
<Data_Set_Citation>
<Dataset_Creator>Arnold, T Elliott</Dataset_Creator>
<Dataset_Title>Hydrogen isotopes of n-alkane biomarkers and brGDGT temperatures from Lake Tulane, Florida, USA</Dataset_Title>
<Dataset_Release_Date>2026-01-26</Dataset_Release_Date>
<Dataset_Publisher>PANGAEA</Dataset_Publisher>
<Data_Presentation_Form>Dataset</Data_Presentation_Form>
<Online_Resource>https://doi.pangaea.de/10.1594/PANGAEA.989435</Online_Resource>
</Data_Set_Citation>
<Personnel>
<Role>Investigator</Role>
<First_Name>T Elliott</First_Name>
<Last_Name>Arnold</Last_Name>
<Email>tea27@pitt.edu</Email>
</Personnel>
<Discipline>
<Discipline_Name>Earth Science</Discipline_Name>
</Discipline>
<Parameters>
<Detailed_Variable>Event label</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Latitude of event</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Longitude of event</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Date/Time of event</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Core</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Device type</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>AGE</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>Temperature, water</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ Deuterium, n-alkane C23</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ Deuterium, n-alkane C27</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ Deuterium, n-alkane C29</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ Deuterium, n-alkane C31</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ Deuterium, n-alkane C33</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>δ Deuterium, n-alkane C35</Detailed_Variable>
</Parameters>
<Parameters>
<Detailed_Variable>ε</Detailed_Variable>
</Parameters>
<ISO_Topic_Category>geoscientificInformation</ISO_Topic_Category>
<Keyword>Branched GDGTs</Keyword>
<Keyword>Core</Keyword>
<Keyword>Hydrogen isotopes</Keyword>
<Keyword>Lake_Tulane_AC</Keyword>
<Keyword>Lake_Tulane_SC</Keyword>
<Keyword>Lake core</Keyword>
<Keyword>Lake Tulane</Keyword>
<Keyword>Lake Tulane Archive Core</Keyword>
<Keyword>Lake Tulane Surface Core</Keyword>
<Sensor_Name>
<Long_Name>Reconstructed, using branched GDGTs</Long_Name>
</Sensor_Name>
<Sensor_Name>
<Long_Name>See Device type column</Long_Name>
</Sensor_Name>
<Temporal_Coverage>
<Start_Date>2018-08-11</Start_Date>
<Stop_Date>2018-08-11</Stop_Date>
</Temporal_Coverage>
<Data_Set_Progress>Complete</Data_Set_Progress>
<Spatial_Coverage>
<Southernmost_Latitude>27.585833</Southernmost_Latitude>
<Northernmost_Latitude>27.585833</Northernmost_Latitude>
<Westernmost_Longitude>81.500361</Westernmost_Longitude>
<Easternmost_Longitude>81.500361</Easternmost_Longitude>
</Spatial_Coverage>
<Access_Constraints>unrestricted</Access_Constraints>
<Use_Constraints>CC-BY-4.0: Creative Commons Attribution 4.0 International</Use_Constraints>
<Data_Set_Language>English</Data_Set_Language>
<Data_Center>
<Data_Center_Name>
<Short_Name>PANGAEA</Short_Name>
<Long_Name>Data Publisher for Earth &amp; Environmental Science</Long_Name>
</Data_Center_Name>
<Data_Center_URL>https://www.pangaea.de/</Data_Center_URL>
<Personnel>
<Role>Data Center Contact</Role>
<First_Name>Michael</First_Name>
<Last_Name>Diepenbroek</Last_Name>
<Email>info@pangaea.de</Email>
<Contact_Address>
<Address>Leobener Str.</Address>
<City>Bremen</City>
<Province_or_State>Bremen</Province_or_State>
<Postal_Code>28359</Postal_Code>
<Country>Germany</Country>
</Contact_Address>
</Personnel>
</Data_Center>
<Distribution>
<Distribution_Media>online</Distribution_Media>
<Distribution_Size>269 data points</Distribution_Size>
<Distribution_Format>text/tab-separated-values</Distribution_Format>
</Distribution>
<Reference>Arnold, T Elliott; Hilliker, J L; Werne, Josef P; Thompson, A J (in review): Atmospheric transmission of temperature and precipitation change in Florida during North Atlantic Heinrich events. Paleoceanography and Paleoclimatology</Reference>
<Reference>O'Beirne, Molly D; Scott, Wesley P; Werne, Josef P (2023): A critical assessment of lacustrine branched glycerol dialkyl glycerol tetraether (brGDGT) temperature calibration models. Geochimica et Cosmochimica Acta, 359, 100-118, https://doi.org/10.1016/j.gca.2023.08.019</Reference>
<Summary>This dataset includes temperatures derived from branched glycerol dialkyl glycerol tetraethers (brGDGTs) and regional hydrology changes reconstructed from hydrogen isotope ratios (δ2H) of n-alkanes extracted from a lacustrine sediment core from Lake Tulane, Florida, USA. In 1994, 8 cores from 6 locations (2 complete overlaps) were acquired from a transect along the north basin of Lake Tulane. Cores were taken with a 7.5-cm diameter Wright square-rod piston corer from an anchored raft. Separately, a single surface-water interface core was acquired from the north basin of Lake Tulane in 2010. brGDGTs and n-alkanes were extracted from archived core sections at 8-10 cm intervals in August of 2018 and from the surface-water interface core at 5 cm intervals in August of 2019. The archived core interval spanned Heinrich Stadials 4-2 (41,000-17,000 BP) and the surface-water interface core spanned 78-0 BP. brGDGT distributions from both cores were measured via atmospheric pressure chemical ionization high-performance liquid chromatography-mass spectrometry (APCI/HPLC–MS), and hydrogen isotope ratios of n-alkanes were measured on a Thermo Trace GC Ultra coupled to a Thermo Electron Delta V Advantage IRMS with an Isolink combustion furnace. The brGDGT data was converted to degrees Celsius (°C) following the open-sourced code provided in O'Beirne et al. (2023, doi:10.1016/j.gca.2023.08.019). Hydrogen isotope results are given in the conventional δ-notation. A proxy for seasonal precipitation and aridity (ε(C29-C23)) was created, which reflects the difference between the δ2H values of aquatic n-alkanes (δ2HC23) and terrestrial leaf wax δ2H values (δ2HC29) using the following equations: (1) α = (1000 + 𝛿2HC29)/(1000 + 𝛿2HC23), and (2) ε(C29-C23) = (α -1) x 1000. ** For all details see the full metadata description at "https://doi.pangaea.de/10.1594/PANGAEA.989435"!</Summary>
<Related_URL>
<URL>http://en.wikipedia.org/wiki/Kyr</URL>
<Description>AGE</Description>
</Related_URL>
<Related_URL>
<URL>https://doi.org/10.1016/j.gca.2023.08.019</URL>
<Description>A critical assessment of lacustrine branched glycerol dialkyl glycerol tetraether (brGDGT) temperature calibration models</Description>
</Related_URL>
<Related_URL>
<URL>https://www.geology.pitt.edu/people/elliott-arnold</URL>
</Related_URL>
<Metadata_Name>DIF</Metadata_Name>
<Metadata_Version>9.4</Metadata_Version>
<DIF_Creation_Date>2026-01-26</DIF_Creation_Date>
<Last_DIF_Revision_Date>2026-04-30</Last_DIF_Revision_Date>
</DIF>
